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公开(公告)号：US09371345B2
公开(公告)日：2016-06-21
申请号：US14730623
申请日：2015-06-04
Applicant: Apeiron Synthesis S.A.
Inventor： Krzysztof Skowerski , Lukasz Gulajski , Michal Bieniek , Stefan Czarnocki , Grzegorz Szczpaniak , Celina Wierzbicka
IPC: C07F15/00 , B01J31/22 , C07C209/68 , C07D307/28 , C07C29/32 , C07C29/56 , C07C67/333 , C08G61/08
CPC classification number: C07F15/0046 , B01J31/2204 , B01J31/2273 , B01J31/2278 , B01J31/2295 , B01J2231/543 , B01J2531/821 , B01J2531/825 , B01J2531/96 , B01J2540/42 , B01J2540/64 , C07B2200/09 , C07C29/32 , C07C29/56 , C07C67/333 , C07C209/68 , C07C2601/10 , C07D307/28 , C08G61/08 , C08G2261/3324 , C08G2261/418 , C07C211/63 , C07C69/74 , C07C33/035
Abstract: Disclosed herein is a general method for the preparation of complexes containing a quaternary onium group in an inert ligand. Some of these complexes may be represented by formula 1: Methods for the preparation of complexes of formula 1, the preparation of intermediates and the use of complexes of formula 1 in metathesis reactions and a method for conducting an olefin metathesis reaction are also described.
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2.发明授权Sulfonated organophosphine compounds and use thereof in hydroformylation processes 有权磺化有机膦化合物及其在加氢甲酰化方法中的应用公开(公告)号：US08461366B2
公开(公告)日：2013-06-11
申请号：US12812981
申请日：2009-01-09
Applicant: Michael L. Tulchinsky , Robert E. Hefner, Jr.
Inventor： Michael L. Tulchinsky , Robert E. Hefner, Jr.
IPC: C07C303/00 , C07F17/02 , C07F15/00
CPC classification number: B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
Abstract: A compound comprising a class of sulfonated triorganophosphine compounds of formula R1R2P—R3[—O—(CH2)n—(SO3M)]m, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
Abstract translation: 包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示 通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。 该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和铑的回收和再循环。
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3.发明授权Processes for solubilizing organometallic compounds in fluorinated solvents by addition of a partly fluorinated non-catalytic co-solubilizer 有权通过加入部分氟化的非催化共增溶剂在有机溶剂中溶解有机金属化合物的方法公开(公告)号：US07109365B2
公开(公告)日：2006-09-19
申请号：US10722195
申请日：2003-11-25
Applicant: David J. Gervasi , Santokh S. Badesha , John W. Spiewak
Inventor： David J. Gervasi , Santokh S. Badesha , John W. Spiewak
CPC classification number: C07C49/92 , B01J31/0202 , B01J31/0205 , B01J31/0209 , B01J31/0231 , B01J31/0232 , B01J31/04 , B01J31/1805 , B01J31/1815 , B01J31/2234 , B01J2531/16 , B01J2531/52 , B01J2531/827 , B01J2531/94 , B01J2540/225 , B01J2540/64
Abstract: A process for solubilizing an organometallic compound in a fluorinated solvent to form an organometallic solution by adding and reacting a co-solubilizer having a partly fluorinated polymer, an organometallic compound, and a fluorinated solvent, and the co-solubilizer has the ability to cause the organometallic compound to become miscible in a fluorinated solvent, and further, the co-solubilizer is not a catalyst and is present in the final organometallic solution.
Abstract translation: 通过加入并使具有部分氟化的聚合物，有机金属化合物和氟化溶剂的共增溶剂和共溶解剂进行反应而使有机金属化合物溶解在氟化溶剂中以形成有机金属溶液的方法，并且该助溶剂具有使 有机金属化合物在氟化溶剂中混溶，此外，共增溶剂不是催化剂并存在于最终的有机金属溶液中。
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4.发明申请Processes for solubilizing organometallic compounds in fluorinated solvents by addition of a partly fluorinated non-catalytic co-solubilizer 有权通过加入部分氟化的非催化共增溶剂在有机溶剂中溶解有机金属化合物的方法公开(公告)号：US20050113244A1
公开(公告)日：2005-05-26
申请号：US10722195
申请日：2003-11-25
Applicant: David Gervasi , Santokh Badesha , John Spiewak
Inventor： David Gervasi , Santokh Badesha , John Spiewak
CPC classification number: C07C49/92 , B01J31/0202 , B01J31/0205 , B01J31/0209 , B01J31/0231 , B01J31/0232 , B01J31/04 , B01J31/1805 , B01J31/1815 , B01J31/2234 , B01J2531/16 , B01J2531/52 , B01J2531/827 , B01J2531/94 , B01J2540/225 , B01J2540/64
Abstract: A process for solubilizing an organometallic compound in a fluorinated solvent to form an organometallic solution by adding and reacting a co-solubilizer having a partly fluorinated polymer, an organometallic compound, and a fluorinated solvent, and the co-solubilizer has the ability to cause the organometallic compound to become miscible in a fluorinated solvent, and further, the co-solubilizer is not a catalyst and is present in the final organometallic solution.
