-
公开(公告)号：US4578135A
公开(公告)日：1986-03-25
申请号：US576011
申请日：1984-02-01
申请人： Mitsushi Ueno , Tamotsu Shirogami , Noboru Segawa
发明人： Mitsushi Ueno , Tamotsu Shirogami , Noboru Segawa
CPC分类号： H01M2/1646 , H01M8/02 , H01M8/0293 , H01M2300/0005 , Y02P70/56
摘要： A method for manufacturing a fuel cell electrolyte matrix comprises the steps of providing a fuel electrode and oxidizing electrode respectively coated with a catalyst layer on one side, forming a layer of powdery electrolyte-resistive material on the surface of at least one of the catalyst layers, coating a paste layer prepared from acid electrolyte and powdery electrolyte-resistive material on the powder layer or catalyst layer of the fuel electrode and/or the powder layer or catalyst layer of the oxidizing electrode, tightly superposing the fuel electrode and oxidizing electrode on each other with the paste layer and powder layer interposed therebetween, thereby forming an electrolyte matrix between both electrodes.
-
公开(公告)号：US4661423A
公开(公告)日：1987-04-28
申请号：US816794
申请日：1986-03-10
申请人： Mitsushi Ueno , Tamotsu Shirogami , Noboru Segawa
发明人： Mitsushi Ueno , Tamotsu Shirogami , Noboru Segawa
CPC分类号： H01M8/08 , H01M8/0289 , Y02P70/56
摘要： A method for manufacturing a fuel cell electrolyte matrix comprises the steps of providing a fuel electrode and oxidizing electrode respectively coated with a catalyst layer on one side, forming a layer of powdery electrolyte-resistive material on the surface of at least one of the catalyst layers, coating a paste layer prepared from acid electrolyte and powdery electrolyte-resistive material on the powder layer or catalyst layer of the fuel electrode and/or the powder layer or catalyst layer of the oxidizing electrode, tightly superposing the fuel electrode and oxidizing electrode on each other with the paste layer and powder layer interposed therebetween, thereby forming an electrolyte matrix between both electrodes.
摘要翻译： 一种制造燃料电池电解质基质的方法包括以下步骤：在一侧上设置分别涂覆有催化剂层的燃料电极和氧化电极，在至少一个催化剂层的表面上形成粉末状电解质电阻材料层 将由酸性电解质和粉末状耐电解质材料制成的糊层涂覆在燃料电极的粉末层或催化剂层和/或氧化电极的粉末层或催化剂层上，将燃料电极和氧化电极紧密地叠加在每个 另外，其间插入有膏层和粉末层，从而在两个电极之间形成电解质基质。
-
公开(公告)号：US4461813A
公开(公告)日：1984-07-24
申请号：US440624
申请日：1982-11-10
申请人： Tamotsu Shirogami , Mitsushi Ueno
发明人： Tamotsu Shirogami , Mitsushi Ueno
CPC分类号： H01M8/2415
摘要： The invention provides an electrochemical power generator having a structure where a plurality of unit cells are stacked such that each pair of adjacent unit cells sandwich an interconnector therebetween. Each unit cell is formed such that an anode of a porous carbon substrate having an anode catalyst layer on one surface thereof and a cathode of a porous carbon fiber sheet having a cathode catalyst layer on one surface thereof sandwich a matrix layer containing an electrolyte solution of a concentrated acid solution therebetween so as to respectively bring the two surfaces of the matrix layer into tight contact with the anode and cathode catalyst layers. The interconnector is formed of a high density carbon plate. The electrochemical power generator uses as an anode reactant material a gas containing hydrogen as a major component, and uses as a cathode reactant material an oxidizing gas. The electrochemical power generator has excellent mechanical strength and may be efficiently and stably operated without deterioration over a long time. For this purpose, a plurality of grooves which function as a gas passage for the gas containing hydrogen as its major component are formed in the other surface of the anode, the cathode is thinner than the anode and is waterproofed, and a plurality of grooves which function as a gas passage for the oxidizing gas are formed in one surface of the interconnector.
