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公开(公告)号：US5103062A
公开(公告)日：1992-04-07
申请号：US36955
申请日：1987-04-10
IPC分类号： C08G65/32 , C07C209/16 , C08G65/28
CPC分类号： C07C209/16
摘要： In accordance with the process of the present invention normally liquid, water-soluble poly(oxyethylene/oxypropylene) polyamine products are prepared using an initiator, which may contain oxyethylene groups. In a series of alkoxylation reaction steps the initiator is reacted with predetermined weight percentages of ethylene oxide and propylene oxide, said process comprising the steps of:a. Charging a predetermined percentage of initiator to an alkoxylation reaction zone,b. Alkoxylating said initiator therein with predetermined percentages of ethylene oxide and propylene oxide to provide an intermediate polyol,c. Propoxylating said intermediate polyol with a predetermined percentage of propylene oxide to provide a normally liquid, water-soluble precursor polyol, andd. Catalytically reductively aminating said precursor polyol in the presence of a reductive amination catalyst in a reaction zone under reductive amination conditions in the presence of ammonia and hydrogen to provide said water-soluble poly(oxyethylene/oxypropylene) polyamine product.
摘要翻译： 根据本发明的方法，通常使用可含有氧乙烯基的引发剂来制备通常为水溶性的聚（氧乙烯/氧丙烯）多胺产物。 在一系列烷氧基化反应步骤中，引发剂与预定重量百分比的环氧乙烷和环氧丙烷反应，所述方法包括以下步骤：a。 将预定百分比的引发剂装入烷氧基化反应区，b。 用预定百分比的环氧乙烷和环氧丙烷对所述引发剂进行烷氧基化以提供中间体多元醇，c。 用预定百分比的环氧丙烷丙氧基化所述中间体多元醇以提供通常为液体的水溶性前体多元醇，和d。 在还原胺化条件下，在氨和氢的存在下，在还原胺化催化剂存在下，在反应区域催化还原胺化所述前体多元醇，以提供所述水溶性聚（氧乙烯/氧丙烯）多胺产物。
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公开(公告)号：US4539378A
公开(公告)日：1985-09-03
申请号：US654903
申请日：1984-09-27
IPC分类号： C08F283/00 , C08F283/06 , C08F283/10 , C08G18/00 , C08G18/63 , C08G65/32 , C08G18/14 , C08G18/67 , C08L71/02
CPC分类号： C08F283/10 , Y10S521/914
摘要： Vinyl polymer polyols made by polymerizing in situ via a free-radical mechanism one or more vinyl monomers in an epoxy resin-modified polyol are described. Preferably, styrene and acrylonitrile are copolymerized in a polyol made by adding epoxy resin to the alkoxylation of a polyol initiator having 3 to 4 hydroxyl groups. The vinyl polymer polyols of this invention give flexible polyurethane foams with greater load-bearing properties.
摘要翻译： 描述了通过自由基机理在环氧树脂改性的多元醇中原位聚合制备的一种或多种乙烯基单体制备的乙烯基聚合物多元醇。 优选地，苯乙烯和丙烯腈在通过添加环氧树脂制备的多元醇中共聚合到具有3至4个羟基的多元醇引发剂的烷氧基化。 本发明的乙烯基聚合物多元醇提供具有更大承载性能的柔性聚氨酯泡沫。
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公开(公告)号：US4539339A
公开(公告)日：1985-09-03
申请号：US654904
申请日：1984-09-27
CPC分类号： C08G18/632 , Y10S521/914
摘要： Polyurethane foams employing vinyl polymer polyols made by polymerizing in situ via a free-radical mechanism one or more vinyl monomers in an epoxy resin-modified polyol are described. Preferably, styrene and acrylonitrile are copolymerized in a polyol made by adding epoxy resin to the alkoxylation of a polyol initiator having 3 to 4 hydroxyl groups. The vinyl polymer polyols of this invention give flexible polyurethane foams with greater load-bearing properties.
