公开(公告)号：US5266673A

公开(公告)日：1993-11-30

申请号：US883682

申请日：1992-05-15

申请人： Toru Tsukahara ,  Hiromi Nishimura ,  Mitsutoshi Aritomi ,  Yusuke Arashiro ,  Shinichi Yamauchi

发明人： Toru Tsukahara ,  Hiromi Nishimura ,  Mitsutoshi Aritomi ,  Yusuke Arashiro ,  Shinichi Yamauchi

IPC分类号： C08G65/44 ,  C08G65/48 ,  C08L51/06 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L81/00 ,  C08G65/38

CPC分类号： C08L51/06 ,  C08G65/44 ,  C08G65/485 ,  C08L71/123 ,  C08L71/126 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L81/00

摘要： A hydroxy-substituted poly(phenylene ether) resin can be produced by copolymerizing from 1.5 to 8 mol % of a phenol compound selected from those represented by the following formulae (a), (b), (c), (d), and (e): ##STR1## and from 98.5 to 92 mol % of a phenol compound of the following formula (f): ##STR2## The hydroxy-substituted poly(phenylene ether) resin shows excellent compatibility with a polyamide, a polycarbonate, a poly(butylene terephthalate), a poly(phenylene sulfide), and is useful as a copatibilizer or a modified resin for engineering plastics.

公开(公告)号：US5424359A

公开(公告)日：1995-06-13

申请号：US201008

申请日：1994-02-24

申请人： Yusuke Arashiro ,  Yoshio Katoh ,  Keiko Matsuhisa ,  Mitsutoshi Aritomi

发明人： Yusuke Arashiro ,  Yoshio Katoh ,  Keiko Matsuhisa ,  Mitsutoshi Aritomi

IPC分类号： C08F255/00 ,  C08L51/06 ,  C08L67/02

CPC分类号： C08L51/06 ,  C08F255/00 ,  C08L67/02

摘要： Disclosed is a thermoplastic resin composition comprising(A) 90 to 10% by weight of a modified polyolefin type resin obtained by subjecting 100 parts by weight of a polyolefin type resin to graft polymerization with 0.01 to 20 parts by weight of an .alpha.,.beta.-unsaturated carboxylate having a hydroxyl group and 0.01 to 50 parts by weight of an aromatic vinyl compound; and(B) 10 to 90% by weight of a saturated polyester.

摘要翻译： 公开了一种热塑性树脂组合物，其包含（A）90至10重量％的改性聚烯烃类树脂，其通过使100重量份的聚烯烃类树脂与0.01至20重量份的α，β- 具有羟基的不饱和羧酸酯和0.01〜50重量份的芳族乙烯基化合物; 和（B）10〜90重量％的饱和聚酯。

公开(公告)号：US5360866A

公开(公告)日：1994-11-01

申请号：US49599

申请日：1993-04-20

申请人： Yusuke Arashiro ,  Michiharu Kihara ,  Haruo Ohmura ,  Fumiyoshi Yamada

发明人： Yusuke Arashiro ,  Michiharu Kihara ,  Haruo Ohmura ,  Fumiyoshi Yamada

IPC分类号： C08G65/48 ,  C08L63/00 ,  C08L67/00 ,  C08L71/12 ,  C08F255/02

CPC分类号： C08G65/485 ,  C08L71/126 ,  C08L63/00 ,  C08L67/00 ,  Y10S525/905

摘要： A thermoplastic resin composition comprising (A) from about 10 to about 90% by weight of a hydroxyalkylated polyphenylene ether represented by formula (I): ##STR1## wherein A represents a residue of a polyphenylene ether from which a hydroxyl group is removed; and n represents an integer of from 1 to 10, and (B) from about 10 to about 90% by weight of a resin selected from a carboxyl-containing olefin resin, an epoxy-containing olefin resin, a hydroxyl-containing olefin resin, a polyamide resin, and a saturated polyester resin, provided that when (B) is the olefin resin, the hydroxyalkylated polyphenylene ether also can be represented by formula (II): ##STR2## wherein A is defined as above; X represents an oxygen atom or a nitrogen atom; R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from 1 to 3.

