公开(公告)号：US4655792A

公开(公告)日：1987-04-07

申请号：US680724

申请日：1984-12-12

Applicant: Richard V. Kessler ,  Mitri S. Najjar

Inventor： Richard V. Kessler ,  Mitri S. Najjar

IPC: C01B3/36 ,  C10J3/46 ,  C10J3/66 ,  C10J3/00

CPC classification number: C01B3/36 ,  C10J3/08 ,  C10J3/463 ,  C10J3/466 ,  C10J3/62 ,  C10J3/66 ,  C10J2300/0983 ,  C10J2300/1628 ,  Y10S48/07

Abstract: An ash fusion temperature reducing agent comprising a comminuted ore mixture of the silicates of iron, calcium, magnesium and aluminum is mixed with an ash containing pumpable liquid hydrocarbonaceous material to produce Mixture A. Mixture A is reacted with a free-oxygen containing gas in a partial oxidation gas generator. A hot raw effluent gas stream comprising H.sub.2 +CO along with molten ash having a reduced ash fusion temperature are produced at a lower temperature. Alternatively, Mixture A may be first introduced into a coking zone and converted into petroleum coke in which the ash fusion temperature reducing agent is dispersed throughout. The petroleum coke is then introduced into the partial oxidation gas generator where the hot raw effluent gas stream comprising H.sub.2 +CO is produced along with molten petroleum coke ash having a reduced ash fusion temperature. The molten ash is readily separated from the effluent gas stream and the gas generator may be operated at a lower temperature thereby extending the life of the refractory lined reaction zone.

Abstract translation: 将包含铁，钙，镁和铝的硅酸盐的粉碎矿石混合物的灰熔融降温剂与含灰尘的可泵送液体烃类材料混合以制备混合物A.混合物A与含有游离氧的气体在 部分氧化气体发生器。 在较低的温度下产生包含H 2 + CO以及具有降低的灰熔融温度的熔融灰分的热的原料流出物气流。 或者，可以将混合物A首先引入焦化区并转化为石灰焦炭，其中灰分熔融降温剂分散在其中。 然后将石油焦炭引入到部分氧化气体发生器中，其中产生包含H 2 + CO的热的原料流出气流以及具有降低的灰分熔融温度的熔融石油焦炭。 熔融灰很容易与废气流分离，并且气体发生器可以在较低温度下操作，从而延长耐火材料衬里反应区的寿命。

公开(公告)号：US4705538A

公开(公告)日：1987-11-10

申请号：US795015

申请日：1985-11-04

Applicant: Mitri S. Najjar ,  Richard V. Kessler

Inventor： Mitri S. Najjar ,  Richard V. Kessler

IPC: C01B3/36 ,  C10J3/46 ,  C10J3/66

CPC classification number: C01B3/36 ,  C10J3/08 ,  C10J3/463 ,  C10J3/466 ,  C10J3/62 ,  C10J3/66 ,  C10J2300/0983 ,  C10J2300/1628 ,  Y10S48/07

Abstract: An ash fusion temperature increasing agent principally comprising a silicon and/or titanium compound, such as SiO.sub.2 and/or TiO.sub.2 is mixed with an ash-containing fuel comprising a pumpable liquid hydrocarbonaceous material and/or petroleum coke to produce Mixture A. In one embodiment, the ash fusion temperature increasing agent comprises about 55-100 wt. % of silicon compound selected from the group consisting of fine silica or quartz, volcanic ash, and mixtures thereof; and the remainder, if any, of said ash fusion temperature increasing agent comprises a member of the group consisting of aluminum compound such as Al.sub.2 O.sub.3, magnesium compound such as MgO, and mixtures thereof. Mixture A is reacted with a free-oxygen containing gas in a free-flow refractory lined reaction zone of a partial oxidation gas generator. A hot raw effluent gas stream comprising H.sub.2 +CO along with fly-ash having an increased initial deformation temperature are produced at a higher temperature. Alternatively, Mixture A may be first introduced into a coking zone and converted into petroleum coke in which the ash fusion temperature increasing agent is dispersed throughout. The petroleum coke entrained in a liquid or gaseous carrier is then introduced into the partial oxidation gas generator where a hot raw effluent gas stream comprising H.sub.2 +CO is produced along with fly-ash having an increased ash fusion temperature. The fly-ash is readily separated from the effluent gas stream; and, the gas generator may be operated in the fly-ash mode at a higher temperature, thereby yielding higher carbon conversions while extending the life of the refractory lined reaction zone.

