摘要:
Provided is a composite particle which can improve the capacity per volume and charge-discharge cycle characteristics. The composite particle includes a plurality of specific particles and a binding material. The specific particle contains an alloy phase. The alloy phase undergoes thermoelastic diffusionless transformation when releasing metal ions or occluding metal ions. The binding material contains at least one of non-graphite carbon and a carbon precursor. The plurality of specific particles bind with each other via the binding material.
摘要:
Provided is a negative electrode active material that can improve the discharge capacity per volume and charge-discharge cycle characteristics. The negative electrode active material according to the present embodiment contains an alloy phase. The alloy phase undergoes thermoelastic diffusionless transformation when releasing metal ions or occluding metal ions. The oxygen content of the negative electrode active material is not more than 5000 ppm in mass.
摘要:
An electrode containing a clathrate compound is disclosed that is more likely to withstand load involved in repetition of penetration and desorption of, e.g., lithium ions compared to no guest substance-encapsulating silicon clathrate compounds. An electrode active material making up the electrode according to the present invention includes a clathrate compound. The clathrate compound contains a crystal lattice and a guest substance. The guest substance is encapsulated in the crystal lattice. It is preferable that the clathrate compound be a main component of the electrode active material that makes up the electrode.
摘要:
Provided is an electrode active material containing a clathrate compound that is more likely to withstand load involved in repetition of penetration and desorption of, e.g., lithium ions compared to no guest substance-encapsulating silicon clathrate compounds. An electrode active material according to the present invention includes a clathrate compound. The clathrate compound contains a crystal lattice and a guest substance. The guest substance is encapsulated in the crystal lattice. It is preferable that the clathrate compound be a main component of the electrode active material.
摘要:
A negative electrode active material is provided that is utilized in a nonaqueous electrolyte secondary battery, and that can improve the capacity per volume and charge-discharge cycle characteristics. The negative electrode active material according to the present embodiment contains an alloy having a chemical composition consisting of, in at %, Sn: 13.0 to 24.5% and Si: 3.0 to 15.0%, with the balance being Cu and impurities. The alloy particles contain a phase with a peak of the most intense diffraction line appearing in a range of 42.0 to 44.0 degrees of a diffraction angle 2θ, the most intense diffraction line being a diffraction line having the largest integrated diffraction intensity in an X-ray diffraction profile. A half-width of the most intense diffraction line of the alloy particles is in a range of 0.15 to 2.5 degrees.
摘要:
Provided is a negative electrode active material that can improve the discharge capacity per volume and charge-discharge cycle characteristics. The negative electrode active material of the present embodiment includes a powder material and an oxide layer. The powder material contains an alloy phase which undergoes thermoelastic diffusionless transformation when releasing metal ions or occluding the metal ions. The oxide layer is formed on the surface of the powder material, and has a thickness of not more than 10 nm.
摘要:
Provided is a negative electrode active material which can improve discharge capacity per amount and charge-discharge cycle characteristics. The negative electrode active material of the present embodiment contains at least one of material A and material B, and material C: material A: carbonaceous powder material in which a ratio of a peak intensity at 1360 cm−1 with respect to a peak intensity at 1580 cm−1 in the Raman spectrum is not more than 0.5; material B: carbonaceous powder material in which a ratio of a peak intensity at 1360 cm−1 with respect to a peak intensity at 1580 cm−1 in the Raman spectrum is more than 0.5; material C: powder material whose main component is an active substance made up of an alloy phase. This alloy phase undergoes thermoelastic diffusionless transformation when releasing metal ions or occluding the metal ions.
摘要:
Provided is a negative electrode active material that can improve the discharge capacity per volume and/or charge-discharge cycle characteristics. The negative electrode active material according to the present embodiment contains an alloy phase and ceramics. The alloy phase undergoes thermoelastic diffusionless transformation when releasing or occluding metal ions. The ceramics is dispersed in the metal phase. The content of ceramics in the alloy phase is more than 0 to 50 mass % with respect to the total mass of the alloy phase and the ceramics.