-
公开(公告)号:US06310163B1
公开(公告)日:2001-10-30
申请号:US08899002
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: C08F22010
CPC分类号: C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是关于它们的微观结构,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚法合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
-
公开(公告)号:US5880241A
公开(公告)日:1999-03-09
申请号:US590650
申请日:1996-01-24
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Steven Dale Ittel , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Steven Dale Ittel , Daniel Joseph Tempel
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是关于它们的微结构,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
-
公开(公告)号:US5866663A
公开(公告)日:1999-02-02
申请号:US891332
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
-
公开(公告)号:US6034259A
公开(公告)日:2000-03-07
申请号:US891398
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US06573353B1
公开(公告)日:2003-06-03
申请号:US09660578
申请日:2000-09-12
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Daniel Joseph Tempel
IPC分类号: C08F1006
CPC分类号: C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US5886224A
公开(公告)日:1999-03-23
申请号:US891403
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Samuel David Arthur , Jerald Feldman , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Samuel David Arthur , Jerald Feldman , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US5891963A
公开(公告)日:1999-04-06
申请号:US891442
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microsructure, which give some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是关于它们的微结构,其中给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US06894134B2
公开(公告)日:2005-05-17
申请号:US09887273
申请日:2001-06-22
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Samuel David Arthur
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Samuel David Arthur
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US06140439A
公开(公告)日:2000-10-31
申请号:US891405
申请日:1997-07-10
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US06710007B2
公开(公告)日:2004-03-23
申请号:US10057090
申请日:2002-01-25
申请人: Maurice S. Brookhart , Keith Kunitsky , Weijun Liu , Jon M. Malinoski , Lin Wang , Ying Wang , Lynda Kaye Johnson , Kristina A. Kreutzer , Steven Dale Ittel
发明人: Maurice S. Brookhart , Keith Kunitsky , Weijun Liu , Jon M. Malinoski , Lin Wang , Ying Wang , Lynda Kaye Johnson , Kristina A. Kreutzer , Steven Dale Ittel
IPC分类号: C08F444
CPC分类号: C07F15/04 , C07F15/006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F2500/02 , C08F220/10 , C08F2500/20 , C08F4/7014 , C08F4/80
摘要: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, &agr;-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.
摘要翻译: 当与过渡金属络合时,含有具有膦基,氨基或亚氨基的配体以及第二官能团如酰胺,酯或酮的某些络合物催化乙烯,α-烯烃等烯烃化合物的(共)聚合, 烯烃和/或丙烯酸酯。 描述了使用后期过渡金属络合物制备含极性单体的共聚物的新认可的一类配体。
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