公开(公告)号：US5611959A

公开(公告)日：1997-03-18

申请号：US515807

申请日：1995-08-16

申请人： Naoto Kijima ,  Yasuo Shimomura ,  Chisato Miura ,  Takayuki Hisamune ,  Masakazu Nabu ,  Koichi Toriumi

发明人： Naoto Kijima ,  Yasuo Shimomura ,  Chisato Miura ,  Takayuki Hisamune ,  Masakazu Nabu ,  Koichi Toriumi

IPC分类号： C09K11/77 ,  C09K11/80 ,  C09K11/64

CPC分类号： C09K11/7734 ,  C09K11/7792

摘要： An aluminate phosphor comprising (a) at least one element selected from the group consisting of Ba, Sr and Ca, (b) Eu, (c) Mg and/or Zn, (d) optionally Mn and (e) Al, said aluminate phosphor comprising a crystalline inorganic compound which shows, in its powder X-ray diffraction pattern upon incidence of X-rays of CuK.alpha..sub.1, no peak at Miller index 008 independent of a diffraction peak at Miller index 110.

摘要翻译： 一种铝酸盐荧光体，其包含（a）选自Ba，Sr和Ca中的至少一种元素，（b）Eu，（c）Mg和/或Zn，（d）任选的Mn和（e）Al，所述铝酸盐 包含结晶无机化合物的荧光体，其以其在CuKα1的X射线入射时的粉末X射线衍射图中显示，在Miller指数008处无峰，与Miller指数110的衍射峰无关。

公开(公告)号：US08269410B2

公开(公告)日：2012-09-18

申请号：US11909009

申请日：2006-03-17

申请人： Naoto Kijima ,  Yasuo Shimomura ,  Hideaki Kaneda ,  Kimiya Takeshita

发明人： Naoto Kijima ,  Yasuo Shimomura ,  Hideaki Kaneda ,  Kimiya Takeshita

IPC分类号： H01L33/50 ,  H01L33/52

CPC分类号： C09K11/7721 ,  C09K11/661 ,  C09K11/7734 ,  C09K11/7739 ,  C09K11/7774 ,  C09K11/778 ,  C09K11/7784 ,  C09K11/7788 ,  C09K11/7794 ,  H01L24/45 ,  H01L33/502 ,  H01L2224/32245 ,  H01L2224/45015 ,  H01L2224/45124 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2924/12036 ,  H01L2924/12041 ,  H01L2924/12042 ,  H01L2924/181 ,  Y02B20/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/20752 ,  H01L2924/20753 ,  H01L2924/00012

摘要： To achieve a light-emitting device emitting light with high brightness, closer to natural light, and less color shift due to a small change in intensity of emitted light, in a light-emitting device including a light source emitting light by driving current and at least one wavelength-converting material absorbing at least part of the light from the light source and emitting light having a different wavelength, the color coordinate x1(17.5) and the color coordinate y1(17.5) of the light emitted at a driving current density of 17.5 A/cm2 and the color coordinate x1(70) and the color coordinate y1(70) of the light emitted at a driving current density of 70 A/cm2 satisfy the following Expressions (D) and (E): −0.006≦x1(17.5)−x1(70)≦0.006  (D), −0.006≦y1(17.5)−y1(70)≦0.006  (E).

摘要翻译： 为了实现在包括通过驱动电流发射光的光源和发光装置的发光装置中发射具有高亮度，更接近自然光的光的发光装置和由于发射光的强度的小的变化而导致的较少的颜色偏移 至少一个波长转换材料吸收来自光源的光的至少一部分并且发射具有不同波长的光，以驱动电流密度发射的光的颜色坐标x1（17.5）和颜色坐标y1（17.5） 在驱动电流密度为70A / cm2时发出的光的色度坐标x1（70）和颜色坐标x1（70）满足下列表达式（D）和（E）：-0.006＆nlE; x1（17.5）-x1（70）＆nlE; 0.006（D），-0.006＆nlE; y1（17.5）-y1（70）＆nlE; 0.006（E）。

公开(公告)号：US20100213817A1

公开(公告)日：2010-08-26

申请号：US12713546

申请日：2010-02-26

申请人： Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima

发明人： Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima

IPC分类号： H01J1/62 ,  C09K11/08 ,  C09K11/54 ,  C09K11/77 ,  C09K11/55

CPC分类号： C09K11/0883 ,  C04B35/22 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3229 ,  C04B2235/442 ,  C09K11/7721 ,  C09K11/7731 ,  C09K11/7774 ,  H01L33/502 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/49107 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