Abstract translation: 主要包含硅和/或钛化合物如SiO 2和/或TiO 2的灰熔融增温剂与包含可泵送液体含烃材料和/或石油焦炭的含灰分燃料混合以产生混合物A.在一个实施方案中 ，所述灰熔融升温剂包含约55-100wt。 ％的选自二氧化硅或石英的硅化合物，火山灰及其混合物; 并且所述灰熔融升温剂的剩余部分（如果有的话）包括由铝化合物如Al 2 O 3，镁化合物如MgO组成的组的组分，以及它们的混合物。 混合物A与部分氧化气体发生器的自由流动耐火衬里反应区中的含游离氧气体反应。 在较高的温度下产生包含H 2 + CO以及具有增加的初始变形温度的粉煤灰的热的原料流出气流。 或者，可以将混合物A首先引入焦化区并转化为石灰焦炭，其中灰分熔融升温剂分散在其中。 然后将夹带在液体或气体载体中的石油焦炭引入部分氧化气体发生器中，其中产生包含H 2 + CO的热的原始流出气流以及具有增加的灰熔融温度的飞灰。 飞灰容易与废气流分离; 并且气体发生器可以在较高温度下以飞灰模式操作，从而在延长耐火材料衬里反应区的寿命的同时产生更高的碳转化率。

公开(公告)号：US5261602A

公开(公告)日：1993-11-16

申请号：US812310

申请日：1991-12-23

Applicant: Albert Brent ,  Robert J. Stellaccio ,  Mitri S. Najjar ,  Jerrold S. Kassman

Inventor： Albert Brent ,  Robert J. Stellaccio ,  Mitri S. Najjar ,  Jerrold S. Kassman

IPC: C10J3/48 ,  F23D14/78 ,  B05B7/00

CPC classification number: C01B3/363 ,  C10J3/506 ,  F23D14/78 ,  C01B2203/0255 ,  C10J2200/152 ,  C10J2300/1223 ,  Y10S165/907 ,  Y10S165/911 ,  Y10S423/06 ,  Y10S48/07 ,  Y10S48/08

Abstract: A partial oxidation process and a novel burner are provided for simultaneously introducing two or three separate feedstreams into a free-flow partial oxidation gas generator for the production of synthesis gas and fuel gas, or reducing gas. The reactant feedstreams include a liquid hydrocarbonaceous fuel or a pumpable slurry of solid carbonaceous fuel, and a free-oxygen containing gas e.g. air or oxygen. The burner comprises a central conduit and a plurality of spaced concentric coaxial conduits with down-flowing annular passages. A flat annular-shaped disc or cup-shaped porous ceramic or porous metal cooling means of uniform composition, wall thickness and porosity with the various pores interconnecting is attached to the downstream tip of the burner. A controlled amount of liquid coolant under pressure is passed successively through the porous inside surface, porous core and porous outside surface of the cooling means is vaporized. The tip of the burner is thereby cooled. Stress cracking of the burner tip is prevented; and the life of the burner is extended. Further, deposition of ash on the face of the burner is prevented.

Abstract translation: 提供了部分氧化工艺和新型燃烧器，用于同时将两个或三个独立的进料流引入到用于生产合成气和燃料气体或还原气体的自由流部分氧化气体发生器中。 反应物进料流包括液体烃类燃料或固体碳质燃料的可泵送浆料，以及含游离氧气体。 空气或氧气。 燃烧器包括具有向下流动的环形通道的中心管道和多个间隔开的同心同轴管道。 与燃烧器的下游末端连接有平坦的环形盘或杯形多孔陶瓷或多孔金属冷却装置，其均匀组成，壁厚和孔隙率与各种孔互相连接。 压力下的受控量的液体冷却剂依次通过多孔内表面，冷却装置的多孔芯和多孔外表面蒸发。 从而冷却燃烧器的尖端。 防止燃烧器尖端的应力开裂; 燃烧器的寿命延长。 此外，防止灰尘沉积在燃烧器的表面上。

公开(公告)号：US5250083A

公开(公告)日：1993-10-05

申请号：US875950

申请日：1992-04-30

Applicant: James K. Wolfenbarger ,  Mitri S. Najjar

Inventor： James K. Wolfenbarger ,  Mitri S. Najjar

IPC: C10J3/46

CPC classification number: C10J3/00 ,  C10J2300/0983 ,  C10J2300/0996 ,  C10J2300/1846 ,  Y10S48/02

