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公开(公告)号：US5316992A
公开(公告)日：1994-05-31
申请号：US976158
申请日：1992-11-13
申请人： Michael B. Russ , Paul A. Sechrist
发明人： Michael B. Russ , Paul A. Sechrist
IPC分类号： B01J23/64 , B01J23/656 , B01J29/62 , B01J29/64 , B01J29/74 , C10G35/06 , C10G35/095 , B01J29/32 , B01J29/36
CPC分类号： C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要： A catalyst system comprises a physical mixture of a conversion catalyst and a sulfur sorbent to accommodate small quantities of sulfur from a hydrocarbon feedstock. Preferably, the physical mixture comprises a sulfur-sensitive reforming catalyst protected from sulfur deactivation by a manganeseoxide catalyst. The invention shows substantial benefits over prior-art processes in catalyst utilization.
摘要翻译： 催化剂体系包括转化催化剂和硫吸附剂的物理混合物以适应来自烃原料的少量硫。 优选地，物理混合物包含通过氧化锰氧化物催化剂保护硫失活的硫敏感的重整催化剂。 本发明显示出相对于现有技术中催化剂利用过程的优点。
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公开(公告)号：US5614082A
公开(公告)日：1997-03-25
申请号：US490037
申请日：1995-06-13
申请人： Michael B. Russ , Paul A. Sechrist
发明人： Michael B. Russ , Paul A. Sechrist
IPC分类号： B01J23/64 , B01J23/656 , B01J29/62 , B01J29/64 , B01J29/74 , C10G35/06 , C10G35/095
CPC分类号： C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要： A catalyst system comprises a physical mixture of a conversion catalyst and a sulfur sorbent to accommodate small quantities of sulfur from a hydrocarbon feedstock. Preferably, the physical mixture comprises a sulfur-sensitive reforming catalyst protected from sulfur deactivation by a manganese-oxide catalyst. The invention shows substantial benefits over prior-art processes in catalyst utilization.
摘要翻译： 催化剂体系包括转化催化剂和硫吸附剂的物理混合物以适应来自烃原料的少量硫。 优选地，物理混合物包含通过氧化锰催化剂保护硫失活的硫敏感的重整催化剂。 本发明显示出相对于现有技术中催化剂利用过程的优点。
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公开(公告)号：US5935415A
公开(公告)日：1999-08-10
申请号：US963693
申请日：1997-11-04
摘要： A hydrocarbon feedstock is catalytically reformed in a sequence comprising a continuous-reforming zone, consisting essentially of a moving-bed catalytic reforming zone and continuous regeneration of catalyst particles, and a zeolitic-reforming zone containing a catalyst comprising a platinum-group metal and a nonacidic zeolite. The process combination permits higher severity, higher aromatics yields and/or increased throughput in the continuous-reforming zone, thus showing surprising benefits over prior-art processes, and is particularly useful in upgrading existing moving-bed reforming facilities with continuous catalyst regeneration.
摘要翻译： 烃原料以包含连续重整区的顺序进行催化重整，所述连续重整区主要由移动床催化重整区和催化剂颗粒的连续再生组成，以及沸石重整区，其含有包含铂族金属和 非酸性沸石。 该方法组合允许在连续重整区域中更高的苛刻度，更高的芳族化合物产率和/或增加的通量，因此显示出比现有技术方法更令人惊奇的益处，并且特别适用于在连续催化剂再生的现有移动床重整设备的升级中。
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公开(公告)号：US5683573A
公开(公告)日：1997-11-04
申请号：US635857
申请日：1996-04-22
IPC分类号： C10G47/14 , C10G35/06 , C10G35/095 , C10G49/08 , C10G59/02
CPC分类号： C10G59/02 , C10G35/06 , C10G35/095
摘要： A hydrocarbon feedstock is catalytically reformed in a sequence comprising a continuous-reforming zone, consisting essentially of a moving-bed catalytic reforming zone and continuous regeneration of catalyst particles, and a zeolitic-reforming zone containing a catalyst comprising a platinum-group metal and a nonacidic zeolite. The process combination permits higher severity, higher aromatics yields and/or increased throughput in the continuous-reforming zone, thus showing surprising benefits over prior-art processes, and is particularly useful in upgrading existing moving-bed reforming facilities with continuous catalyst regeneration.