摘要： To present a green- to yellow-emitting phosphor whereby a light-emitting device having high color rendering properties and high luminance can be obtained, a light-emitting device employing such a phosphor, and an image display device and a lighting system, containing such a light-emitting device.A phosphor made of a compound represented by the following formula (I), which comprises, as matrix, a compound of a garnet structure and which contains, as a luminescent center ion, a metal element in the matrix: M1aM2bXcM3dM43Oe  (I) wherein M1 is Mg and/or Zn, M2 is a bivalent metal element excluding Mg and Zn, X is a metal element as a luminescent center ion composed mainly of Ce, M3 is a trivalent metal element excluding X, M4 is a tetravalent metal element, and a, b, c, d and e are numbers satisfying the following formulae, respectively: 0.001≦a≦0.5 2.5≦b≦3.3 0.005≦c≦0.5 1.5≦d≦2.3 e={(a+b)×2+(c+d)×3+12}/2.

摘要翻译： 为了呈现绿色至黄色的发光荧光体，可以获得具有高显色性和高亮度的发光装置，使用这种荧光体的发光装置，以及包含这种荧光体的图像显示装置和照明系统 发光装置。 1.一种由下述式（I）表示的化合物构成的荧光体，其特征在于，在所述基质中含有作为基质的石榴石结构化合物，所述化合物含有作为发光中心离子的金属元素：M1aM2bXcM3dM43Oe（Ⅰ），其中M1 是Mg和/或Zn，M2是不包括Mg和Zn的二价金属元素，X是作为主要由Ce组成的发光中心离子的金属元素，M3是不包括X的三价金属元素，M4是四价金属元素，以及 a，b，c，d和e分别为满足下列公式的数字：0.001＆nlE; a＆nlE; 0.5 2.5＆nlE; b＆nlE; 3.3 0.005＆nlE; c＆nlE; 0.5 1.5＆nlE; d＆nlE; 2.3 e = {（a + b） ×2 +（c + d）×3 + 12} / 2。

公开(公告)号：US07713441B2

公开(公告)日：2010-05-11

申请号：US11577016

申请日：2005-10-14

申请人： Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima

发明人： Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima

IPC分类号： C09K11/59 ,  C09K11/55 ,  C09K11/79 ,  C09K11/64

CPC分类号： C09K11/0883 ,  C04B35/22 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3224 ,  C04B2235/3229 ,  C04B2235/442 ,  C09K11/7721 ,  C09K11/7731 ,  C09K11/7774 ,  H01L33/502 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/49107 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

摘要： To present a green- to yellow-emitting phosphor whereby a light-emitting device having high color rendering properties and high luminance can be obtained, a light-emitting device employing such a phosphor, and an image display device and a lighting system, containing such a light-emitting device.A phosphor made of a compound represented by the following formula (I), which comprises, as matrix, a compound of a garnet structure and which contains, as a luminescent center ion, a metal element in the matrix: M1aM2bXcM3dM43Oe  (I) wherein M1 is Mg and/or Zn, M2 is a bivalent metal element excluding Mg and Zn, X is a metal element as a luminescent center ion composed mainly of Ce, M3 is a trivalent metal element excluding X, M4 is a tetravalent metal element, and a, b, c, d and e are numbers satisfying the following formulae, respectively: 0.001≦a≦0.5 2.5≦b≦3.3 0.005≦c≦0.5 1.5≦d≦2.3 e={(a+b)×2+(c+d)×3+12}/2.

摘要翻译： 为了呈现绿色至黄色的发光荧光体，可以获得具有高显色性和高亮度的发光装置，使用这种荧光体的发光装置，以及包含这种荧光体的图像显示装置和照明系统 发光装置。 1.一种由下述式（I）表示的化合物构成的荧光体，其特征在于，在所述基质中含有作为基质的石榴石结构化合物，所述化合物含有作为发光中心离子的金属元素：M1aM2bXcM3dM43Oe（Ⅰ），其中M1 是Mg和/或Zn，M2是不包括Mg和Zn的二价金属元素，X是作为主要由Ce组成的发光中心离子的金属元素，M3是不包括X的三价金属元素，M4是四价金属元素，以及 a，b，c，d和e分别为满足下列公式的数字：0.001＆nlE; a＆nlE; 0.5 2.5＆nlE; b＆nlE; 3.3 0.005＆nlE; c＆nlE; 0.5 1.5＆nlE; d＆nlE; 2.3 e = {（a + b） ×2 +（c + d）×3 + 12} / 2。

