Readily fibrillatable fiber
    2.
    发明授权
    Readily fibrillatable fiber 失效
    易纤维纤维

    公开(公告)号:US6048641A

    公开(公告)日:2000-04-11

    申请号:US237810

    申请日:1999-01-27

    IPC分类号: D01F8/02 D01F8/10 H01M2/16

    CPC分类号: D01F8/10 D01F8/02

    摘要: A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water. From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution. The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.

    摘要翻译: 海岛相分离纤维,其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物,岛组分包括具有优异的碱溶液吸收性,耐热性和耐热熔性的水不溶性纤维素基聚合物, 并且其中岛的尺寸为0.03〜10μm,强度为3g / d以上时,当对纤维进行机械应力湿润时,容易分解成直径为0.05〜8μm的原纤维 水。 从具有良好亲水性,高强度,巨大的颗粒俘获和优异的增强性能的原纤维,另外具有良好的碱溶液吸收性和高耐热性和耐热熔性,其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板,水泥板状板的增强纤维,摩擦材料的增强纤维等。

    Separator for a battery comprising a fibrillatable fiber
    3.
    发明授权
    Separator for a battery comprising a fibrillatable fiber 失效
    一种用于包含可原纤化纤维的电池分离器

    公开(公告)号:US6124058A

    公开(公告)日:2000-09-26

    申请号:US237809

    申请日:1999-01-27

    IPC分类号: D01F8/02 D01F8/10 H01M2/16

    摘要: A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water.From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution.The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.

    摘要翻译: 海岛相分离纤维,其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物,岛组分包括具有优异的碱溶液吸收性,耐热性和耐热熔性的水不溶性纤维素基聚合物, 并且其中岛的尺寸为0.03〜10μm,强度为3g / d以上时,当对纤维进行机械应力湿润时,容易分解成直径为0.05〜8μm的原纤维 水。 从具有良好亲水性,高强度,巨大的颗粒俘获和优异的增强性能的原纤维,另外具有良好的碱溶液吸收性和高耐热性和耐热熔性,其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板,水泥板状板的增强纤维,摩擦材料的增强纤维等。

    Flame-retardant polyvinyl alcohol base fiber
    4.
    发明授权
    Flame-retardant polyvinyl alcohol base fiber 失效
    阻燃聚乙烯醇基纤维

    公开(公告)号:US6066396A

    公开(公告)日:2000-05-23

    申请号:US319239

    申请日:1999-06-07

    摘要: A vinyl-alcohol-based polymer and vinyl-halide-based polymer are dissolved in a common organic solvent for them, a typical example of which is dimethylsulfoxide, to obtain a dope wherein a solution of the vinyl-halide-based polymer having a particle size of 1-50 .mu.m is present in the solution of the vinyl-alcohol-based polymer. This dope is spun into a low temperature solidifying bath comprising a solidifying solvent such as methanol, and the organic solvent. The resultant is subjected to extraction, drying, dry heat drawing, and optional heat shrinking or acetalization to obtain fiber. In the fiber thus obtained, the vinyl-alcohol-based polymer makes sea phases, and the vinyl-halide-based polymer makes island phases whose size is 0.1-3 .mu.m. The crystallinity degree of the vinyl-alcohol-based polymer is 65-85%.The polyvinyl-alcohol-based flame retardant fiber is useful for clothes, industrial materials, living materials and the like. It can be produced at low costs, and has excellent spinning stability and dimensional stability in hot water.

    摘要翻译: PCT No.PCT / JP98 / 04424 Sec。 371日期1999年6月7日 102(e)日期1999年6月7日PCT提交1998年10月1日PCT公布。 公开号WO99 /​​ 18267 日期1999年04月15日乙烯基醇类聚合物和乙烯基卤化物类聚合物溶解在普通的有机溶剂中,其典型的例子是二甲基亚砜,以获得涂料,其中乙烯基卤化物 - 乙烯醇类聚合物的溶液中存在粒径为1-50μm的聚合物。 将该纺丝液纺成包含固化溶剂如甲醇和有机溶剂的低温固化浴。 将所得物进行萃取,干燥,干热拉伸和任选的热收缩或缩醛化以获得纤维。 在由此获得的纤维中,乙烯醇系聚合物形成海相,卤化乙烯基系聚合物形成尺寸为0.1〜3μm的岛相。 乙烯醇系聚合物的结晶度为65〜85%。 聚乙烯醇类阻燃纤维可用于衣服,工业材料,生活材料等。 可以低成本生产,在热水中具有优异的纺丝稳定性和尺寸稳定性。