摘要翻译： 一种热塑性树脂组合物，其包含（A）约10至约90重量％的由式（I）表示的羟烷基化聚苯醚：其中A表示羟基的聚亚苯基醚的残基 删除 和n表示1〜10的整数，（B）约10〜约90重量％的选自含羧基的烯烃树脂，含环氧基的烯烃树脂，含羟基的烯烃树脂， 聚酰胺树脂和饱和聚酯树脂，只要（B）为烯烃树脂，羟基烷基化聚苯醚也可以由式（II）表示：其中A定义如上。 X表示氧原子或氮原子; R1表示碳原子数1〜12的亚烷基。 R2和R3各自表示具有1至6个碳原子的烃基; 当X为氧原子时，s表示1，X表示氮原子时表示2。 t表示1〜3的整数。

公开(公告)号：US5242990A

公开(公告)日：1993-09-07

申请号：US744129

申请日：1991-08-13

申请人： Yusuke Arashiro ,  Haruo Ohmura ,  Michiharu Kihira

发明人： Yusuke Arashiro ,  Haruo Ohmura ,  Michiharu Kihira

IPC分类号： C08G65/48 ,  C08L67/00 ,  C08L71/12 ,  C08L75/00 ,  C08L77/00 ,  C08L81/02

CPC分类号： C08L71/126 ,  C08G65/485 ,  C08L81/02 ,  C08L67/00 ,  C08L71/12 ,  C08L75/00 ,  C08L77/00 ,  Y10S525/905

摘要： A thermoplastic resin composition comprising (a) from 10 to 90% by weight of polyphenylene sulfide and (b) from 10 to 90% by weight of hydroxyalkylated polyphenylene ether which exhibits improved compatibility between components (a) and (b) and provides molded articles having characteristics inherent to polyphenylene sulfide and polyphenylene ether, i.e., excellent mechanical strength, excellent rigidity, and good appearance.

公开(公告)号：US5420184A

公开(公告)日：1995-05-30

申请号：US135970

申请日：1993-10-14

申请人： Toru Tsukahara ,  Hiromi Nishimura ,  Yusuke Arashiro ,  Kiyoji Takagi ,  Koji Nishida

发明人： Toru Tsukahara ,  Hiromi Nishimura ,  Yusuke Arashiro ,  Kiyoji Takagi ,  Koji Nishida

IPC分类号： C08K5/527 ,  C08L67/00 ,  C08L67/02 ,  C08L71/12

CPC分类号： C08K5/527 ,  C08L67/02 ,  C08L71/12 ,  C08L67/00

摘要： Disclosed are a thermoplastic resin composition which comprises(A) 10 to 90% by weight of a polyphenylene ether,(B) 90 to 10% by weight of a saturated polyester,(C) 0.1 to 10 parts by weight of an organic phosphorous acid compound represented by the formula: ##STR1## wherein n represents 1 or 2; Ar represents an aryl group having 6 to 30 carbon atoms or a substituted aryl group and when n is 2, Ars may be the same or different; and R represents an alkylene group having 2 to 18 carbon atoms or arylene group when n is 1 and represents an alkanetetrayl group having 4 to 18 carbon atoms when n is 2, based on 100 parts by weight of Components (A) and (B) , and(D) 0 to 10 parts by weight of an acid receptor based on 100 parts by weight of Components (A) and (B),and a process for preparing the same.

