公开(公告)号：US4913842A

公开(公告)日：1990-04-03

申请号：US579952

申请日：1984-02-14

申请人： Mikio Yoneoka ,  Tomiyoshi Furuta ,  Yasuo Yamamoto ,  Sadao Nozaki ,  Kazuo Takada ,  Kumiko Watabe ,  Takeo Ikarashi

发明人： Mikio Yoneoka ,  Tomiyoshi Furuta ,  Yasuo Yamamoto ,  Sadao Nozaki ,  Kazuo Takada ,  Kumiko Watabe ,  Takeo Ikarashi

IPC分类号： B01B1/00 ,  B01J23/80 ,  B01J23/86 ,  C01B3/32 ,  C02F1/04 ,  F02B3/06 ,  F02M57/02 ,  F02M59/26

CPC分类号： B01J23/80 ,  B01B1/005 ,  B01J23/86 ,  C01B3/323 ,  C01B3/326 ,  C02F1/048 ,  F02M57/02 ,  F02M59/265 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  F02B3/06 ,  Y02P20/52

摘要： A condensed liquid obtained after separation of gaseous components from the gas produced by the steam reforming reaction of methanol is brought into contact, in a gaseous phase, with catalyst (I) containing copper oxide (A), oxide of at least one type of metals selected from the group consisting of zinc, aluminium and chromium (B) and oxide of the group VIII metal in the periodic table (C), or catalyst (II) comprising the group VIII metal in the periodic table or compound thereof supported on carriers.The treatment of the condensed liquid yields water containing substantially no methanol, ethanol and high boiling point components. The treated condensed liquid causes no pollution problem when disposed as effluent and may be reused for the steam reforming reaction of methanol.

摘要翻译： 将气态组分从由甲醇的水蒸气重整反应产生的气体分离后得到的冷凝液与气相相接触，与含有氧化铜（A）的催化剂（I），至少一种金属的氧化物 选自元素周期表（C）中的锌，铝和铬（B）和Ⅷ族金属的氧化物或包含元素周期表中第Ⅷ族金属的催化剂（II）或载体载体上的化合物。 冷凝液的处理产生基本上不含甲醇，乙醇和高沸点组分的水。 经处理的冷凝液体作为流出物排放时不会造成污染问题，可用于甲醇的蒸汽重整反应。

公开(公告)号：US4459365A

公开(公告)日：1984-07-10

申请号：US379446

申请日：1982-05-18

申请人： Takashi Suzuki ,  Kouichi Kitahara ,  Tomiyoshi Furuta ,  Sadao Nozaki

发明人： Takashi Suzuki ,  Kouichi Kitahara ,  Tomiyoshi Furuta ,  Sadao Nozaki

IPC分类号： B01J31/40 ,  C07C51/47 ,  B01J37/06 ,  B01J37/00

CPC分类号： B01J31/04 ,  B01J31/26 ,  B01J31/4015 ,  B01J31/403 ,  C07C51/47 ,  B01J2231/70 ,  B01J2531/72 ,  B01J2531/845 ,  Y02P20/584

摘要： A method of recovering a catalytic cobalt and/or manganese from a distillation residue in a process for preparing an aromatic carboxylic acid comprising a liquid-phase oxidation of the aromatic hydrocarbon having aliphatic substituent(s) or its oxidized derivatives in the presence of the catalytic cobalt and/or manganese and the distillation of the reaction product, which comprises successively or simultaneously treating the distillation residue with water and with an organic solvent having a relative dielectric constant D of3.0.ltoreq.D.ltoreq.35

摘要翻译： 在制备芳族羧酸的方法中从蒸馏残余物中回收催化剂的钴和/或锰的方法，该方法包括在催化剂存在下具有脂族取代基或其氧化衍生物的芳族烃的液相氧化 钴和/或锰，并且蒸馏反应产物，其包括用水和有机溶剂连续或同时处理蒸馏残余物和相对介电常数D的有机溶剂

