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    Process for the treatment of light naphtha hydrocarbon streams
    3.
    发明授权
    Process for the treatment of light naphtha hydrocarbon streams 有权
    用于处理轻石脑油烃流的方法

    公开(公告)号：US07153415B2

    公开(公告)日：2006-12-26

    申请号：US10285852

    申请日：2002-11-01

    申请人： Gary G. Podrebarac ,  Willibrord A. Groten ,  Manoj Som ,  Martinus J. Almering

    发明人： Gary G. Podrebarac ,  Willibrord A. Groten ,  Manoj Som ,  Martinus J. Almering

    IPC分类号： C10G45/00 ,  C10G29/20

    CPC分类号： C10G45/02 ,  C10G2400/02

    摘要： A light cracked naphtha is treated to convert mercaptans to sulfides and saturate dienes and then subjected to destructive hydrodesulfurization (HDS) to convert the organic sulfur compounds to hydrogen sulfide. The recombinant mercaptans formed by reaction of hydrogen sulfide and olefins at the outlet of the HDS are generally heavier than the light cracked naphtha is fractionated in admixture with a heavy cracked naphtha. A low sulfur content light cracked naphtha is produced as an overheads and the major portion of the mercaptans leave with heavy cracked naphtha as bottoms. It also advantageous to pass the heavy cracked naphtha through the HDS in admixture with the light cracked naphtha, since the recombinant mercaptans formed with the heavy cracked naphtha olefins (which displace some of the lower mercaptans which would form the light cracked naphtha olefins) will be even higher boiling and easier to separate by fractionation.

    摘要翻译： 处理轻质裂解石脑油，将硫醇转化为硫化物，饱和二烯，然后进行破坏性加氢脱硫（HDS），将有机硫化合物转化为硫化氢。 在HDS出口处通过硫化氢和烯烃的反应形成的重组硫醇通常比轻质裂化石脑油与重质裂解石脑油混合分馏更重。 产生低硫含量的轻质裂化石脑油作为塔顶馏出物，硫醇的主要部分以重的裂解石脑油为底部。 由于与重质裂解石脑油烯烃（其将形成轻质裂化石脑油烯烃的一部分低级硫醇取代）形成的重组硫醇将是重要的硫醇与轻质裂化石脑油混合，所以将重质裂解石脑油与HDS混合也是有利的 甚至更高沸点，更容易通过分馏分离。

    Process for the selective desulfurization of a mid range gasoline cut
    4.
    发明授权
    Process for the selective desulfurization of a mid range gasoline cut 有权
    中程汽油切割的选择性脱硫工艺

    公开(公告)号：US07351327B2

    公开(公告)日：2008-04-01

    申请号：US10820399

    申请日：2004-04-07

    申请人： Gary G. Podrebarac ,  Willibrord A. Groten ,  Lawrence A. Smith, Jr.

    发明人： Gary G. Podrebarac ,  Willibrord A. Groten ,  Lawrence A. Smith, Jr.

    IPC分类号： C10G45/04 ,  C10G45/32

    CPC分类号： C10G65/02 ,  C10G2300/4087 ,  C10G2400/02

    摘要： A process for concurrently fractionating and treating a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans is passed on to a polishing hydrodesulfurization reactor where a low sulfur, low olefin gas oil is concurrently fed to the polishing reactor to insure that a liquid phase is present.

    摘要翻译： 一种同时分馏和处理全程石脑油流的方法。 全沸点石脑油流首先进行同时硫代醚化并分裂成轻沸石石脑油，中沸程石脑油和重沸石石脑油。 含有噻吩和噻吩沸点范围的硫醇的中沸程石脑油被传递到抛光加氢脱硫反应器，其中低硫低烯烃瓦斯油同时进料到抛光反应器以确保存在液相。

    Etherification process
    5.
    发明授权
    Etherification process 失效
    醚化过程

    公开(公告)号：US06232509B1

    公开(公告)日：2001-05-15

    申请号：US09591520

    申请日：2000-06-09

    申请人： Lawrence A. Smith, Jr. ,  Henry J. Semerak ,  Willibrord A. Groten

    发明人： Lawrence A. Smith, Jr. ,  Henry J. Semerak ,  Willibrord A. Groten

    IPC分类号： C07C4109

    CPC分类号： C07C41/06 ,  B01D3/009 ,  C07C41/42 ,  Y02P20/127 ,  C07C43/046

    摘要： A process for the separation and recovery of methyl tertiary butyl ether from mixed C4/C5 streams, such as resulting from the co-production of methyl tertiary butyl ether and tertiary amyl methyl ether from the reaction of methanol with isobutene and isoamylenes in a mixed C4/C5 stream. In a distillation column reactor the reaction is carried out concurrently with distillation of the products from the unreacted materials. In the distillation little or no MTBE is carried overhead with the unreacted C4's, C5's and methanol by controlling the methanol concentration in said column to maintain substantially a methanol/C5 azeotrope in the overheads.