摘要翻译： 烃原料以包含连续重整区的顺序进行催化重整，所述连续重整区主要由移动床催化重整区和催化剂颗粒的连续再生组成，以及沸石重整区，其含有包含铂族金属和 非酸性沸石。 该方法组合允许在连续重整区域中更高的苛刻度，更高的芳族化合物产率和/或增加的通量，因此显示出比现有技术方法更令人惊奇的益处，并且特别适用于在连续催化剂再生的现有移动床重整设备的升级中。
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公开(公告)号：US5658453A
公开(公告)日：1997-08-19
申请号：US453604
申请日：1995-05-30
申请人： Michael B. Russ , Aaron P. Kelly , John Y. G. Park
发明人： Michael B. Russ , Aaron P. Kelly , John Y. G. Park
摘要： A process combination is disclosed to selectively upgrade naphtha in a manner to obtain an aromatics-rich, low-olefin product from the combination. Preferably the naphtha is subjected to aromatization to obtain an aromatics concentrate which is upgraded by hydrogenation of olefins in the aromatics-rich stream. Olefin saturation is effected following separation of the major portion of hydrogen from the aromatics concentrate and before fractionation/stabilization for removal of light ends, with concomitant low saturation of aromatics and with removal of light ends in a fractionator which would be associated with the aromatization in any case.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油，以从组合获得富含芳烃的低烯烃产物。 优选地，将石脑油进行芳构化以获得芳族化合物浓缩物，其通过在富含芳烃的流中的烯烃的氢化而提高。 在将主要部分的氢气与芳族化合物浓缩物分离并且在分馏/稳定化以除去轻馏分之前进行烯烃饱和，伴随着芳族化合物的低饱和度，并且在分馏塔中除去将与芳构化相关的轻馏分 任何情况。
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公开(公告)号：US5401388A
公开(公告)日：1995-03-28
申请号：US117466
申请日：1993-09-07
CPC分类号： C10G59/06
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a head-cut fraction to reforming, and a heavy potion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy potion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得符合目前重新配制的燃料标准的汽油。 将石脑油原料分馏以选择性地将轻石脑油引导至异构化或共混，将头馏分转化为重馏分，并将重质部分引入选择性异链烷烃合成以产生轻质和重质合成石脑油和异丁烷。 通过重整处理合成石脑油的重药剂。 轻石脑油可以异构化，有或没有产物的低辛烷值组分的再循环。 来自工艺组合的轻质，合成和重整产物的汽油组分混合。
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公开(公告)号：US5399257A
公开(公告)日：1995-03-21
申请号：US159643
申请日：1993-11-30
摘要： Hydrocarbon conversion processes having a susceptibility to coke formation on the internal surfaces of processing equipment are improved by inhibiting the formation of coke with the use of a glass bead treatment for the metal surfaces. After treating with ordinary glass bead cleaning methods, metal surfaces are found to inhibit coke formation. The glass bead treatment is easily performed and, therefore, offers advantages over other chemical treatments for the deposition of silica on reactor internals.
摘要翻译： 通过使用用于金属表面的玻璃珠处理来抑制焦炭的形成，改进了对加工设备的内表面上的焦炭形成敏感性的烃转化方法。 在用普通玻璃珠清洗方法处理后，发现金属表面抑制焦炭形成。 玻璃珠处理容易进行，因此与其他化学处理相比，在二氧化硅沉积在反应器内部件上的优点。
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公开(公告)号：US5389235A
公开(公告)日：1995-02-14
申请号：US984652
申请日：1992-12-02
IPC分类号： B01J8/02 , C10G35/095 , C10G61/06 , C10G35/04
CPC分类号： C10G35/095 , B01J8/0214 , C10G61/06
摘要： A combination downflow contaminant treatment and/or removal bed in combination with a radial flow bed of contaminant sensitive catalyst in a single reactor vessel eliminates unexpected deactivation of contaminant sensitive catalyst. The process of this invention also monitors the entrance of contaminants into the downflow contaminant treatment/removal bed to measure total contaminant loading to avoid unnecessary shut-downs of the reactor vessel during temporary contaminant loadings. This invention is particularly useful for highly sulfur sensitive reforming catalysts that are used in combination with a sulfur sorbent for removal of the sulfur contaminants.
摘要翻译： 在单个反应器容器中与污染物敏感催化剂的径向流动床组合的下流式污染物处理和/或去除床组合消除了污染物敏感催化剂的意外失活。 本发明的方法还监测污染物进入下流污染物处理/去除床中以测量总污染物负荷，以避免临时污染物装载期间反应容器的不必要的关闭。 本发明特别适用于与硫吸附剂组合用于除去硫污染物的高硫敏感性重整催化剂。
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9.发明授权Selective upgrading of naphtha fractions by a combination of reforming and selective isoparaffin synthesis 失效通过重组和选择性异链烷烃合成的组合选择性提升石脑油馏分
公开(公告)号：US5242576A
公开(公告)日：1993-09-07
申请号：US795573
申请日：1991-11-21
IPC分类号： C10G59/06
CPC分类号： C10G59/06
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a heart-cut fraction to reforming, and a heavy portion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy portion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得符合目前重新配制的燃料标准的汽油。 分馏石脑油原料以选择性地将轻质石脑油引导至异构化或共混，心切成分转化为重馏分，并将重质部分引导至选择性异链烷烃合成以产生轻质和重质合成石脑油和异丁烷。 合成石脑油的重质部分通过重整进行处理。 轻石脑油可以异构化，有或没有产物的低辛烷值组分的再循环。 来自工艺组合的轻质，合成和重整产物的汽油组分混合。
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公开(公告)号：US5108582A
公开(公告)日：1992-04-28
申请号：US709040
申请日：1991-06-03
IPC分类号： C10G35/04
CPC分类号： C10G35/04
摘要： An aromatic-hydrocarbon solvent is utilized to purge contaminants, such as sulfur, from a conversion system. Complementary contaminant-removal steps may include oxidation, reduction, and contaminant removal with a sacrificial particulate bed. This solvent purge avoids deactivation of a subsequently loaded contaminant-sensitive catalyst, such as a reforming catalyst selective for dehydrocyclization.
摘要翻译： 芳族烃溶剂用于从转化系统中清除污染物，如硫。 补充污染物去除步骤可包括用牺牲颗粒床除去氧化，还原和污染物。 这种溶剂吹扫避免了随后加载的污染物敏感催化剂的失活，例如对脱氢环化选择性的重整催化剂。
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