公开(公告)号：US20090026920A1

公开(公告)日：2009-01-29

申请号：US11631390

申请日：2005-06-30

申请人： Yasuo Shimomura ,  Naoto Kijima

发明人： Yasuo Shimomura ,  Naoto Kijima

IPC分类号： H01J63/04 ,  H01J1/62 ,  C09K11/78

CPC分类号： C09K11/7768 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00012

摘要： The present invention relates to a phosphor represented by the following general formula (I), comprising: a composite oxide containing a divalent and trivalent metal elements as a host crystal; and at least Ce as an activator element in said host crystal, wherein the phosphor has a maximum emission peak in a wavelength range of from 485 nm to 555 nm in the emission spectrum at room temperature: M1aM2bM3cOd  (I) wherein M1 represents an activator element containing at least Ce; M2 represents a divalent metal element; M3 represents a trivalent metal element; a is a number within a range of 0.0001≦a≦0.2; b is a number within a range of 0.8≦b≦1.2; c is a number within a range of 1.6≦c≦2.4; and d is a number within a range of 3.2≦d≦4.8. Further, a light emitting device comprising said phosphor and a display and a lighting system having said light emitting device as a light source are disclosed. In accordance with the present invention, a phosphor which can be easily produced and can provide a light emitting device having a high color rendering, a light emitting device comprising the phosphor, and a display and a lighting system comprising the light emitting device as a light source can be provided.

摘要翻译： 本发明涉及由以下通式（I）表示的荧光体，其包含：含有二价和三价金属元素作为主体晶体的复合氧化物; 并且至少Ce作为所述主晶体中的活化剂元素，其中在室温下的发射光谱中，所述荧光体在485nm至555nm的波长范围内具有最大发射峰值：<？in-line-formula description =“ 在线公式“end =”lead“？> M1aM2bM3cOd（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中M1表示至少含有Ce的活化元素; M2表示二价金属元素; M3表示三价金属元素; a是0.0001

公开(公告)号：US20080290786A1

公开(公告)日：2008-11-27

申请号：US11631103

申请日：2005-06-29

申请人： Yasuo Shimomura ,  Hideaki Kaneda ,  Naoto Kijima

发明人： Yasuo Shimomura ,  Hideaki Kaneda ,  Naoto Kijima

IPC分类号： H01J1/62

CPC分类号： C09K11/64 ,  C09K11/0883 ,  C09K11/7734 ,  C09K11/7774 ,  H01L33/504 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H05B33/12 ,  H01L2924/00014 ,  H01L2924/00

摘要： To enhance luminance and color rendering of a light emitting device comprising phosphors as wavelength converting material and at least one semiconductor light emitting device that emits visible light, as said phosphors, are used phosphors which are one or more kinds of phosphors selected from a group consisting of oxides, oxynitrides and nitrides, and are a mixture consisting of two or more kinds of phosphors whose luminous efficiency is 35% or higher when excited by the visible light from said semiconductor light emitting device at room temperature. In addition, said mixture contains a first phosphor, and a second phosphor that is different from said first phosphor and capable of absorbing emitted light from said first phosphor, and said first phosphor is contained 85 weight % or more of said mixture of phosphors.

摘要翻译： 为了提高包括作为波长转换材料的荧光体和发射可见光的至少一个半导体发光器件的发光器件的亮度和显色性，作为所述荧光体，使用荧光体，它们是一种或多种磷光体，其选自： 的氧化物，氮氧化物和氮化物，并且是由在室温下来自所述半导体发光器件的可见光激发时发光效率为35％以上的两种以上的荧光体组成的混合物。 此外，所述混合物包含第一荧光体和与所述第一荧光体不同的能够吸收来自所述第一荧光体的发射光的第二荧光体，并且所述第一荧光体含有所述荧光体混合物的85重量％以上。

公开(公告)号：US09028718B2

公开(公告)日：2015-05-12

申请号：US13533242

申请日：2012-06-26

申请人： Naoto Kijima ,  Yasuo Shimomura ,  Hideaki Kaneda ,  Kimiya Takeshita

发明人： Naoto Kijima ,  Yasuo Shimomura ,  Hideaki Kaneda ,  Kimiya Takeshita

IPC分类号： H01L33/50 ,  H01L33/52 ,  C09K11/77 ,  C09K11/66 ,  H01L23/00

CPC分类号： C09K11/7721 ,  C09K11/661 ,  C09K11/7734 ,  C09K11/7739 ,  C09K11/7774 ,  C09K11/778 ,  C09K11/7784 ,  C09K11/7788 ,  C09K11/7794 ,  H01L24/45 ,  H01L33/502 ,  H01L2224/32245 ,  H01L2224/45015 ,  H01L2224/45124 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2924/12036 ,  H01L2924/12041 ,  H01L2924/12042 ,  H01L2924/181 ,  Y02B20/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/20752 ,  H01L2924/20753 ,  H01L2924/00012