摘要翻译： 公开了一种热塑性树脂组合物，其包含（A）10〜90重量％的聚苯醚，（B）90〜10重量％的饱和聚酯，（C）0.1〜10重量份的有机亚磷酸 由下式表示的化合物：其中n表示1或2; Ar表示碳原子数为6〜30的芳基或取代芳基，n为2时，Ar可以相同或不同， 当n为1时，R表示碳原子数为2〜18的亚烷基或n为2时的亚芳基，n为2时，表示碳原子数为4〜18的烷基醚基，基于100重量份的成分（A）和（B） 和（D）基于100重量份组分（A）和（B）的0至10重量份的酸受体及其制备方法。

公开(公告)号：US5244983A

公开(公告)日：1993-09-14

申请号：US732004

申请日：1991-07-18

申请人： Yusuke Arashiro ,  Michiharu Kihira ,  Haruo Ohmura ,  Shinichi Yamauchi

发明人： Yusuke Arashiro ,  Michiharu Kihira ,  Haruo Ohmura ,  Shinichi Yamauchi

IPC分类号： C08G65/48 ,  C08L63/00 ,  C08L67/00 ,  C08L71/12

CPC分类号： C08G65/485 ,  C08L71/126 ,  C08L63/00 ,  C08L67/00 ,  Y10S525/905

摘要： A thermoplastic resin composition comprising (A) from about 10 to about 90% by weight of a hydroxyalkylated polyphenylene ether represented by formula (I): ##STR1## wherein A represents a residue of a polyphenylene ether from which a hydroxyl group is removed; and n represents an integer of from 1 to 10,and (B) from about 10 to about 90% by weight of a resin selected from a carboxyl-containing olefin resin, an epoxy-containing olefin resin, a hydroxyl-containing olefin resin, a polyamide resin, and a saturated polyester resin, provided that when (B) is the olefin resin, the hydroxyalkylated polyphenylene ether also can be represented by formula (II): ##STR2## werein A is defined as above; X represents an oxygen atom or a nitrogen atom; R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from 1 to 3.

公开(公告)号：US4764559A

公开(公告)日：1988-08-16

申请号：US120838

申请日：1987-11-16

申请人： Shin-ichi Yamauchi ,  Yusuke Arashiro ,  Kenyu Ohno

发明人： Shin-ichi Yamauchi ,  Yusuke Arashiro ,  Kenyu Ohno

IPC分类号： C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L25/06 ,  C08L53/00 ,  C08L53/02 ,  C08L71/00 ,  C08L71/12 ,  C08L71/04

CPC分类号： C08L53/025 ,  C08L23/10 ,  C08L23/12 ,  C08L53/02 ,  C08L71/123 ,  C08L2205/03 ,  C08L2205/035 ,  C08L23/142 ,  C08L25/06 ,  C08L53/00 ,  C08L71/12 ,  Y10S525/905

摘要： A resin composition is described, comprising (a) a polyphenylene ether resin having a low degree of polymerization or a mixture thereof with a styrene resin, (b) a polyolefin resin, and (c) a styrene compound/conjugated diene block copolymer or a hydrogenation product thereof at a specific compounding ratio. The composition is excellent in melt processability, stiffness at elevated temperatures, and impact strength.

公开(公告)号：US5202409A

公开(公告)日：1993-04-13

申请号：US799967

申请日：1991-11-29

申请人： Toru Tsukahara ,  Mitsutoshi Aritomi ,  Yusuke Arashiro ,  Shinichi Yamauchi ,  Hiromi Nishimura

发明人： Toru Tsukahara ,  Mitsutoshi Aritomi ,  Yusuke Arashiro ,  Shinichi Yamauchi ,  Hiromi Nishimura

IPC分类号： C08G65/44 ,  C08L51/06 ,  C08L63/00 ,  C08L71/12

CPC分类号： C08L51/06 ,  C08G65/44 ,  C08L71/126 ,  C08L63/00 ,  Y10S525/905

摘要： Disclosed is a process for preparing a polyhydroxyphenylene ether resin which comprises copolymerizing a phenol-substituted compound having hydroxyl group as a substituent, represented by the formula (I): ##STR1## wherein m and n each represents an integer satisfying the formulae 1.ltoreq.m and m+n.ltoreq.4; J represents {(HO).sub.a --R.sup.1 --S}.sub.b --R.sup.2 -- where a and b each represents an integer of 1 to 6; and R.sup.1 and R.sup.2 each represents unsubstituted or halogen-substituted alkylene, alkenylene or arylene, or alkylene; K represents halogen, primary or secondary alkyl, alkenyl, phenyl, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy;with at least one phenol-substituted compound represented by the formula (II): ##STR2## wherein Qs each represents hydrogen, halogen, primary or secondary alkyl, alkenyl, aromatic, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy,and a resin composition containing the polyhydroxyphenylene ether resin prepared by the above method.