公开(公告)号：US4894188A

公开(公告)日：1990-01-16

申请号：US700347

申请日：1985-02-13

申请人： Takehiko Takahashi ,  Makoto Takagawa ,  Tomiyoshi Furuta ,  Toshio Hidaka ,  Kazuo Takada

发明人： Takehiko Takahashi ,  Makoto Takagawa ,  Tomiyoshi Furuta ,  Toshio Hidaka ,  Kazuo Takada

IPC分类号： C07C67/37 ,  B01J27/00 ,  C07C51/00 ,  C07C51/10 ,  C07C51/12 ,  C07C51/14 ,  C07C67/00 ,  C07C67/36

CPC分类号： C07C51/14 ,  C07C51/12 ,  C07C67/36 ,  C07C67/37 ,  C07C67/38 ,  C07C2101/14

摘要： Fatty acid and their derivatives are simply produced by reacting an olefin, carbon monoxide and water or reacting an alcohol or its derivative and carbon monoxide in the presence of a hydrogen fluoride catalyst and thermally decomposing the resulting reaction product in the presence of a lower hydrocarbon or a lower halogenated hydrocarbon.

摘要翻译： 脂肪酸及其衍生物简单地通过使烯烃，一氧化碳和水反应，或者在氟化氢催化剂的存在下使醇或其衍生物和一氧化碳反应，或者在低级烃存在下热分解所得反应产物 低级卤代烃。

公开(公告)号：US4933473A

公开(公告)日：1990-06-12

申请号：US342226

申请日：1989-04-21

申请人： Teruyuki Ninomiya ,  Tomiyoshi Furuta ,  Seiji Kita ,  Yoshimi Fujii

发明人： Teruyuki Ninomiya ,  Tomiyoshi Furuta ,  Seiji Kita ,  Yoshimi Fujii

IPC分类号： B01J23/652 ,  C07B61/00 ,  C07C27/00 ,  C07C29/141 ,  C07C31/20 ,  C07C45/75 ,  C07C67/00

CPC分类号： C07C29/141 ,  C07C45/75

摘要： A process for production of neopentyl glycol by hydrogenation of hydroxypivaldehyde in the presence of a Pt-Ru-W catalyst. This catalyst exhibits high activity and selectivity, and further has a long life. Neopentyl glycol is an important intermediate for use in production of a wide variety of chemicals.

公开(公告)号：US4824992A

公开(公告)日：1989-04-25

申请号：US104892

申请日：1987-10-06

申请人： Toru Tanaka ,  Tomiyoshi Furuta ,  Kazue Suwa

发明人： Toru Tanaka ,  Tomiyoshi Furuta ,  Kazue Suwa

IPC分类号： B01J27/128 ,  B01J27/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/255 ,  C07C51/265 ,  C07C63/313 ,  C07C67/00

CPC分类号： C07C51/265

摘要： A process for producing pyromellitic acid which comprises oxidizing 2,4,5-trimethylbenzaldehyde with a gas containing molecular oxygen in the presence of a water solvent containing 0.5 to 12% by weight of bromine ion, 0.01 to 2.0% by weight of manganese ion and 0.1 to 10,000 ppm by weight of iron ion.According to the present invention, pyromellitic acid can be obtained in a high yield and, at the same time, the amount of remaining intermediate compounds such as methyltrimellitic acid and the like can be made few, so that pyromellitic acid can be purified easily.

摘要翻译： 一种制备均苯四酸的方法，其包括在含有0.5-12重量％溴离子，0.01-2.0重量％锰离子的水溶剂和0.01-2.0重量％锰离子的水溶剂存在下，用含有分子氧的气体氧化2,4,5-三甲基苯甲醛，和 0.1〜10,000ppm的铁离子。 根据本发明，可以高收率地获得均苯四酸，同时可以使少量残留的中间体化合物如甲基偏苯三酸等，从而可以容易地纯化均苯四酸。