摘要:
Disclosed is an electrophotographic toner binder which comprises a silicone-grafted copolymer produced by radical copolymerization of an organopolysiloxane compound represented by the following general formula (I) and another monomer capable of undergoing the radical copolymerization with said organopolysiloxane compound: ##STR1## wherein R.sup.1 represents a hydrogen atom or a methyl group; R.sup.2 represents a divalent hydrocarbon group containing 1 to 12 carbon atoms, which may have one or more of an oxygen atom interposed in its carbon chain; R.sup.3 represents a monovalent hydrocarbon group containing 1 to 6 carbon atoms; m represents 1, 2 or 3; and n represents an integer from 20 to 200.
摘要:
Organopolysiloxanes having two different functional groups selected from the group consisting of 3-glycidoxy-propyl, 2-(3',4'-epoxycyclohexyl)ethyl, 3-hydroxypropyl, 3-(2'-hydroxyethoxy)propyl, 3-acryloxypropyl, and 3-methacryloxypropyl groups are more compatible with organic resins and more effective for tailoring the organic resins. They are produced by hydrosilylation of organohydrogenpolysiloxanes with functional group-containing alkenes.
摘要:
A method for removing an acidic gas from a raw gas containing the acid gas by contacting the raw gas with an aqueous alkanol amine solution, characterized in that a composition comprising an organopolysiloxane containing a polyoxyalkylene group and a fine silica powder is caused to be present. In some embodiments, a composition comprising the above-mentioned organopolysiloxane and a fine silica powder is added appropriately according to the state of foaming in an acidic gas removing reaction system from the outside of the system, or use is made of an alkanol amine containing in advance a composition comprising the above-mentioned organopolysiloxane and a fine silica powder. In preferred embodiments, the fine silica powder has a specific surface area of 50 m2/g or more, and/or the composition comprising the above-mentioned organopolysiloxane and a fine silica powder is used in an amount of 0.1 to 5000 ppm relative to the alkanol amine. As a further embodiment, a method for removing an acidic gas from a raw gas by contacting the raw gas with an aqueous alkanol amine solution containing 40 mass % or more of an alkanol amine, characterized in that a composition comprising the above-mentioned organopolysiloxane and a fine silica powder is caused to be present in an amount of 0.1 to 5000 ppm relative to the alkanol amine.
摘要:
Coating agents for electrophotography carriers are disclosed which are resistant to wear, peel-off, cracks, and prevent the occurrence of a spent phenomenon, and which possess a durability for a long period of use and a superior stability in the carrier charge characteristics. The coating provides long lifetime electrophotography carriers which possess reduced temperature dependency and improved stability in the carrier charge characteristics.The coating agents for the electrophotography carrier are characterized by having an organopolysiloxane expressed by the formula below as a main component:R.sub.a.sup.f R.sub.b.sup.1 Si(OR.sup.2).sub.c O.sub.(4-(a+b+c))/2IwhereinR.sup.f is C.sub.p F.sub.2p+1 Q;p is 1-12;Q is a bivalent organic group with 2-12 carbon atoms;R.sup.1 is alkyl with 1-12 carbon atoms or phenyl;R.sup.2 is H or alkyl with 1-6 carbon atoms; anda, b and c are numbers satisfying the following conditions:0
摘要翻译:公开了耐磨损,剥离,裂纹,防止出现现象的电子照相载体用涂料,其具有长时间使用的耐久性和载体电荷特性优异的稳定性。 涂层提供长寿命的电子照相载体,其具有降低的温度依赖性和改善载体电荷特性的稳定性。 电子照相载体的涂层剂的特征在于具有由下式表示的有机聚硅氧烷作为主要成分:RafRb1Si(OR2)cO(4-(a + b + c))/ 2I,其中Rf为CpF2p + 1Q; p为1-12; Q是具有2-12个碳原子的二价有机基团; R1是具有1-12个碳原子的烷基或苯基; R2是H或具有1-6个碳原子的烷基; 和a,b和c是满足以下条件的数字:0 和0 a + b + / = 4。
摘要:
A process for preparing a polyester-modified silicone resin comprises mixing an alkoxysilane and/or its hydrolyzate, i.e. an alkoxysiloxane, and a polyester resin having at least two hydroxyl groups in the molecule, and subjecting the mixture to hydrolysis and polycondensation reactions in the presence of an acid catalyst. This process is performed by a continuous one-stage reaction sequence including hydrolysis, polycondensation and modification and is simplified. A composition comprising the polyester-modified silicone resin is also described. The composition comprising organozinc compounds along with the modified silicone resin is significantly improved in heat resistance and color-difference.
摘要:
The present invention provides a coating agent for an electrophotographic carrier comprising as a major component a copolymer of at least one monomer selected from the organopolysiloxanes represented by the following general formulas 1, 2, and 3 with other polymerizable monomer: ##STR1## wherein the general formulas 1, 2, and 3, R.sup.1 is hydrogen atom or methyl group; R.sup.2 is C.sub.1 -C.sub.10 alkyl or phenyl group; R.sup.3 is R.sup.2 or CH.sub.2 .dbd.C(R.sup.1)COOC.sub.3 H.sub.6 ; n, p, and q are defined as n.gtoreq.3, p.gtoreq.0, q.gtoreq.3, and p
摘要:
Novel organopolysiloxanes containing both a (meth)acryl group and a carboxyl group in a molecule are well compatible with organic resins and useful as resin modifiers.
摘要:
A curable resin composition comprising (a) an acrylic, polyester, epoxy or polyol resin having a plurality of alkynyl groups, (b) an organohydrogenpolysiloxane, and (c) an amount of platinum catalyst effective to catalyze the crosslink reaction between (a) and (b). The composition is useful for coating and molding purposes and gives a cured product having excellent acid resistance, water resistance and other properties.
摘要:
Hydrogenpolysiloxanes having a (meth)acryloxypropyl group on a side chain are useful intermediates. They are prepared by equilibration reaction of siloxane compounds.
摘要:
A curable resin composition containing (a) a homo- or copolymer of an organohydrogenpolysiloxane macromonomer, (b) an alkenyl group-containing polymer, and (c) a hydrosilylation catalyst is disclosed. The organohydrogenpolysiloxane macromonomer may be incorporated into a single polymer entity together with an alkenyl group-containing monomer unit to produce a self-crosslinkable copolymer.