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1.发明授权公开(公告)号：US08466306B2
公开(公告)日：2013-06-18
申请号：US12812978
申请日：2009-01-09
IPC分类号： C07F9/02
CPC分类号： C07F9/5018
摘要： A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R1R2PR3—(SO3M)n, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.
摘要翻译： 包含式R 1 R 2 PR 3 - （SO 3 M）n的磺化二烃基（芳烷基）膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基，R 3是二价或多价芳基亚烷基，使得烷基部分 键合到磷原子上，芳基部分键合到烷基上并且也被一个或多个磺酸基团取代; M是一价阳离子，n在1至3的范围内。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一个或多个 更多相应的醛产品。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少，改进配体和过渡金属，例如铑，回收和回收。
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2.发明申请公开(公告)号：US20110054203A1
公开(公告)日：2011-03-03
申请号：US12812978
申请日：2009-01-09
CPC分类号： C07F9/5018
摘要： A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R1R2PR3—(SO3M)n, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.
摘要翻译： 包含式R 1 R 2 PR 3 - （SO 3 M）n的磺化二烃基（芳烷基）膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基，R 3是二价或多价芳基亚烷基，使得烷基部分 键合到磷原子上，芳基部分键合到烷基上并且也被一个或多个磺酸基团取代; M是一价阳离子，n在1至3的范围内。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一个或多个 更多相应的醛产品。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少，改进配体和过渡金属，例如铑，回收和回收。
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公开(公告)号：US20140316148A1
公开(公告)日：2014-10-23
申请号：US14007534
申请日：2012-02-22
IPC分类号： C07C41/01 , C07C43/13 , C07D307/20
CPC分类号： C07C41/01 , C07C43/13 , C07D307/12 , C07D307/20
摘要： Polyol ether compounds and processes for their preparation. A representative process comprises melting a polyol, and reacting the molten polyol, a carbonyl compound, and hydrogen in the presence of a hydrogenation catalyst to provide the poly of ether. The polyol ether has surfactant properties.
摘要翻译： 多元醇醚化合物及其制备方法。 代表性的方法包括熔融多元醇，并在氢化催化剂存在下使熔融的多元醇，羰基化合物和氢反应以提供聚醚。 多元醇醚具有表面活性剂性质。
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公开(公告)号：US08829229B2
公开(公告)日：2014-09-09
申请号：US12543751
申请日：2009-08-19
IPC分类号： C07C67/08 , C07C41/01 , C07C43/13 , C07C69/708 , C07C67/31
CPC分类号： C07C69/708 , C07C41/01 , C07C67/08 , C07C67/31 , C07C2601/14 , C07C43/13 , C07C43/135 , C07C43/1785
摘要： New polyol ether compounds and a process for their preparation. The process comprises reacting a polyol, a carbonyl compound, and hydrogen in the presence of hydrogenation catalyst, to provide the polyol ether. The molar ratio of polyol to carbonyl compound in the process is greater than 5:1.
摘要翻译： 新型多元醇醚化合物及其制备方法。 该方法包括在氢化催化剂存在下使多元醇，羰基化合物和氢反应，得到多元醇醚。 该过程中多元醇与羰基化合物的摩尔比大于5：1。
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公开(公告)号：US08722944B2
公开(公告)日：2014-05-13
申请号：US12430171
申请日：2009-04-27
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/12
摘要： The invention relates to processes for the etherification of olefins with alcohols. According to one aspect, a heterogeneous etherification catalyst is used under conditions that permit limiting the contact time between the desired product and the catalyst, thereby mitigation reverse reactions. According to a second aspect, a recycling process is used that significantly increases the yield of desired product.
摘要翻译： 本发明涉及烯烃与醇醚化的方法。 根据一个方面，在允许限制所需产物和催化剂之间的接触时间的条件下使用异相醚化催化剂，从而减轻逆向反应。 根据第二方面，使用显着增加所需产物的产率的再循环方法。
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6.发明授权Sulfonated organophosphine compounds and use thereof in hydroformylation processes 有权磺化有机膦化合物及其在加氢甲酰化方法中的应用公开(公告)号：US08461366B2
公开(公告)日：2013-06-11
申请号：US12812981
申请日：2009-01-09
IPC分类号： C07C303/00 , C07F17/02 , C07F15/00
CPC分类号： B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
摘要： A compound comprising a class of sulfonated triorganophosphine compounds of formula R1R2P—R3[—O—(CH2)n—(SO3M)]m, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
摘要翻译： 包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示 通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。 该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和铑的回收和再循环。
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公开(公告)号：US20150005225A1
公开(公告)日：2015-01-01
申请号：US14345347
申请日：2012-09-11
申请人： Michael L. Tulchinsky , Wanglin Yu , Sze S. Ng , Cynthia L. Rand
发明人： Michael L. Tulchinsky , Wanglin Yu , Sze S. Ng , Cynthia L. Rand
CPC分类号： C11D7/263 , C11D1/72 , C11D7/06 , C11D7/3218
摘要： Provided is a surfactant composition comprising an oligoglycerol compound of formula I, wherein R and m are as defined above. The compounds exhibit favorable surfactancy properties. Advantageously, the compounds may be prepared from renewable materials.