摘要翻译： 本发明提供一种电化学发电机，其具有堆叠多个单电池的结构，使得每对相邻的单元电池在其间夹有互连器。 每个单电池被形成为使得在其一个表面上具有阳极催化剂层的多孔碳基板的阳极和在其一个表面上具有阴极催化剂层的多孔碳纤维板的阴极夹着包含电解质溶液的基质层 其间的浓酸溶液分别使基质层的两个表面与阳极和阴极催化剂层紧密接触。 互连器由高密度碳板形成。 电化学发电机使用含有氢作为主要成分的气体作为阳极反应物质，并用作阴极反应物质的氧化气体。 电化学发电机具有优异的机械强度，可长期有效且稳定地运行而不劣化。 为此，在阳极的另一个表面上形成有用作气体作为主要成分的气体的气体通路的多个槽，阴极比阳极薄，并且是防水的， 作为用于氧化气体的气体通道的功能形成在互连器的一个表面中。
-
公开(公告)号：US4515871A
公开(公告)日：1985-05-07
申请号：US523598
申请日：1983-08-16
申请人： Tamotsu Shirogami , Mitsushi Ueno
发明人： Tamotsu Shirogami , Mitsushi Ueno
CPC分类号： H01M8/2415 , H01M4/96 , H01M8/0271 , H01M8/0289
摘要： An electrochemical power generator is disclosed which is composed of a plurality of unit cells stacked with interconnectors interposed therebetween; said unit cells being each composed of an anode consisting of a porous carbon plate having on its one surface a plurality of grooves constituting gas passages and on its other surface an anode catalyst layer; a cathode formed on its one surface with a cathode catalyst layer and applied on its other surface a hydrophobic material powder consisting of fluoropolymer resin; and an electrolyte layer interposed between the anode and the cathode in such a manner that its two surfaces are allowed to come into contact, respectively; said anode catalyst layer and said cathode catalyst layer, the electrolyte layer being prepared by causing an acidic electrolyte to be impregnated into an inorganic compound powder having heat resistance and chemical resistance; the interconnectors being each compressed of a high density carbon plate and having, on each surface coming into contact with the cathode, a plurality of grooves for gas passages, being used as an anode-active material, of a gas consisting mainly of hydrogen and, as a cathode-active material, of an oxidizing gas. First ribs and second ribs wider than said first ribs are formed between adjacent ones of the grooves of the anode substrate, and a catalyst is dispersed in the cathode substrate over a range extending from a boundary between a surface of contact of the cathode substrate with the cathode catalyst layer up to a point located inside the cathode substrate.
摘要翻译： 公开了一种电化学发电机，其由多个单元电池组成，多个单电池堆叠在其间插入有互连器件; 所述单元电池各自由多孔碳板构成的阳极组成，所述多孔碳板在其一个表面上具有构成气体通道的多个槽，在其另一个表面上具有阳极催化剂层; 在其一个表面上形成有阴极催化剂层的阴极，并在其另一个表面上施加由含氟聚合物树脂组成的疏水性材料粉末; 以及插入在阳极和阴极之间的电解质层，使得其两个表面分别被接触; 所述阳极催化剂层和所述阴极催化剂层，所述电解质层通过使酸性电解质浸渍到具有耐热性和耐化学性的无机化合物粉末中而制备; 互连器各自被压缩成高密度碳板，并且在与阴极接触的每个表面上具有主要由氢组成的气体的用作气体通道的多个用作阳极活性材料的槽， 作为阴极活性物质的氧化气体。 在阳极基板的相邻槽之间形成有比所述第一肋宽的第一肋和第二肋，并且在从阴极基板的接触面与边界的边界延伸的范围内将催化剂分散在阴极基板中 阴极催化剂层直到位于阴极衬底内的点。
-
公开(公告)号：US4555324A
公开(公告)日：1985-11-26
申请号：US607786
申请日：1984-05-07
CPC分类号： H01M8/0271 , H01M12/02 , H01M2/08
摘要： A porous gas diffusion electrode for use in an air-metal cell or a hydrogen-air (oxygen) cell comprising an electroconductive porous substrate, which has itself on one surface thereof reaction gas feed channels or is to be used with one surface in contact with reaction gas feed channels during use, and which comprises gas impermeable and electrically insulating seals formed of a tetrafluoroethylene-perfluoroalkyl vinyl ether compolymer provided on the substrate at least at both end portions parallel to said reaction gas feed channels, is capable of positively shielding the gas streams at the end portions parallel to the reaction gas feed channels and maintaining electrical insulation.Such a porous gas diffusion electrode can be prepared by a method comprising applying a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer on the substrate at least at the end portions parallel to the reaction gas feed channels and then subjecting the substrate coated with the copolymer to hot pressure bonding by means of a pressure bonding tool made of a metal previously coated with a fluoride oil to form gas impermeable and electrically insulating seals comprising said copolymer.