Abstract translation: 通过加入并使具有部分氟化的聚合物，有机金属化合物和氟化溶剂的共增溶剂和共溶解剂进行反应而使有机金属化合物溶解在氟化溶剂中以形成有机金属溶液的方法，并且该助溶剂具有使 有机金属化合物在氟化溶剂中混溶，此外，共增溶剂不是催化剂并存在于最终的有机金属溶液中。
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公开(公告)号：US6087481A
公开(公告)日：2000-07-11
申请号：US230575
申请日：1999-01-27
Applicant: Manfred T. Reetz , Siegfried Waldvogel
Inventor： Manfred T. Reetz , Siegfried Waldvogel
CPC classification number: C08B37/0012 , B01J31/065 , B01J31/1683 , B01J31/2409 , C07C45/50 , C07C67/313 , C07C67/347 , B01J2231/321 , B01J2531/0272 , B01J2531/822 , B01J2531/985 , B01J2540/64 , C07C2101/08 , C07C2101/16 , C07C2101/18
Abstract: The present invention relates to a process for the hydroformylation of terminal and internal olefins in a two-phase system using novel metal catalysts. The two-phase system consists of an aqueous and an organic phase. The metals belong to group VIII of the Periodic Table, e.g., Rh, Ru, Ir, Co or Pd. The ligands for the metals are novel phosphane-modified .beta.-cyclodextrins which are water-soluble.
Abstract translation: PCT No.PCT / EP97 / 04117 Sec。 371日期1999年1月27日第 102（e）日期1999年1月27日PCT提交1997年7月29日PCT公布。 出版物WO98 / 05618 日期1998年2月12日本发明涉及使用新型金属催化剂的两相体系中末端和内烯烃加氢甲酰化的方法。 两相系统由水相和有机相组成。 金属属于周期表第VIII族，例如Rh，Ru，Ir，Co或Pd。 金属配体是水溶性的新型膦改性β-环糊精。
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Patent Agency Ranking
公开(公告)号：US09573125B2
公开(公告)日：2017-02-21
申请号：US13928155
申请日：2013-06-26
Applicant: California Institute of Technology
Inventor： Raymond Weitekamp , Robert H. Grubbs
IPC: B01J31/22 , C08F4/44 , C07D233/02 , B01J31/16 , C07F9/6506 , B01J31/02
CPC classification number: B01J31/22 , B01J31/0259 , B01J31/1625 , B01J31/2273 , B01J2231/543 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2540/64 , C07F9/6506 , Y02P20/582
Abstract: An efficient method for the preparation of backbone-substituted imidazolinium salts for use as N-heterocyclic carbene ligands, e.g., for organometallic catalysts is provided. These functionalized N-heterocyclic carbene ligands are used to prepare solid-supported catalysts, e.g., for olefin metathesis.
Abstract translation: 提供了用于制备用作N-杂环卡宾配体的骨架取代的咪唑啉鎓盐的有效方法，例如用于有机金属催化剂。 这些官能化的N-杂环卡宾配体用于制备固体负载的催化剂，例如用于烯烃复分解。
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公开(公告)号：US08986638B2
公开(公告)日：2015-03-24
申请号：US14128070
申请日：2012-06-21
Applicant: Ivana Ivanovic-Burmazovic , Milos Filipovic
Inventor： Ivana Ivanovic-Burmazovic , Milos Filipovic
IPC: B01D53/52 , C01B17/64 , C02F1/72 , B01D53/86 , C01B17/05 , C10G27/10 , B01J31/16 , B01J31/18 , B01J31/22 , C02F101/10
CPC classification number: B01D53/52 , B01D53/8612 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/705 , B01D2256/24 , B01D2257/304 , B01D2258/025 , B01D2258/0283 , B01D2258/05 , B01J31/1616 , B01J31/165 , B01J31/1815 , B01J31/2243 , B01J2231/70 , B01J2531/025 , B01J2531/0252 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/42 , B01J2540/54 , B01J2540/64 , C01B17/05 , C02F1/725 , C02F2101/101 , C10G27/10 , C10G2300/207
Abstract: The present invention relates to a process for the catalytic oxidation of sulphide, mono- and/or dihydrogen sulphide, comprising the step of contacting the sulphide, mono- and/or dihydrogen sulphide in the presence of oxygen with a chelate complex comprising (i) a metal cation selected from the group consisting of Fez+, Mnz+, Niz+ and Coz+, where z=2 or 3, and (ii) a chelate ligand containing a porphyrin, a phthalocyanine or a porphyrazine ring coordinated to the metal cation, and at least one cationic substituent covalently attached to the ring in the chelate ligand.