摘要： To achieve a light-emitting device emitting light with high brightness, closer to natural light, and less color shift due to a small change in intensity of emitted light, in a light-emitting device including a light source emitting light by driving current and at least one wavelength-converting material absorbing at least part of the light from the light source and emitting light having a different wavelength, the color coordinate x1(17.5) and the color coordinate y1(17.5) of the light emitted at a driving current density of 17.5 A/cm2 and the color coordinate x1(70) and the color coordinate y1(70) of the light emitted at a driving current density of 70 A/cm2 satisfy the following Expressions (D) and (E): −0.006≦x1(17.5)−x1(70)≦0.006  (D), −0.006≦y1(17.5)−y1(70)≦0.006  (E).

摘要翻译： 为了实现在包括通过驱动电流发射光的光源和发光装置的发光装置中发射具有高亮度，更接近自然光的光的发光装置和由于发射光的强度的小的变化而导致的较少的颜色偏移 至少一个波长转换材料吸收来自光源的光的至少一部分并且发射具有不同波长的光，以驱动电流密度发射的光的颜色坐标x1（17.5）和颜色坐标y1（17.5） 在驱动电流密度为70A / cm2时发出的光的色度坐标x1（70）和颜色坐标x1（70）满足下列表达式（D）和（E）：-0.006＆nlE; x1（17.5）-x1（70）＆nlE; 0.006（D），-0.006＆nlE; y1（17.5）-y1（70）＆nlE; 0.006（E）。

公开(公告)号：US07790058B2

公开(公告)日：2010-09-07

申请号：US12124595

申请日：2008-05-21

申请人： Yasuo Shimomura ,  Naoto Kijima

发明人： Yasuo Shimomura ,  Naoto Kijima

IPC分类号： C09K11/79 ,  C09K11/55 ,  H01L33/00

CPC分类号： C09K11/7731 ,  C09K11/0883 ,  C09K11/665 ,  C09K11/7721 ,  C09K11/7728 ,  C09K11/7734 ,  C09K11/7774 ,  C09K11/7789 ,  H01L33/502 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/49107 ,  H01L2924/181 ,  H01L2924/00012 ,  H01L2924/00

摘要： A phosphor (A) comprising a host material composed of a compound having a garnet crystal structure represented by the general formula (I): M1aM2bM3cOd  (I) (wherein M1 is a divalent metal element, M2 is a trivalent metal element, M3 is a tetravalent metal element containing at least Si, a is the number of 2.7 to 3.3, b is the number of 1.8 to 2.2, c is the number of 2.7 to 3.3, and d is the number of 11.0 to 13.0), and a luminescent center ion incorporated in the host material; a light emitting device (B) comprising the phosphor as a wavelength conversion material and a semiconductor light emitting element capable of emitting a light in the range of from ultraviolet light to visible light; and a display (C) and a lighting system (D) using the light emitting device (B) as a light source. The above phosphor can be readily produced, and can provide a light emitting device having a high color rendering property.

摘要翻译： 一种荧光体（A），其特征在于，具有由具有通式（I）表示的石榴石晶体结构的化合物构成的主体材料：M1aM2bM3cOd（Ⅰ）（其中M1为二价金属元素，M2为三价金属元素，M3为 至少含有Si的四价金属元素，a为2.7〜3.3的数量，b为1.8〜2.2的数量，c为2.7〜3.3的数量，d为11.0〜13.0的数量），发光中心 离子掺入主体材料中; 包括作为波长转换材料的荧光体的发光器件（B）和能够发射从紫外光到可见光的范围内的光的半导体发光元件; 以及使用发光装置（B）作为光源的显示器（C）和照明系统（D）。 可以容易地制造上述荧光体，并且可以提供具有高显色性能的发光器件。

公开(公告)号：US20090072255A1

公开(公告)日：2009-03-19

申请号：US11997926

申请日：2006-08-10

申请人： Tomoko Takahashi ,  Nobuhiro Kodama ,  Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima ,  Takashi Hase ,  Eiji Hattori ,  Kouichi Adachi ,  Keiichi Seki ,  Yutaka Mori