摘要翻译： 一种用于空气 - 金属电池或氢 - 空气（氧气）电池的多孔气体扩散电极，其特征在于，包括导电性多孔质基材，该导电性多孔基材的一个表面上具有反应气体供给通道，或者与一个与 反应气体供给通道在使用过程中至少在平行于反应气体进料通道的两个端部处设置在基板上的由四氟乙烯 - 全氟烷基乙烯基醚共聚物形成的气体不可渗透和电绝缘的密封件能够积极地屏蔽气体 在与反应气体供给通道平行的端部处的气流并保持电绝缘。 这样的多孔气体扩散电极可以通过以下方法制备：至少在与反应气体进料通道平行的端部处在基材上施加四氟乙烯 - 全氟烷基乙烯基醚共聚物，然后使用共聚物涂布的基材进行热压粘合 通过由预先涂覆有氟化油的金属制成的压接工具，以形成包含所述共聚物的气体不可渗透和电绝缘密封。
-
公开(公告)号：US4766043A
公开(公告)日：1988-08-23
申请号：US009918
申请日：1987-02-02
申请人： Tamotsu Shirogami , Mitsushi Ueno
发明人： Tamotsu Shirogami , Mitsushi Ueno
CPC分类号： H01M8/04283 , H01M8/2415
摘要： In a fuel cell according to the present invention, a plurality of unit cells each includes an anode and a cathode, each formed of a porous substrate, and an electrolyte matrix layer interposed between the anode and the cathode. A fuel gas channel is formed on one surface of the anode that is located on the side opposite to the electrolyte matrix layer, and an electrolyte-solution permeable portion is formed on the same surface of the anode. The unit cells are stacked in layers, and a plurality of separator elements are interposed between the adjacent unit cells to form a stacked structure. Each of the separator elements has a recess formed on its surface that is located on the side facing the anode. The recess serves to store an electrolyte solution and contain the electrolyte-solution permeable portion. Thus, if an electrolyte solution, with which the electrolyte matrix layer is impregnated, is reduced, the solution stored in the recess permeates the matrix layer, flowing through the permeable portion. As a result, the voltage of the fuel cell is prevented from dropping, thus permitting a prolonged continuous operation of the fuel cell.
摘要翻译： 在根据本发明的燃料电池中，多个单电池各自包括阳极和阴极，每个阳极和阴极由多孔基底和介于阳极和阴极之间的电解质基质层形成。 在位于与电解质基体层相反的一侧的阳极的一个表面上形成燃料气体通道，在阳极的同一表面上形成电解质溶液渗透部。 单元电池堆叠在一起，并且在相邻的单元电池之间插入多个隔板元件以形成堆叠结构。 每个分离器元件在其表面上形成有位于面向阳极的一侧上的凹部。 凹槽用于储存电解质溶液并容纳电解质溶液渗透部分。 因此，如果电解质基质层被浸渍的电解质溶液被还原，则储存在凹槽中的溶液渗入基质层，流过可渗透部分。 结果，能够防止燃料电池的电压下降，能够延长燃料电池的连续运转。
-
公开(公告)号：US4478918A
公开(公告)日：1984-10-23
申请号：US449998
申请日：1982-12-15
申请人： Mitsushi Ueno , Tadanori Maoka , Kenji Murata , Tamotsu Shirogami
发明人： Mitsushi Ueno , Tadanori Maoka , Kenji Murata , Tamotsu Shirogami
CPC分类号： H01M8/04074 , H01M8/04
摘要： A fuel cell stack has a plurality of stacked unit cells, each consisting of a pair of gas diffusion electrodes with a matrix containing an electrolyte solution interposed between them, with an interconnector having a fuel gas passage on one surface and an oxidizing gas agent passage on the other surface interposed between each pair of adjacent unit cells. One out of every three to five interconnectors is a one-piece-molded product which has at least one cooling pipe embedded in it and which provides an excellent cooling effect. The fuel cell stack stably provides a high output voltage over a long period of operation time.