摘要翻译： 提供了包含式I的低聚甘油化合物的表面活性剂组合物，其中R和m如上所定义。 该化合物表现出有利的表面活性。 有利地，化合物可以由可再生材料制备。
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公开(公告)号：US20130046065A1
公开(公告)日：2013-02-21
申请号：US13643321
申请日：2011-04-21
IPC分类号： C07C47/445 , C08G8/32 , C08G8/04
CPC分类号： C07C261/02 , C07C39/17 , C07C2603/68 , C07C2603/91
摘要： Embodiments of the present disclosure include polycyclopentadiene compounds represented by Formula (I): in which each X is either a hydrogen or a cyano group (N≡C—), n has an average value from zero to 20; each m independently has a value of zero to 3; p has a value of zero to 20; each R is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; and each Q is independently hydrogen or an alkyl group containing 1 to 6 carbon atoms. Embodiments of the present disclosure also include a curable composition that includes the polycyclopentadiene compound(s) of Formula (I) and a curing amount of a resin or a catalyst amount of a catalyst and/or a cure accelerating amount of an accelerating agent.
摘要翻译： 本公开的实施方案包括由式（I）表示的聚环戊二烯化合物：其中每个X为氢或氰基（N≡C-），n的平均值为0至20; 每个m独立地具有零到3的值; p的值为零到20; 每个R独立地是卤素，腈基，硝基，烷基，烷氧基，烯基或烯氧基，其中烷基，烷氧基，烯基和烯氧基各自 独立地含有1至6个碳原子; 并且每个Q独立地是氢或含有1至6个碳原子的烷基。 本公开的实施方案还包括包含式（I）的聚环戊二烯化合物和树脂的固化量或催化剂的催化剂量和/或加速剂的固化促进量的可固化组合物。
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公开(公告)号：US20090281359A1
公开(公告)日：2009-11-12
申请号：US12430171
申请日：2009-04-27
IPC分类号： C07C41/06
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/12
摘要： The invention relates to processes for the etherification of olefins with alcohols. According to one aspect, a heterogeneous etherification catalyst is used under conditions that permit limiting the contact time between the desired product and the catalyst, thereby mitigation reverse reactions. According to a second aspect, a recycling process is used that significantly increases the yield of desired product.
摘要翻译： 本发明涉及烯烃与醇醚化的方法。 根据一个方面，在允许限制所需产物和催化剂之间的接触时间的条件下使用异相醚化催化剂，从而减轻逆向反应。 根据第二方面，使用显着增加所需产物的产率的再循环方法。
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公开(公告)号：US09233908B2
公开(公告)日：2016-01-12
申请号：US13383361
申请日：2010-07-30
申请人： Abraham D. Schuitman , Shawn D. Feist , Barry B. Fish , Daniel A. Hickman , Erich J. Molitor , Michael L. Tulchinsky
发明人： Abraham D. Schuitman , Shawn D. Feist , Barry B. Fish , Daniel A. Hickman , Erich J. Molitor , Michael L. Tulchinsky
IPC分类号： C07C209/00 , C07C209/48 , C07C209/26
CPC分类号： C07C209/48 , C07C209/26 , C07C2601/14 , C07C211/18
摘要： The instant invention provides cycloaliphatic diamines and a method of making the same. The cycloaliphatic diamines according to the instant invention comprise the reaction product of one or more cycloaliphatic cyanoaldehydes selected from the group consisting of 1,3-cyanocyclohexane carboxaldehyde, 1,4-cyanocyclohexane carboxaldehyde, mixtures thereof, and combinations thereof, hydrogen, and ammonia fed into a continuous reductive amination reactor system; wherein the one or more cycloaliphatic cyanoaldehydes, hydrogen, and ammonia are contacted with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature in the range of from 80° C. to about 160° C. and a pressure in the range of from 700 to 3500 psig; and wherein one or more cycloaliphatic diamines are formed; and wherein said one or more cycloaliphatic diamines are selected from the group consisting of 1,3-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, combinations thereof, and mixtures thereof.
摘要翻译： 本发明提供脂环族二胺及其制备方法。 根据本发明的脂环族二胺包括一种或多种选自1,3-氰基环己烷甲醛，1,4-氰基环己烷甲醛，其混合物及其组合的脂环族氰醛的反应产物，氢和氨进料 成为连续还原胺化反应器系统; 其中所述一种或多种环脂族氰醛，氢和氨在一种或多种非均相金属基催化剂体系的存在下在80℃至约160℃的温度下彼此接触，并且压力 在700至3500psig范围内; 并且其中形成一种或多种脂环族二胺; 并且其中所述一种或多种脂环族二胺选自1,3-双（氨基甲基）环己烷，1,4-双（氨基甲基）环己烷，其组合，及其混合物。
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