NOVEL SHEAR-RESISTANT POLYMER SYSTEMS, PRODUCTION THEREOF, AND ALSO USE THEREOF AS THICKENERS
    6.
    发明申请
    NOVEL SHEAR-RESISTANT POLYMER SYSTEMS, PRODUCTION THEREOF, AND ALSO USE THEREOF AS THICKENERS 审中-公开
    新型耐磨聚合物系统,其生产,并且还作为更大的使用者

    公开(公告)号:US20140350205A1

    公开(公告)日:2014-11-27

    申请号:US14115539

    申请日:2012-05-02

    IPC分类号: C08F220/58

    摘要: The present invention relates to thickener polymers which comprise the following structural elements 1-3: a) as structural feature 1 at least one betainic monomer unit according to the formula below with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are as follows: m=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R3=n- or isoalkylene of the formula —(CxH2x)—, in which x is an integer from 1 to 30; R4=—H, cycloalkyl, n- or isoalkyl, aryl; R5=n- or isoalkylene of the formula —(CyH2y)—, in which y is an integer from 1 to 30; A=—S—, —O—, —NR2, in which R2═H, C1-3 alkyl; b) as structural feature 2 at least one anionically charged monomer unit according to the following formula with a proportion by weight of from 0.1 to 99.9% by weight, based on the copolymer in which the mutually independent definitions are: l=integer≧1; R1═H, C1-3 alkyl, —COOH; R2═H, C1-3 alkyl; R6=—OH, —OOH, —SH, —(CxH2x)—COOH, —(CxH2x)—SO3H, —N (R2)—(CxH2x)—SO3H, in which —(CxH2x)—=n- or isoalkylene and x is an integer from 1 to 30; c) optionally as structural feature 3 one or more non-ionic comonomer units with a proportion by weight of from 0 to 50% by weight, based on the copolymer. When compared with the prior art, the thickener polymers have increased shear resistance in aqueous formulations.

    摘要翻译: 本发明涉及包含以下结构单元1-3的增稠剂聚合物:a)作为结构特征1,根据下式的至少一种甜菜碱单体单元,其重量比为0.1至99.9重量%,基于 其中相互独立定义的共聚物如下:m =整数≧1; R1 = H,C1-3烷基,-COOH; R2 = H,C1-3烷基; R3 =式 - (CxH2x) - 的n-或异亚烷基,其中x为1至30的整数; R4 = -H,环烷基,正或异烷基,芳基; R5 =式 - (CyH2y) - 的n-或异亚烷基,其中y为1至30的整数; A = -S-,-O-,-NR2,其中R2 = H,C1-3烷基; b)结构特征2至少一个根据下式的阴离子带电单体单元,其重量比为0.1至99.9重量%,基于相互独立定义的共聚物:l =整数≥1; R1 = H,C1-3烷基,-COOH; R2 = H,C1-3烷基; R6 = -OH,-OOH,-SH, - (CxH2x)-COOH, - (CxH2x)-SO3H,-N(R2) - (CxH2x)-SO3H,其中 - (CxH2x) - = x是1至30的整数; c)任选地作为结构特征3一种或多种基于共聚物的重量比为0至50重量%的非离子共聚单体单元。 当与现有技术相比时,增稠剂聚合物在水性配方中具有增加的抗剪切性。

    Soil release oligoesters
    9.
    发明授权
    Soil release oligoesters 有权
    土壤释放低聚物

    公开(公告)号:US6153723A

    公开(公告)日:2000-11-28

    申请号:US330103

    申请日:1999-06-10

    摘要: The invention relates to oligoesters obtained by polycondensation ofa) from 40 to 52 mol %, preferably from 45 to 50 mol %, of one or more dicarboxylic acids or esters thereof,b) from 10 to 40 mol %, preferably from 20 to 35 mol %, of ethylene glycol and/or propylene glycol,c) from 3 to 20 mol %, preferably from 10 to 15 mol %, of polyethylene glycol,d) from 0.5 to 10 mol %, preferably from 1 to 7.5 mol %, of a water-soluble addition product of from 5 to 80 mol of an alkylene oxide with 1 mol of C.sub.1 -C.sub.24 -alcohols, C.sub.6 -C.sub.18 -alkylphenols or C.sub.8 -C.sub.24 -alkylamines ande) from 0.4 to 10 mol %, preferably from 0.5 to 8 mol %, of one or more polyols having from 3 to 6 hydroxyl groups.These oligoesters are used as soil release polymers in detergents.

    摘要翻译: 本发明涉及通过a)从40至52mol%,优选45至50mol%的一种或多种二羧酸或其酯的缩聚获得的低聚酯,b)10至40mol%,优选20至35 mol%的乙二醇和/或丙二醇,c)3至20mol%,优选10至15mol%的聚乙二醇,d)0.5至10mol%,优选1至7.5mol% 的5至80摩尔环氧烷与1摩尔C 1 -C 24醇,C 6 -C 18烷基酚或C 8 -C 24烷基胺的水溶性加成产物,e)为0.4至10摩尔%,优选为 0.5至8mol%的一种或多种具有3至6个羟基的多元醇。 这些低聚酯用作洗涤剂中的去污聚合物。