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1.发明申请公开(公告)号：US20180195997A1
公开(公告)日：2018-07-12
申请号：US15708855
申请日：2017-09-19
IPC分类号： G01N27/414 , H01L51/05 , H01L51/00 , C01B32/159
CPC分类号： G01N27/4141 , C01B32/159 , C01B2202/02 , C08G73/0644 , G01N27/4146 , H01L51/0002 , H01L51/0003 , H01L51/0025 , H01L51/0026 , H01L51/0048 , H01L51/0545 , H01L51/0558 , H01L51/0566
摘要： A process for purifying semiconducting single-walled carbon nanotubes (sc-SWCNTs) extracted with a conjugated polymer, the process comprising exchanging the conjugated polymer with an s-tetrazine based polymer in a processed sc-SWCNT dispersion that comprises the conjugated polymer associated with the sc-SWCNTs. The process can be used for production of thin film transistors and chemical sensors. In addition, disclosed herein is use of an s-tetrazine based polymer for purification of semiconducting single-walled carbon nanotubes (sc-SWCNTs).
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公开(公告)号：US20210301166A1
公开(公告)日：2021-09-30
申请号：US17265572
申请日：2019-08-02
发明人： Xiangyang LIU , Jianfu DING , Patrick Roland Lucien MALENFANT , Chantal PAQUET , Bhavana DEORE , Arnold J. KELL
IPC分类号： C09D11/52 , H01B1/22 , C09D11/033 , C09D11/101
摘要： A printable molecular ink that is can be treated (e.g. dried or curable) and sintered using broad spectrum ultraviolet light is provided to produce electrically conductive traces on a low temperature substrate, for example PET. The ink includes a silver or copper carboxylate, an organic amine compound, and may include a thermal protecting agent.
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公开(公告)号：US20240341108A1
公开(公告)日：2024-10-10
申请号：US18293522
申请日：2022-08-08
发明人： Zhao LI , Jianying OUYANG , Jianfu DING , Patrick R. L. MALENFANT
IPC分类号： H10K30/65 , H10K30/80 , H10K71/13 , H10K71/40 , H10K85/20 , H10K101/30 , H10K101/40
CPC分类号： H10K30/65 , H10K30/865 , H10K71/13 , H10K71/40 , H10K85/211 , H10K85/221 , H10K2101/30 , H10K2101/40
摘要： A composition for use in a photo-active device has: a charge transfer network of single walled carbon nanotubes (SWCNT) having at least 95 wt % of semiconducting single walled carbon nanotubes (sc-SWCNT) based on total weight of the SWCNT, the sc-SWCNT containing at least 30 wt % of one chiral type of sc-SWCNT based on total weight of the sc-SWCNT; and, a solution processible electron trapping material of a fullerene compound, the electron trapping material in contact with the charge transfer network of SWCNT. The composition is readily prepared from solution processible components and is highly sensitive in a narrow wavelength band. The composition is particularly useful in photoconductors and phototransistors that operate on the infrared region of the electromagnetic spectrum.
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公开(公告)号：US20190010342A1
公开(公告)日：2019-01-10
申请号：US16068298
申请日：2016-04-19
发明人： Jianfu DING , Zhao LI , Patrick MALENFANT
IPC分类号： C09D11/03 , C09D11/102 , C09D11/52 , C01B32/159 , C08G61/02 , C08L65/00 , C08K3/04 , H05K1/09
摘要： A single-walled carbon nanotube composition includes single-walled carbon nanotubes substantially enriched in semiconducting single-walled carbon nanotubes in association with a polymer having one or more oligoether side groups. The oligoether side groups render the composition dispersable in polar organic solvents, for example alkyl carbitols, permitting formulation of ink compositions containing single-walled carbon nanotubes substantially enriched in semiconducting single-walled carbon nanotubes. Such ink compositions may be readily printed using common printing methods, such as inkjet, flexography and gravure printing.
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5.发明申请公开(公告)号：US20180198065A1
公开(公告)日：2018-07-12
申请号：US15401421
申请日：2017-01-09
CPC分类号： H01L51/0003 , C08G61/122 , C08G61/123 , C08G61/125 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/228 , C08G2261/3221 , C08G2261/3222 , C08G2261/3223 , C08G2261/3243 , C08G2261/3247 , C08G2261/92 , H01L51/0048 , H01L51/0558
摘要： A process for purifying semiconducting single-walled carbon nanotubes (sc-SWCNTs) extracted with a conjugated polymer, the process comprising exchanging the conjugated polymer with an s-tetrazine based polymer in a processed sc-SWCNT dispersion that comprises the conjugated polymer associated with the sc-SWCNTs. The process can be used for production of thin film transistors. In addition, disclosed herein is use of an s-tetrazine based polymer for purification of semiconducting single-walled carbon nanotubes (sc-SWCNTs).