Abstract: A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

Abstract translation: 一种用于含硫和含硅酸盐的含碳燃料的部分氧化以产生具有降低的硫含量的合成气的方法，其包括在1900℃-2600°F的温度范围内部分氧化所述燃料， 温度调节剂，含氧气体和硫捕获添加剂，其包含含钙化合物部分，含钠化合物部分和含氟化物的化合物部分，以产生包含具有降低的硫含量的H 2和CO的合成气 和熔渣，其包括（1）含硫的氟化钠 - 硅酸钙相; 和（2）硫化钠钠相。

公开(公告)号：US5181941A

公开(公告)日：1993-01-26

申请号：US807489

申请日：1991-12-16

Applicant: Mitri S. Najjar ,  Carl A. Hultman

Inventor： Mitri S. Najjar ,  Carl A. Hultman

IPC: B01D53/22 ,  B01D71/02

CPC classification number: B01D67/0069 ,  B01D53/228 ,  B01D71/022 ,  B01D2325/023 ,  Y10S55/05

Abstract: A novel membrane system, including a layer of platinum or palladium on graphite, is used to separate hydrogen from a hydrocarbon stream.

Abstract translation: 使用包括石墨上的铂或钯层的新型膜系统从烃流中分离氢。

公开(公告)号：US5141649A

公开(公告)日：1992-08-25

申请号：US772314

申请日：1991-10-07

Applicant: Mordechai Pasternak ,  Uygur Kokturk ,  Mitri S. Najjar ,  Raymond D. Malouf

Inventor： Mordechai Pasternak ,  Uygur Kokturk ,  Mitri S. Najjar ,  Raymond D. Malouf

IPC: B01D61/36 ,  B01D69/10 ,  B01D69/12 ,  B01D71/38

CPC classification number: B01D61/362 ,  B01D69/10 ,  B01D69/125 ,  B01D71/38

Abstract: Charge compositions containing aqueous mixtures of organic oxygenates may be separated by pervaporation through a membrane assembly containing a porous ceramic support bearing as separating layer, a membrane of cured polyvinyl alcohol which has been cross-linked as with glutaraldehyde.

Abstract translation: 含有有机含氧化合物的含水混合物的电荷组合物可以通过包含多孔陶瓷载体轴承作为分离层的膜组件通过渗透蒸发分离，固化的聚乙烯醇膜已经与戊二醛交联。

公开(公告)号：US5124305A

公开(公告)日：1992-06-23

申请号：US563019

申请日：1990-08-06

Applicant: Arnulf Muan ,  Mitri S. Najjar

Inventor： Arnulf Muan ,  Mitri S. Najjar

IPC: B01J23/78 ,  B01J23/847

CPC classification number: B01J23/78 ,  B01J23/8472

Abstract: The present invention pertains to novel phases involving FeO, V.sub.2 O.sub.3 and CaO and the method for their preparation. The solid compositions involving FeO--V.sub.2 O.sub.3 --CaO fall within the shaded area of a polygon in a ternary composition diagram of FeO, V.sub.2 O.sub.3 and CaO as shown in the drawing herein e.g., FIG. 1. The compositions may be used as a catalyst for oxidation or reduction reactions.

Abstract translation: 本发明涉及FeO，V2O3和CaO的新型相及其制备方法。 涉及FeO-V2O3-CaO的固体组合物在FeO，V 2 O 3和CaO的三元组成图中落在多边形的阴影区域内，如图所示，如图1所示。 该组合物可用作氧化还原反应的催化剂。

公开(公告)号：US5102834A

公开(公告)日：1992-04-07

申请号：US615533

申请日：1990-11-19

Applicant: Arnulf Muan ,  Mitri S. Najjar

Inventor： Arnulf Muan ,  Mitri S. Najjar

IPC: C30B9/00 ,  C30B11/00 ,  H01S3/16

CPC classification number: C30B29/22 ,  C30B11/00 ,  C30B9/00 ,  H01S3/16

Abstract: Vanadium garnet materials and a method for their preparation. The vanadium garnet material has a trivalent vanadium cation and a composition that falls within a specific prismatic-shaped volume in a quaternary composition diagram of MnO, CaO, V.sub.2 O.sub.3, and SiO.sub.2. The prismatic-shaped volume represents compositions of liquids with which said vanadium garnet is in equilibrium on the liquidus surface and from which the vanadium garnet phase is crystallized. A typical vanadium garnet material has the formula Mn.sub.1.3 Ca.sub.1.7 V.sub.2 Si.sub.3 O.sub.12, as provided in the drawing by point F. The vanadium garnet materials may be used in laser applications.