摘要翻译： 描述了使用通过自由基机理原位聚合制备的乙烯基聚合物多元醇的聚氨酯泡沫，其中环氧树脂改性多元醇中的一种或多种乙烯基单体。 优选地，苯乙烯和丙烯腈在通过添加环氧树脂制备的多元醇中共聚合到具有3至4个羟基的多元醇引发剂的烷氧基化。 本发明的乙烯基聚合物多元醇提供具有更大承载性能的柔性聚氨酯泡沫。
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公开(公告)号：US4994621A
公开(公告)日：1991-02-19
申请号：US338664
申请日：1989-04-17
CPC分类号： C08C19/22 , C08C19/38 , C08G18/696
摘要： Aminated, alkoxylated hydroxyl-terminated polymers are made by a process involving first polymerizing one or more unsaturated hydrocarbons, such as butadiene, to form a liquid polymer. Next, the liquid polymer is provided with terminal hydroxyl groups. Then, the hydroxylated liquid polymer is alkoxylated with one or more alkylene oxides, such as ethylene oxide, propylene oxide, butylene oxide, and mixtures thereof, to provide secondary terminal hydroxyl groups. Finally, the alkoxylated liquid polymer is aminated over a transition metal oxide catalyst, such as a combination of nickel oxide/copper oxide/chromium oxide. If the alkoxylated, hydroxyl-terminated liquid polymer is terminated with primary hydroxyl groups, then the amination does not proceed well.
摘要翻译： 氨基化的，烷氧基化的羟基封端的聚合物通过包括首先聚合一种或多种不饱和烃如丁二烯以形成液体聚合物的方法制备。 接着，液态聚合物具有末端羟基。 然后，羟基化液体聚合物用一种或多种环氧烷，如环氧乙烷，环氧丙烷，环氧丁烷及其混合物进行烷氧基化，以提供次级末端羟基。 最后，将烷氧基化液体聚合物胺化成过渡金属氧化物催化剂，例如氧化镍/氧化铜/氧化铬的组合。 如果烷氧基化的羟基封端的液体聚合物用伯羟基封端，则胺化不能很好地进行。
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公开(公告)号：US4785026A
公开(公告)日：1988-11-15
申请号：US124665
申请日：1987-11-24
CPC分类号： C08G18/409 , C08G18/0876 , C08G18/3271 , C08G18/4072 , C08G18/4081
摘要： Polymer polyols with high polymer or solids content made by the reaction of alkanolamines with polyisocyanates in a dispersing media of polymer polyols created from vinyl monomers in a conventional manner. The equivalents of alkanolamine to equivalents of polyisocyanate ranges from about 1/1 to 5/1 to give novel polymer polyols with solid contents from about 25% to up to 50%. Polyurethane foams made employing the novel polymer polyols of the present invention have higher load bearing properties, and provide a good balance between the load bearing properties and the open cell content of the foam to provide a stable foam, as compared with those employing only conventional polymer polyols.
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6.发明授权Aromatic polyester polycarbonates from polyols derived from recycled polyethylene terephthalate 失效衍生自再生聚对苯二甲酸乙二醇酯的多元醇的芳族聚酯聚碳酸酯
公开(公告)号：US4468483A
公开(公告)日：1984-08-28
申请号：US491943
申请日：1983-05-05
CPC分类号： C08G18/44 , C08G18/6655 , C08G63/64
摘要： A novel class of aromatic polyester polycarbonates is described. The polycarbonates are made by reacting an alkylene carbonate with an aromatic polyester polyol over a polycarbonate formation catalyst such as potassium stannate. In turn, the polyol is made by esterifying a dibasic acid waste stream with an alkylene glycol to produce a polyester polyol which is subsequently used to transesterify recycled polyethylene terephthalate.
摘要翻译： 描述了一类新型的芳族聚酯聚碳酸酯。 聚碳酸酯通过碳酸亚烷基酯与芳族聚酯多元醇在聚碳酸酯形成催化剂如锡酸锡上反应制备。 反过来，多元醇通过用二亚烷基二醇酯化二元酸废物流来制备聚酯多元醇，随后用于酯化回收的聚对苯二甲酸乙二醇酯。
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公开(公告)号：US4439551A
公开(公告)日：1984-03-27
申请号：US476736
申请日：1983-03-18
CPC分类号： C08G18/4216 , C08G18/4213 , C08G18/6655 , C08G2101/005 , C08G2101/0075 , Y10S516/07
摘要： Economical, open-celled packaging foams of better quality than foams from commercial aromatic polyester polyols may be prepared with a novel polyol blend. The most important component in the polyol blend is an aromatic polyester polyol made from dibasic acid waste streams and recycled polyethylene terephthalate. This type of polyol made from waste or recycled reactant streams is economical to make and serves as an inexpensive substitute for a portion of more expensive amino polyols normally used.