    摘要翻译： 从混合的C4 / C5流中分离和回收甲基叔丁基醚的方法，例如由甲醇与异丁烯和异戊烯在混合C4中的反应中共同生产甲基叔丁基醚和叔戊基甲基醚 / C5流。 在蒸馏塔反应器中，反应与来自未反应物质的产物蒸馏同时进行。 在蒸馏中，通过控制所述塔中的甲醇浓度，很少或没有MTBE与未反应的C4，C5和甲醇一起承载，从而在塔顶馏出物中维持基本上甲醇/ C5共沸物。

    Process and apparatus for catalytic distillations
    7.
    发明授权
    Process and apparatus for catalytic distillations 有权

    公开(公告)号：US07030277B2

    公开(公告)日：2006-04-18

    申请号：US10839401

    申请日：2004-05-05

    申请人： Willibrord A. Groten ,  Mario J. Maraschino

    发明人： Willibrord A. Groten ,  Mario J. Maraschino

    IPC分类号： C07C319/00 ,  C07C41/05 ,  C07C41/06 ,  B01D3/34

    CPC分类号： B01D3/141 ,  B01D3/009 ,  C07C2/06 ,  C07C2/66 ,  C07C5/03 ,  C07C5/10 ,  C07C5/23 ,  C07C5/2506 ,  C07C5/27 ,  C07C41/06 ,  C07C41/42 ,  C07C319/18 ,  Y02P20/127 ,  C07C43/046

    摘要： A process for reacting a first component with itself or a second component to produce a third component in which a first material comprising a first component or said first component and a second component is fed to divided wall column having a catalytic distillation structure in at least one of the separate vertical sections of the divided wall column where concurrently: (1) a first component alone or with a second component is contacted with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the first component with itself or with the second component to form a product and (2) a first mixture comprising the first component and the product or the first component, the second component and the product; and withdrawing the product from the distillation column reactor; while within the column concurrently with the catalytic reaction and fractionation a second mixture is fractionated, which contains the first component and the product or first and second components (if a second component is present) and the product in a parallel and separate distillation non reaction zone to fractionate the product and withdrawing the product from said distillation non reaction zone. For example, tertiary amyl methyl ether may be prepared by reacting methanol with isoamylene in a C5 stream utilizing a distillation column reactor wherein the distillation column reactor comprises one side of a divided wall column. On one side the product, tertiary amyl methyl ether, is separated from the unreacted methanol and C5's and on the other side the remaining isoamylenes are reacted with methanol and a separation of the tertiary amyl methyl ether and C5's from the methanol/C5 azeotrope is effected.

    Process for desulfurization of cracked naphtha
    8.
    发明授权
    Process for desulfurization of cracked naphtha 失效
    裂化石脑油脱硫工艺

    公开(公告)号：US06946068B2

    公开(公告)日：2005-09-20

    申请号：US09877277

    申请日：2001-06-08

    申请人： Willibrord A. Groten

    发明人： Willibrord A. Groten

    IPC分类号： B01J23/44 ,  B01J23/755 ,  B01J23/882 ,  C10G7/00 ,  C10G45/02 ,  C10G45/08 ,  C10G45/10 ,  C10G45/32 ,  C10G45/40 ,  C10G45/04 ,  B01D3/34

    CPC分类号： C10G45/08 ,  B01J23/44 ,  B01J23/755 ,  B01J23/882 ,  C10G7/00 ,  C10G45/02 ,  C10G45/10 ,  C10G45/32 ,  C10G45/40 ,  C10G2300/4087

    摘要： A process for concurrently fractionating and hydrotreating of a full range naphtha stream. The full boiling range naphtha stream, for example which is derived from fluid catalytic cracking, is first subjected to simultaneous hydrogenation of the thiophene contained therein and thioetherification and fractionation to remove the mercaptans the light fraction and then to simultaneous hydrodesulfurization and splitting of the bottoms into an intermediate boiling range naphtha and a heavy boiling range naphtha. The three boiling range naphthas are treated separately according to the amount of sulfur in each cut and the end use of each fraction.