发明人： Tomoko Takahashi ,  Nobuhiro Kodama ,  Yasuo Shimomura ,  Naoto Kijima ,  Tomoyuki Kurushima ,  Takashi Hase ,  Eiji Hattori ,  Kouichi Adachi ,  Keiichi Seki ,  Yutaka Mori

IPC分类号： H01L33/00 ,  C01F17/00 ,  C09K11/77

CPC分类号： C09K11/7734 ,  C09K11/584 ,  C09K11/642 ,  C09K11/665 ,  C09K11/7721 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7741 ,  C09K11/7768 ,  C09K11/7774 ,  C09K11/7789 ,  C09K11/7792 ,  H01L33/502 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/73265 ,  H01L2224/8592 ,  H01L2924/12044 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

摘要： The present invention relates to a phosphor that satisfies requirements (1) to (3): (1) the phosphor satisfies Formula [2] and/or Formula [3]: 85≦{R455(125)/R455(25)}×100

摘要翻译： 本发明涉及满足要求（1）〜（3）的荧光体：（1）荧光体满足式[2]和/或式[3]：<？in-line-formula description =“In-Line Formulas “end =”lead“？> 85 <= {R455（125）/ R455（25）} x100 <110 [2] <？in-line-formula description =”In-line Formulas“end =”tail“？> <？in-line-formula description =“In-line formula”end =“lead”？> 92 <= {R405（100）/ R405（25）} x100 <110 [3] 其中R455（125）表示当在125℃下峰值波长为455nm的光激发荧光体时的发射峰强度，（2）发射峰值 波长在570nm至680nm的范围内，（3）发射峰的半峰全宽为90nm以下。 本发明的荧光体具有高的发光效率并以高亮度发出橙色至红色的光。 通过使用荧光体，可以制造出效率高，显色性优异的发光装置，照明装置和图像显示装置。

公开(公告)号：US08384285B2

公开(公告)日：2013-02-26

申请号：US13102416

申请日：2011-05-06

申请人： Yasuo Shimomura ,  Naoto Kijima

发明人： Yasuo Shimomura ,  Naoto Kijima

IPC分类号： C09K11/02 ,  C09K11/08 ,  C09K11/77 ,  H01J1/52 ,  H01J19/40

CPC分类号： C09K11/7768 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2924/181 ,  H05B33/14 ,  H01L2924/00014 ,  H01L2924/00012

摘要： The present invention relates to a phosphor represented by the following general formula (I), comprising: a composite oxide containing a divalent and trivalent metal elements as a host crystal; and at least Ce as an activator element in said host crystal, wherein the phosphor has a maximum emission peak in a wavelength range of from 485 nm to 555 nm in the emission spectrum at room temperature: M1aM2bM3cOd  (I) wherein M1 represents an activator element containing at least Ce; M2 represents a divalent metal element; M3 represents a trivalent metal element; a is a number within a range of 0.0001≦a≦0.2; b is a number within a range of 0.8≦b≦1.2; c is a number within a range of 1.6≦c≦2.4; and d is a number within a range of 3.2≦d≦4.8. Further, a light emitting device comprising said phosphor and a display and a lighting system having said light emitting device as a light source are disclosed. In accordance with the present invention, a phosphor which can be easily produced and can provide a light emitting device having a high color rendering, a light emitting device comprising the phosphor, and a display and a lighting system comprising the light emitting device as a light source can be provided.

摘要翻译： 本发明涉及由以下通式（I）表示的荧光体，其包含：含有二价和三价金属元素作为主体晶体的复合氧化物; 并且至少Ce作为所述主晶体中的活化元素，其中在室温下的发射光谱中，所述荧光体在485nm至555nm的波长范围内具有最大发射峰：M1aM2bM3cOd（I）其中M1表示活化元素 至少含有Ce; M2表示二价金属元素; M3表示三价金属元素; a是在0.0001＆nlE范围内的数字; a＆nlE; 0.2; b为0.8＆nlE; b＆nlE; 1.2; c为1.6＆nlE范围内的数字; c＆nlE; 2.4; d为3.2＆nlE; d＆nlE; 4.8的范围内的数字。 此外，公开了包括所述荧光体和显示器的发光装置和具有所述发光装置作为光源的照明系统。 根据本发明，可以容易地制造出能够提供具有高显色性的发光装置的荧光体，包括荧光体的发光装置和显示器以及包括发光装置作为光的照明系统 源可以提供。