摘要翻译： 可以使用新型多元醇混合物来制备比商业芳族聚酯多元醇泡沫更好质量的经济开放的开孔包装泡沫。 多元醇共混物中最重要的成分是由二元酸废物流和回收的聚对苯二甲酸乙二醇酯制成的芳族聚酯多元醇。 由废物或再循环的反应物流制成的这种类型的多元醇是经济的，并且用作通常使用的一部分更昂贵的氨基多元醇的廉价替代物。
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8.发明授权Fuels containing an alkenylsuccinyl polyglycolcarbonate ester as a deposit-control additive 失效含有烯基琥珀酰基聚乙二醇酯碳酸酯作为沉积物控制添加剂的燃料
公开(公告)号：US4490154A
公开(公告)日：1984-12-25
申请号：US496698
申请日：1983-05-20
CPC分类号： C10L1/1985
摘要： A fuel for internal combustion engines containing as a deposit-control additive at least one alkenylsuccinyl (polycarbonate-polyglycolethyleneoxy)-B-hydroxypropionate.
摘要翻译： 含有至少一种烯基琥珀酰基（聚碳酸酯 - 聚乙二醇乙烯基）-B-羟基丙酸酯作为沉积物控制添加剂的内燃机的燃料。
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9.发明授权Production of 2-substituted-1,3-dioxolanes from 1,3-dioxolane and formaldehyde 失效由1,3-二氧戊环和甲醛生产2-取代-1,3-二氧戊环
公开(公告)号：US4628108A
公开(公告)日：1986-12-09
申请号：US683548
申请日：1984-12-19
IPC分类号： C07D317/20 , C07D317/22 , C07D317/00
CPC分类号： C07D317/22 , C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of an organic peroxide and an ionizable, at least sparingly soluble metal salt, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes. 2-Hydroxyalkyl-1,3-dioxolanes are hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译： 根据本发明令人惊奇地发现，当1,3-二氧戊环与有机过氧化物和可电离的至少微溶的金属盐存在下，甲醛反应时，反应优先包括将甲醛加入到 1,3-二氧戊环的2-亚甲基与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1， 3-二氧戊环。 相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基烷基-1,3-二氧戊环水解。 二醇醛依次可以被催化氢化以形成额外量的乙二醇。
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公开(公告)号：US4049657A
公开(公告)日：1977-09-20
申请号：US583019
申请日：1975-06-02
IPC分类号： C07D295/12 , B01J27/00 , C07B61/00 , C07D295/023 , C07D295/13 , C07D241/00
CPC分类号： C07D295/023 , C07D295/13
摘要： An improved process for selectively preparing an N-(aminoalkyl)piperazine compound is disclosed wherein piperazine is contacted with a primary or secondary amino alkanol compound in the presence of a catalytically effective amount of a phosphorus-containing substance at a temperature of from about 250.degree. to about 350.degree. C under a pressure sufficient to maintain the mixture essentially in liquid phase and the N-(aminoalkyl)piperazine is then recovered from the resultant reaction mixture. In a preferred embodiment piperazine is contacted with monoethanolamine to produce N-(2-aminoethyl)-piperazine.
摘要翻译： 公开了一种用于选择性制备N-（氨基烷基）哌嗪化合物的改进方法，其中哌嗪在催化有效量的含磷物质存在下，在约250℃的温度下与伯或仲氨基烷醇化合物接触 至约350℃，压力足以使混合物基本保持液相，然后从所得反应混合物中回收N-（氨基烷基）哌嗪。 在优选的实施方案中，使哌嗪与单乙醇胺接触以产生N-（2-氨基乙基） - 哌嗪。
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