Cyclohexenone oxime ethers
    3.
    发明授权
    Cyclohexenone oxime ethers 失效
    环己烯酮肟醚

    公开(公告)号:US5604183A

    公开(公告)日:1997-02-18

    申请号:US523682

    申请日:1995-09-05

    摘要: Cyclohexenone oxime ethers I ##STR1## where n is from 0 to 5, m is from 0 to 2, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or benzyl, A is unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkenylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene or an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene or C.sub.4 -C.sub.6 -alkenylene chain, where in each case a methylene group may be replaced with O, S, SO, SO.sub.2 or --N(R.sup.a)--, R.sup.a is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, Z is phenyl, a 5-membered heteroaromatic radical or a 6-membered heteroaromatic radical having from 1 to 4 nitrogen atoms, X is NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkoxy, COOH, C.sub.1 -C.sub.4 -alkoxycarbonyl, unsubstituted or substituted benzyloxycarbonyl, unsubstituted or substituted phenyl, unsubstituted or substituted pyridyl or --NR.sup.b R.sup.c, R.sup.b is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl and R.sup.c is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl, and the agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids are suitable as herbicides.

    摘要翻译: 环己烯酮肟醚I其中n为0至5,m为0至2,R 1为C 1 -C 6烷基,R 2为C 1 -C 4 - 烷基或苄基,A为未取代或取代的C 1 -C 6 - 亚烷基,未取代或取代的C 3 -C 6亚烯基,未取代或取代的C 3 -C 6亚炔基或未取代或取代的C 3 -C 6亚烷基或C 4 -C 6亚烯基链,其中在每种情况下亚甲基可以被O, S,SO,SO2或-N(Ra) - ,Ra是H,C1-C4-烷基,C3-C6-烯基或C3-C6-炔基,Z是苯基,5元杂芳族基团或6元 具有1至4个氮原子的杂芳族基团,X是NO 2,CN,卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,COOH, C 1 -C 4烷氧基羰基,未取代或取代的苄氧基羰基,未取代或取代的苯基,未取代或取代的吡啶基或-NRbRc,Rb是H,C1-C4-烷基,C3-C6-烯基或C3-C6-炔基,Rc是H, C 1 -C 4 - 烷基,C 3 -C 6 - 烯基,C 3 -C 6炔基,C 1 -C 6 - 酰基或不饱和的 取代或取代的苯甲酰基,C1-C10-羧酸和无机酸的农业上有用的盐和酯适合作为除草剂。

    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and
intermediates for their preparation
    7.
    发明授权
    3-(Het)aryloxy(thio)carboxylic acid derivatives, their preparation and intermediates for their preparation 失效
    3-(Het)芳氧基(硫代)羧酸衍生物,其制备方法及其制备中间体

    公开(公告)号:US5661106A

    公开(公告)日:1997-08-26

    申请号:US537759

    申请日:1995-10-19

    摘要: 3-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I ##STR1## where R.sup.1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH;R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen;R.sup.4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted;an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted;R.sup.5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl, each of which is unsubstituted or substituted;R.sup.6 is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;Y is sulfur or oxygen or a single bond; andZ is sulfur or oxygen.

    摘要翻译: PCT No.PCT / EP94 / 01156 Sec。 371 1995年10月19日日期 102(e)1995年10月19日PCT PCT 1994年4月14日PCT公布。 WO94 / 25443 PCT出版物 日期:1943年11月10日 - (Het)式I的芳氧基(硫代)羧酸衍生物其中R 1是氢,COOH或可被水解得到COOH的基团; R2和R3各自为卤素,烷基,卤代烷基,烷氧基,卤代烷氧基或烷硫基; X是氮或CR 14,其中R 14是氢或与R 3一起形成3元或4元亚烷基或亚烯基链,其中亚甲基被氧代替; R4是烷基,环烷基,环烯基,烯基或炔基,其各自为未取代或取代的; 含有一至三个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; 未取代或取代的苯基或萘基; R 4和R 5与相邻的碳原子一起形成可含有氧或硫原子且未被取代或取代的3元至8元环; R5是氢,烷基,烯基,炔基,环烷基,卤代烷基,烷氧基烷基,烷硫基烷基或苯基,各自为未取代或取代的; R6是未取代或取代的苯基或萘基或含1-3个氮原子或一个硫或氧原子的未取代或取代的五元或六元杂芳族结构; Y是硫或氧或单键; Z是硫或氧。