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公开(公告)号：US20230271838A1
公开(公告)日：2023-08-31
申请号：US18112751
申请日：2023-02-22
发明人： Jianfu DING , Zhao LI , Chang GUO , Francois LAPOINTE , Jianying OUYANG , Patrick Roland Lucien MALENFANT
IPC分类号： C01B32/174 , B82Y30/00 , B82Y40/00 , G01N27/30
CPC分类号： C01B32/174 , B82Y30/00 , B82Y40/00 , G01N27/308 , C01B2202/02
摘要： A composite material suitable for use in sensing and catalysis applications with conjugated polymers non-covalently bound to the carbon nanotubes. The conjugated polymers have alternating aromatic (Ar) units and bipyridine (BPy) units. Metal nanoparticles having a size that is between about 0.3 nm and about 5 nm are bound to the conjugated polymers at respective BPy units, thereby anchoring the metal nanoparticles to the carbon nanotubes. Thus, a metal salt solution was added into the polymer/carbon nanotube solution to form a metal-BPy complex, which is in situ photo reduced to metal nanoparticles. Therefore, the formed nanoparticles are tightly anchored to the nanotube and can be self-regenerated by room light to offer the material a high performance and durability.
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公开(公告)号：US20210293734A1
公开(公告)日：2021-09-23
申请号：US17267184
申请日：2019-08-13
IPC分类号： G01N27/12 , C08G61/12 , C01B32/174 , C01B32/172
摘要： A compound of Formula (0): where Ar is one or more substituted or unsubstituted aromatic units, R is independently H, F, CN, a C1-C20 linear or branched aliphatic group or a C1-C20 linear or branched aliphatic acyl group, and n is an integer 3 or greater, is useful for sorting and dispersing carbon nanotubes (CNTs) and for producing printed electronic devices (e.g. CO2 sensors, TFTs) in which the CNTs are functionalized with the compound.
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公开(公告)号：US20200317937A1
公开(公告)日：2020-10-08
申请号：US16907409
申请日：2020-06-22
发明人： Jianfu DING , Zhao LI , Patrick MALENFANT
IPC分类号： C09D11/03 , C09D11/52 , C09D11/102 , C08G61/02 , H05K1/09 , C01B32/159 , C08G61/12 , C01B32/172 , C09D11/037 , H01B1/24 , C08K3/04 , C08L65/00
摘要： A single-walled carbon nanotube composition includes single-walled carbon nanotubes substantially enriched in semiconducting single-walled carbon nanotubes in association with a polymer having one or more oligoether side groups. The oligoether side groups render the composition dispersable in polar organic solvents, for example alkyl carbitols, permitting formulation of ink compositions containing single-walled carbon nanotubes substantially enriched in semiconducting single-walled carbon nanotubes. Such ink compositions may be readily printed using common printing methods, such as inkjet, flexography and gravure printing.
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公开(公告)号：US20180354799A1
公开(公告)日：2018-12-13
申请号：US15618242
申请日：2017-06-09
IPC分类号： C01B32/159 , C08F32/08 , C08F36/04
CPC分类号： C01B32/159 , B82Y30/00 , C01B2202/02 , C07C211/02 , C07D213/06 , C08F32/08 , C08F36/04
摘要： Processes for selectively dispersing semi-conducting single-walled carbon nanotubes (sc-SWCNTs) in a solvent. One process comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs, in which the amine partially displaces the conjugate polymer associated with the sc-SWNTs dispersed in the solvent. Another process comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs, with the proviso that the amine excludes EDTA. Also, a process for displacement of a conjugated polymer from the surface of semi-conducting single-walled carbon nanotubes (sc-SWCNTs) dispersed in a solvent, which comprises adding an amine either: to a conjugated polymer extraction process (CPE) of the sc-SWCNTs; or after the CPE of the sc-SWCNTs.
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10.发明申请公开(公告)号：US20180346335A1
公开(公告)日：2018-12-06
申请号：US15612538
申请日：2017-06-02
IPC分类号： C01B32/159 , B01D11/02
CPC分类号： C01B32/159 , B01D11/0288 , C01B2202/02 , C01B2202/22
摘要： A method for modulation of yield and semiconducting (sc)-purity of single-walled carbon nanotubes (SWCNTs) in a conjugated polymer extraction (CPE) process, the method comprising addition of an n-type dopant or a p-type dopant to the CPE process, wherein: the n-type dopant has a reduction potential of between −4.2 eV and −3.0 eV; and the p-type dopant has a reduction potential of between −6.0 eV and −4.5 eV.
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