    摘要翻译： 一种用于同时分馏和加氢处理全程石脑油流的方法。 首先对来自流化催化裂化的全沸点石脑油流进行同时氢化其中所含的噻吩和硫醚化和分馏以除去轻馏分的硫醇，然后同时加氢脱硫和将塔底分解成 中间沸点石脑油和重沸点石脑油。 根据每个切割中的硫量和每个馏分的最终使用，分别处理三个沸点范围的石脑油。

    Process and apparatus for catalytic distillations
    9.
    发明授权
    Process and apparatus for catalytic distillations 有权
    催化蒸馏工艺和设备

    公开(公告)号：US06930206B1

    公开(公告)日：2005-08-16

    申请号：US10167196

    申请日：2002-06-11

    申请人： Willibrord A. Groten ,  Mario J. Maraschino

    发明人： Willibrord A. Groten ,  Mario J. Maraschino

    IPC分类号： B01D3/00 ,  C07C2/06 ,  C07C2/66 ,  C07C5/03 ,  C07C5/10 ,  C07C5/23 ,  C07C5/25 ,  C07C5/27 ,  C07C41/06 ,  C07C41/42 ,  C07C319/18 ,  C07C319/00 ,  B01D3/34 ,  C07C41/05

    CPC分类号： B01D3/141 ,  B01D3/009 ,  C07C2/06 ,  C07C2/66 ,  C07C5/03 ,  C07C5/10 ,  C07C5/23 ,  C07C5/2506 ,  C07C5/27 ,  C07C41/06 ,  C07C41/42 ,  C07C319/18 ,  Y02P20/127 ,  C07C43/046

    摘要： A process for reacting a first component with itself or a second component to produce a third component in which a first material comprising a first component or said first component and a second component is fed to divided wall column having a catalytic distillation structure in at least one of the separate vertical sections of the divided wall column where concurrently: (1) a first component alone or with a second component is contacted with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the first component with itself or with the second component to form a product and (2) a first mixture comprising the first component and the product or the first component, the second component and the product; and withdrawing the product from the distillation column reactor; while within the column concurrently with the catalytic reaction and fractionation a second mixture is fractionated, which contains the first component and the product or first and second components (if a second component is present) and the product in a parallel and separate distillation non reaction zone to fractionate the product and withdrawing the product from said distillation non reaction zone. For example, tertiary amyl methyl ether may be prepared by reacting methanol with isoamylene in a C5 stream utilizing a distillation column reactor wherein the distillation column reactor comprises one side of a divided wall column. On one side the product, tertiary amyl methyl ether, is separated from the unreacted methanol and C5's and on the other side the remaining isoamylenes are reacted with methanol and a separation of the tertiary amyl methyl ether and C5's from the methanol/C5 azeotrope is effected.

    摘要翻译： 一种使第一组分与其自身或第二组分反应以产生第三组分的方法，其中将包含第一组分或所述第一组分的第一组分或第二组分加入到具有催化蒸馏结构的至少一种 的分隔壁柱的单独的竖直部分，其中同时：（1）单独的第一组分或与第二组分的第一组分在蒸馏反应区中与催化蒸馏结构接触，从而使第一组分的至少一部分与其自身的催化反应 或与第二组分形成产物和（2）包含第一组分和产物或第一组分，第二组分和产物的第一混合物; 并从蒸馏塔反应器中取出产物; 同时在塔内同时进行催化反应和分馏，将第二混合物分馏，其含有第一组分和产物或第一和第二组分（如果存在第二组分），并且产物在平行和分离的蒸馏非反应区 以分馏产物并从所述蒸馏非反应区抽出产物。 例如，叔戊基甲基醚可以通过使用蒸馏塔反应器的甲醇与C 6 C 5流中的异戊烯反应制备，其中蒸馏塔反应器包括分隔壁塔的一侧。 一方面，将产物叔戊基甲基醚与未反应的甲醇和C 5 S分离，另一侧将剩余的异戊烯与甲醇反应并分离叔戊基甲基醚 和来自甲醇/ C 5 H 3共沸物的C 5 S 5。