摘要翻译： 燃料电池堆具有多个层叠的单元电池，每个单元电池由一对气体扩散电极组成，该气体扩散电极具有介于其间的电解质溶液的基体，具有在一个表面上具有燃料气体通道的互连器和在一个表面上的氧化剂气体通道 插入在每对相邻单元电池之间的另一表面。 每三到五个互连器中的一个是一体式成型产品，其中至少有一个冷却管嵌入其中，并提供优异的冷却效果。 燃料电池堆在长时间的运行时间内稳定地提供高输出电压。
-
公开(公告)号：US4143212A
公开(公告)日：1979-03-06
申请号：US842889
申请日：1977-10-17
申请人： Mitsushi Ueno , Tamotsu Shirogami
发明人： Mitsushi Ueno , Tamotsu Shirogami
CPC分类号： G01R31/3665 , H01M10/34 , H01M10/42 , H02J7/0077
摘要： A sealed storage battery comprising a sealed container, an electricity generating means contained in the sealed container and composed of a positive electrode, a negative electrode and an electrolyte, a hydrogen gas oxidation auxiliary electrode disposed within the sealed container, and a resistance means connected to the auxiliary electrode and having an inverse current checking characteristic (or property).In this sealed storage battery, the (critical) point of time of overcharging in charging the sealed storage battery may be detected by monitoring the variation of the voltage between the positive electrode or a separately provided measurement electrode and the auxiliary electrode.
-
公开(公告)号：US3951687A
公开(公告)日：1976-04-20
申请号：US525667
申请日：1974-11-20
CPC分类号： H01M2/16 , H01M10/30 , H01M2/162 , H01M4/244 , Y02E60/124
摘要： Provided is a nickel-zinc storage battery prepared, preferably, by winding into a whirlpool a sheet-like zinc electrode, a sheet-like nickel electrode and a separator with the separator interposed between the zinc and nickel electrodes, said zinc electrode being obtained by bonding under pressure to a collector a mixture sheet consisting of zinc oxide, zinc, bismuth oxide, calcium hydroxide and fluoroplastic, said nickel electrode being obtained by bonding under pressure an oxide of nickel to a collector together with a conductive material, said separator being obtained by coating on an alkali-resisting nonwoven fabric a mixture of polyvinyl alcohol and at least either of one selected from the group consisting of boric acids and metal oxides having low solubility to alkali solution and drying the nonwoven fabric thus coated.
摘要翻译： 本发明提供一种镍锌蓄电池，优选通过将片状锌电极，片状镍电极和带状隔膜夹在锌电极和镍电极之间的隔膜中，将锌离子和 在氧化锌，锌，氧化铋，氢氧化钙和氟塑料组成的混合物片上，在压力下接合所述镍电极，所述镍电极是通过在压力下将镍的氧化物与导电材料一起接合到集电体而得到的， 通过在耐碱性无纺布上涂布聚乙烯醇和选自硼酸和碱溶液溶解度低的金属氧化物中的至少一种的混合物，并干燥所涂覆的无纺布。
-
公开(公告)号：US4708916A
公开(公告)日：1987-11-24
申请号：US927942
申请日：1986-11-07
申请人： Takashi Ogawa , Tamotsu Shirogami , Kenji Murata
发明人： Takashi Ogawa , Tamotsu Shirogami , Kenji Murata
CPC分类号： H01M8/0206 , H01M8/142 , H01M8/244 , H01M2008/147 , H01M2300/0051 , H01M8/0208 , H01M8/021 , H01M8/0228 , Y02E60/526
摘要： In a stacked structure for forming a molten carbonate fuel cell according to the present invention, a plurality of unit cells are stacked, and separator elements are respectively interposed between the adjacent unit cells. First and second internal manifolds extend in the stacking direction, at both sides of the stacked structure. Third internal manifold extends at the center of the structure, in the direction of stacking. First fuel gas passages, communicating with the first and third internal manifolds, are formed at the anode side of the separator element. Second fuel gas passages, communicating with the second and third internal manifolds, are formed at the anode side of the separator element. Thus, the fuel gas flows through the first internal manifold, the first fuel gas passages and the third internal manifold, and the fuel gas flows through the second internal manifold, the second fuel gas passages and the third internal manifold. As a result, the current density distribution and the temperature distribution are uniform.
摘要翻译： 在根据本发明的用于形成熔融碳酸盐燃料电池的堆叠结构中，堆叠多个单元电池，并且分离器元件分别插入在相邻单元电池之间。 第一和第二内部歧管在层叠结构的两侧沿层叠方向延伸。 第三内部歧管在结构的中心沿堆叠方向延伸。 与分离器元件的阳极侧形成有与第一和第三内部歧管连通的第一燃料气体通道。 与分离器元件的阳极侧形成有与第二和第三内部歧管连通的第二燃料气体通道。 因此，燃料气体流过第一内部歧管，第一燃料气体通道和第三内部歧管，并且燃料气体流过第二内部歧管，第二燃料气体通道和第三内部歧管。 结果，电流密度分布和温度分布均匀。
-
-
-
-
-
-
-
-
-
搜索结果
13 条记录 (耗时 0.018 秒)