Abstract translation: 钒石榴石材料及其制备方法。 钒石榴石材料具有三价钒阳离子和在MnO，CaO，V2O3和SiO2的四元组成图中落入特定棱柱形体积内的组合物。 棱柱形体积表示所述钒石榴石在液相线表面处于平衡状态并使钒石榴石相结晶的液体组成。 典型的钒石榴石材料具有配方Mn1.3Ca1.7V2Si3O12，如附图F所示。钒石榴石材料可用于激光应用。

公开(公告)号：US5086029A

公开(公告)日：1992-02-04

申请号：US615761

申请日：1990-11-19

Applicant: Arnulf Muan ,  Mitri S. Najjar

Inventor： Arnulf Muan ,  Mitri S. Najjar

IPC: B01J23/00 ,  B01J23/22 ,  B01J23/34 ,  C04B35/495

CPC classification number: B01J23/22 ,  B01J23/005 ,  B01J23/34 ,  C04B35/495 ,  Y10S502/524

Abstract: The present invention pertains to novel vanadium spinel materials and a method for their preparation. Each vanadium spinel material has a trivalent vanadium cation and is crystallized from a liquid having a composition that falls within a specific polygon shaped area in a ternary composition diagram of V.sub.2 O.sub.3 --MnO--SiO.sub.2 as shown in the drawing herein e.g., FIG. 1. The compositions may be used as a catalyst for oxidation reactions.

Abstract translation: 本发明涉及新型钒尖晶石材料及其制备方法。 每个钒尖晶石材料具有三价钒阳离子，并且在V2O3-MnO-SiO2的三元组成图中由具有落入特定多边形区域内的组成的液体结晶，如图所示。 该组合物可用作氧化反应的催化剂。

公开(公告)号：US4971601A

公开(公告)日：1990-11-20

申请号：US506138

申请日：1990-04-09

Applicant: Mitri S. Najjar ,  Walter C. Gates, Jr.

Inventor： Mitri S. Najjar ,  Walter C. Gates, Jr.

IPC: C10J3/46

CPC classification number: C10J3/466 ,  C10K1/101 ,  C10K3/005 ,  C10J2300/1223 ,  C10J2300/1846

Abstract: Synthesis gas, reducing gas, or fuel gas is produced by the partial oxidation of ash-containing solid carbonaceous and/or liquid hydrocarbonaceous fuel at an autogenous temperature in the range of about 20.degree. F. to 200.degree. F. below the softening temperature of the ash in said fuel, and at a pressure in the range of about 17 to 100 atmospheres to produce a raw effluent gas stream containing entrained carbon-rich fly-ash which is separated from the effuent gas stream. A fuel mixture comprising about 20 to 100 wt. % of said carbon-rich fly-ash and about 0 to 80 wt. % of a supplemental fuel is reacted by partial oxidation at an autogenous temperature of about 100.degree. F. above the ash-fusion temperature, and at a reduced pressure e.g. in the range of about 1 to 16 atmospheres and at least 16 atmospheres below the pressure in the partial oxidation reaction used to produce said carbon-rich fly-ash. By reducing the pressure less carbon-rich particulate material is produced in the second partial oxidation reaction at a significant cost savings and improved process efficiency.

Abstract translation: 合成气体，还原气体或燃料气体是通过将含灰分的固体含碳和/或液体烃类燃料在自发温度下部分氧化而产生的，所述固体碳质和/或液体烃类燃料的温度低于软化温度约20°F至200°F 所述燃料中的灰分，并且在约17至100个大气压的范围内的压力，以产生包含夹带的富含碳的飞灰的原料流出气流，其与所述流体气流分离。 一种燃料混合物，其包含约20至100wt。 ％的所述富碳飞灰和约0至80wt。 补充燃料的％通过部分氧化在高于灰熔融温度约100°F的自生温度下和在减压下反应。 在约1至16个大气压的范围内，并且在用于产生所述富碳飞灰的部分氧化反应中的压力以下至少16个大气压。 通过减少压力，在显着的成本节约和改进的工艺效率下，在第二部分氧化反应中产生较少的富碳颗粒材料。