    Easily fibrillatable fiber
    5.
    发明授权
    Easily fibrillatable fiber 失效
    易纤维化纤维

    公开(公告)号:US5972501A

    公开(公告)日:1999-10-26

    申请号:US983133

    申请日:1998-01-20

    摘要: A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water.From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution.The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.

    摘要翻译: PCT No.PCT / JP96 / 01322 Sec。 371日期1998年1月20日 102(e)1998年1月20日PCT PCT 1996年5月20日PCT公布。 第WO97 / 44511号公报 日期1997年11月27日海岛相分离纤维,其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物,岛组分包含具有优异的碱溶液吸收性,耐热性的水不溶性纤维素基聚合物 耐热融合性,并且岛的尺寸为0.03〜10μm,强度为3g / d以上时,当施加机械应力时容易分解为直径为0.05〜8μm的原纤维 在水中浸湿纤维。 从具有良好亲水性,高强度,巨大的颗粒俘获和优异的增强性能的原纤维,另外具有良好的碱溶液吸收性和高耐热性和耐热熔性,其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板,水泥板状板的增强纤维,摩擦材料的增强纤维等。

    Water-soluble heat-press-bonding polyvinyl alcohol binder fiber of a
sea-islands structure
    7.
    发明授权
    Water-soluble heat-press-bonding polyvinyl alcohol binder fiber of a sea-islands structure 失效
    海岛结构的水溶性热压粘合聚乙烯醇粘合纤维

    公开(公告)号:US5486418A

    公开(公告)日:1996-01-23

    申请号:US322424

    申请日:1994-10-13

    IPC分类号: D01F8/10 D04H1/54 D02G3/04

    摘要: By mixing a high-melting polyvinyl alcohol type polymer (A) and a low-melting water-soluble polymer (B) in a solvent for the polymer (A) to prepare a spinning solution and then subjecting the solution to low-temperature spinning so that the resulting filaments are solidified uniformly in the cross-sectional direction, there is formed a fiber of sea-islands structure comprising said high-melting polyvinyl alcohol type polymer (A) as the sea component and said low-melting water-soluble polymer (B) as the islands component. In this fiber, at least part of the islands component is present in a fiber zone ranging from the fiber surface to 2 .mu.m inside and the fiber surface contains substantially no islands component. This fiber ordinarily shows the performance of the matrix phase, i.e. the performance of a high-melting polyvinyl alcohol fiber; however, when the fiber is pressurized at high temperatures, the low-melting polymer (the islands component) is pushed out onto the fiber surface and there occurs heat bonding between fibers. Owing to this property of the fiber, a nonwoven fabric can be produced advantageously from the fiber.

    摘要翻译: 通过在聚合物(A)的溶剂中混合高熔点聚乙烯醇型聚合物(A)和低熔点水溶性聚合物(B),制备纺丝溶液,然后使溶液进行低温纺丝 所得长丝在横截面方向上均匀地固化,形成海岛结构的纤维,其包含作为海成分的所述高熔点聚乙烯醇型聚合物(A)和所述低熔点水溶性聚合物( B)作为岛屿组成部分。 在该纤维中,至少部分岛成分存在于从纤维表面到内部2μm的纤维区域中,并且纤维表面基本上不含有岛成分。 该纤维通常表现出基质相的性能,即高熔点聚乙烯醇纤维的性能; 然而,当纤维在高温下加压时,低熔点聚合物(岛组分)被推出到纤维表面上,并且在纤维之间发生热粘合。 由于纤维的这种性质,可以有利地从纤维制造非织造织物。