公开(公告)号：US5177156A

公开(公告)日：1993-01-05

申请号：US701910

申请日：1991-05-17

申请人： Mitsutoshi Aritomi ,  Haruo Ohmura ,  Hiroshi Nakano ,  Michiharu Kihira ,  Yusuke Arashiro ,  Fumiyoshi Yamada ,  Shinako Mori ,  Fumiyo Ikehata

发明人： Mitsutoshi Aritomi ,  Haruo Ohmura ,  Hiroshi Nakano ,  Michiharu Kihira ,  Yusuke Arashiro ,  Fumiyoshi Yamada ,  Shinako Mori ,  Fumiyo Ikehata

IPC分类号： C08G65/48 ,  C08L67/00 ,  C08L71/12 ,  C08L77/00

CPC分类号： C08G65/485 ,  C08L71/126 ,  C08L67/00 ,  C08L77/00

摘要： A process for producing a terminal-modified polyphenylene ether represented by formula (III): ##STR1## wherein Q.sup.1 represents a halogen atom, a primary of secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; Q.sup.2 represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; n represents an integer of at least 10; X represents an oxygen atom or a nitrogen atom;R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from from 1 to 3,which comprises reacting a polyphenylene ether represented by formula (I): ##STR2## wherein Q.sup.1, Q.sup.2, and n are as defined above, with a compound represented by formula (II): ##STR3## wherein X, R.sup.1, R.sup.2, R.sup.3, s, and t are as defined above; a process for producing an alkoxysilylated polyphenylene ether represented by formula (V): ##STR4## wherein Q.sup.1, Q.sup.2, and n are as defined above; R.sup.11 represents a bond or an alkylene group having from 1 to 12 carbon atoms; R.sup.12 and R.sup.13 each represents a hydrocarbon group having from 1 to 6 carbon atoms; and m represents an integer of from 1 to 3, which comprises reacting a polyphenylene ether represented by formula (I) shown above with a compound represented by formula (IV): ##STR5## wherein R.sup.11, R.sup.12, R.sup.13, and m are as defined above; and Y represents a halogen atom;and a thermoplastic resin composition comprising the modified polyphenylene ether of formula (III) or (IV) with a saturated polyester, a polyamide, or a modified olefin resin.

公开(公告)号：US5134194A

公开(公告)日：1992-07-28

申请号：US644564

申请日：1991-01-23

申请人： Takayuki Inoue ,  Yusuke Arashiro ,  Shin-ichi Yamauchi ,  Michiharu Kihira ,  Haruo Ohmura ,  Fumiyoshi Yamada

发明人： Takayuki Inoue ,  Yusuke Arashiro ,  Shin-ichi Yamauchi ,  Michiharu Kihira ,  Haruo Ohmura ,  Fumiyoshi Yamada

IPC分类号： C08G65/48 ,  C08L43/04 ,  C08L51/06 ,  C08L67/02 ,  C08L69/00 ,  C08L71/12

CPC分类号： C08L69/00 ,  C08G65/485 ,  C08L43/04 ,  C08L51/06 ,  C08L67/02 ,  C08L71/12 ,  C08L71/126

摘要： Thermoplastic resin composition comprising the following components A and B is presented which improves the compatibility of component resins, to achieve a thermoplastic resin having excellent molding property and mechanical strength:A. 90 to 10 wt % of a polyolefin resin containing a substituted silyl group represented by general formula;--SiR.sub.n Y.sub.3-n (wherein, R is aliphatic hydrocarbon group; Y is hydrolyzable group or hydroxyl group; n represents 0, 1 or 2), andB. 10 to 90 wt % of saturated polyester resin or hydroxyalkylated polycarbonate resin or hydroxyalkylated polyphenylene ether resin.