Abstract translation: 本发明涉及硫化物，硫化氢和/或二氢化硫的催化氧化方法，包括在氧气存在下使硫化物，硫化氢和/或硫化氢与螯合络合物接触的步骤，所述螯合络合物包括（i） 选自Fez +，Mnz +，Niz +和Coz +的金属阳离子，其中z = 2或3，和（ii）含有与金属阳离子配位的卟啉，酞菁或四氮杂卟啉环的螯合配体，至少 一个阳离子取代基共价连接到螯合配体中的环上。
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8.发明申请SULFONATED ORGANOPHOSPHINE COMPOUNDS AND USE THEREOF IN HYDROFORMYLATION PROCESSES 有权硫化有机磷化合物及其在氢化方法中的应用公开(公告)号：US20110054204A1
公开(公告)日：2011-03-03
申请号：US12812981
申请日：2009-01-09
Applicant: Michael L. Tulchinsky , Robert E. Hefner, JR.
Inventor： Michael L. Tulchinsky , Robert E. Hefner, JR.
CPC classification number: B01J31/2404 , B01J31/2447 , B01J31/4046 , B01J31/4053 , B01J2231/321 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , B01J2531/96 , B01J2540/32 , B01J2540/64 , C07F9/5004 , C07F9/5018 , Y02P20/584
Abstract: A compound comprising a class of sulfonated triorganophosphine compounds of formula R1R2P—R3[—O—(CH2)n—(SO3M)]m, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.
Abstract translation: 包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示 通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。 该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和铑的回收和再循环。
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公开(公告)号：US20180050331A1
公开(公告)日：2018-02-22
申请号：US15682991
申请日：2017-08-22
Inventor： Hoyong Chung
IPC: B01J31/22 , B01J31/12 , C07C67/333
CPC classification number: B01J31/2278 , B01J31/123 , B01J31/2208 , B01J31/2273 , B01J31/4023 , B01J31/4038 , B01J35/12 , B01J38/52 , B01J2231/543 , B01J2531/821 , B01J2540/10 , B01J2540/64 , C07C29/46 , C07C29/56 , C07C41/28 , C07C41/30 , C07C67/333 , C07C209/68 , C07C209/70 , C07C2601/10 , C07C2603/74 , C07D207/20 , C07D209/48 , C07D211/02 , C07D211/70 , C07D223/10 , C07D307/28 , C07F15/0046 , C07H3/06 , C08B37/0012 , C08B37/0015 , C08F132/08 , Y02P20/584 , C07C43/196 , C07C43/235 , C07C211/63
Abstract: A method for separating a homogeneous catalyst from a solution includes forming a host-guest compound between a first isomer of the catalyst and inclusion compound in the solution and isolating the host-guest compound from the solution. The catalyst may be released from the inclusion compound by converting the first isomer of the catalyst to a second isomer of the catalyst.
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公开(公告)号：US09403860B2
公开(公告)日：2016-08-02
申请号：US13779602
申请日：2013-02-27
Applicant: Apeiron Synthesis S.A.
Inventor： Krzysztof Skowerski , Lukasz Gulajski , Michal Bieniek , Stefan Czarnocki , Grzegorz Szczpaniak , Celina Wierzbicka
IPC: C07F15/00 , B01J31/22 , C07C209/68 , C07D307/28 , C07C29/32 , C07C29/56 , C07C67/333 , C08G61/08
CPC classification number: C07F15/0046 , B01J31/2204 , B01J31/2273 , B01J31/2278 , B01J31/2295 , B01J2231/543 , B01J2531/821 , B01J2531/825 , B01J2531/96 , B01J2540/42 , B01J2540/64 , C07B2200/09 , C07C29/32 , C07C29/56 , C07C67/333 , C07C209/68 , C07C2601/10 , C07D307/28 , C08G61/08 , C08G2261/3324 , C08G2261/418 , C07C211/63 , C07C69/74 , C07C33/035
Abstract: Disclosed herein is a general method for the preparation of complexes containing a quaternary onium group in an inert ligand. Some of these complexes may be represented by formula 1: Methods for the preparation of complexes of formula 1, the preparation of intermediates and the use of complexes of formula 1 in metathesis reactions and a method for conducting an olefin metathesis reaction are also described.
Abstract translation: 本文公开了在惰性配体中制备含有季鎓基团的络合物的一般方法。 这些配合物中的一些可以由式1表示：还描述了制备式1的络合物的方法，中间体的制备和式1的络合物在复分解反应中的用途和用于进行烯烃复分解反应的方法。
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