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18 条记录 (耗时 0.017 秒)

    Acid scavenged polymer halogenation
    1.
    发明授权
    Acid scavenged polymer halogenation 失效
    酸清除聚合物卤化

    公开(公告)号：US5087674A

    公开(公告)日：1992-02-11

    申请号：US595915

    申请日：1990-10-11

    申请人： Irwin J. Gardner ,  James V. Fusco ,  Neil F. Newman ,  Ronald C. Kowalski ,  William M. Davis

    发明人： Irwin J. Gardner ,  James V. Fusco ,  Neil F. Newman ,  Ronald C. Kowalski ,  William M. Davis

    IPC分类号： C08F8/20

    CPC分类号： C08F8/20

    摘要： A process for halogenating polymers by contacting a polymer either in solution or in bulk with a halogenating agent in the presence of an acid scavenger. Halogenated polymer, e.g., butyl rubber, with a particular structure is obtained and the product suffers less molecular weight loss. Combinations of acid scavengers can also be used and the scavenger can be dispersed in the polymer prior to halogenation and/or added to the reaction zone during halogenation.

    摘要翻译： 一种通过在酸清除剂存在下使聚合物在溶液中或大量与卤化剂接触来使聚合物卤化的方法。 获得具有特定结构的卤化聚合物，例如丁基橡胶，并且产物的分子量损失较小。 酸清除剂的组合也可以使用，并且清除剂可以在卤化之前分散在聚合物中和/或在卤化过程中加入到反应区中。

    Craft curing of modified isomonoolefin/para-alkylstyrene copolymers
    5.
    发明授权
    Craft curing of modified isomonoolefin/para-alkylstyrene copolymers 失效
    改性异单烯烃/对烷基苯乙烯共聚物的工艺固化

    公开(公告)号：US5567775A

    公开(公告)日：1996-10-22

    申请号：US469285

    申请日：1995-06-06

    申请人： Hsien C. Wang ,  Irwin J. Gardner ,  James V. Fusco

    发明人： Hsien C. Wang ,  Irwin J. Gardner ,  James V. Fusco

    IPC分类号： C08F290/12 ,  C08F8/00 ,  C08F290/04 ,  C08F255/10 ,  C08F257/02

    CPC分类号： C08F290/04 ,  C08F8/00

    摘要： This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R.sub.4 is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; andb) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g. benzylic(meth)acrylic acid ester groups present in isobutylene/para-methystyrene interpolymer chains, are capable of participating in free radical initiated reactions with monofunctional or polyfunctional free radically polymerizable monomers to produce graft-crosslinked compositions having an unusual balance of physical properties. These compositions may be formed into shaped articles such as films, coatings, adhesive layers and moldings and subjected to free radical polymerization conditions to produce crosslinked shaped articles.

    摘要翻译： 本发明提供了由混合物制备的可固化和接枝固化的聚合物组合物，其包含：a）含有约0.01至约10摩尔％的Y酯基的弹性体共聚物，其随机分布并垂直于弹性体聚合物链，所述Y酯 具有以下结构的基团：其中R 2和R 3独立地选自氢和含有1至约6个碳原子的烷基，R 4选自氢，含1至 约28个碳原子，芳基和含有2至约28个碳原子的烯基; 和b）至少一种可自由基聚合的单体。 本发明还提供了制备接枝固化的聚合物组合物的方法，包括形成上述（a）和（b）的混合物并使所述混合物经受自由基聚合条件。 Y酯基垂直于弹性体聚合物链，例如。 存在于异丁烯/对 - 甲基苯乙烯互聚物链中的苄基（甲基）丙烯酸酯基能够参与与单官能或多官能的可自由基聚合单体的自由基引发的反应，以产生具有不寻常的物理平衡平衡的接枝交联组合物。 这些组合物可以形成成型制品如薄膜，涂料，粘合剂层和模制品，并进行自由基聚合条件以制备交联成型制品。

    Method of manufacture of elastomer polyester molding compounds
    6.
    发明授权
    Method of manufacture of elastomer polyester molding compounds 失效
    弹性体聚酯模塑料的制造方法

    公开(公告)号：US4160758A

    公开(公告)日：1979-07-10

    申请号：US873102

    申请日：1978-01-30

    申请人： Irwin J. Gardner

    发明人： Irwin J. Gardner

    IPC分类号： C08F299/04 ,  C08L67/06 ,  C08G63/52 ,  C08J3/20

    CPC分类号： C08L67/06 ,  C08F299/04

    摘要： Methods for preparing reinforced molding compounds are disclosed, comprising preparing a first paste component from a mixture of a thermosetting unsaturated polyester component, a free radical polymerizable monomer component and an inorganic particulate filler component, preparing a second paste component from a conjugated diene butyl elastomer copolymer component, a free radical polymerizable monomer component, and an inorganic particulate filler component, and combining the first and second paste components in order to produce an elastomer modified thermosetting unsaturated polyester molding compound having improved surface appearance, toughness and impact strength. Preferably, one or both of the paste components will include a thermoplastic polymer additive component to provide low profile qualities to the product.

    摘要翻译： 公开了制备增强模塑料的方法，包括由热固性不饱和聚酯组分，自由基可聚合单体组分和无机颗粒填料组分的混合物制备第一浆料组分，由共轭二烯丁基弹性体共聚物制备第二浆料组分 组分，可自由基聚合的单体组分和无机颗粒填料组分，并组合第一和第二浆料组分以制备具有改进的表面外观，韧性和冲击强度的弹性体改性的热固性不饱和聚酯模塑料。 优选地，一种或两种糊料组分将包括热塑性聚合物添加剂组分以向产品提供低轮廓质量。

    Curing systems for halogenated elastomers
    7.
    发明授权
    Curing systems for halogenated elastomers 失效
    卤化弹性体的固化体系

    公开(公告)号：US5373062A

    公开(公告)日：1994-12-13

    申请号：US55125

    申请日：1993-04-29

    申请人： Irwin J. Gardner ,  Donald S. Tracey

    发明人： Irwin J. Gardner ,  Donald S. Tracey

    IPC分类号： C08F8/42

    CPC分类号： C08F8/42

    摘要： An improved promoted curing system for halogenated elastomers has been discovered wherein the curing system contains one or a mixture of bismuth carboxylates having the structure of Formula 1: ##STR1## wherein R.sub.1 is selected from the group consisting of straight or branched chain alkyl groups having from 4 to about 30 carbon atoms, aromatic groups containing 6 to about 30 carbon atoms and alkaryl groups containing from 7 to about 30 carbon atoms.It has been found that the use of these bismuth salts, alone or in combination with zinc compounds in the cure of compositions containing halogenated elastomers leads to full, low reversion cures and curable compositions exhibiting very low precure scorch properties.

    摘要翻译： 已经发现改进了用于卤化弹性体的促进固化体系，其中固化体系含有一种或其具有式1结构的羧酸铋的混合物：其中R 1选自直链或支链烷基 具有4至约30个碳原子，含有6至约30个碳原子的芳族基团和含有7至约30个碳原子的烷芳基。 已经发现，在含有卤化弹性体的组合物的固化中，单独或与锌化合物组合使用的这些铋盐导致表现出非常低的预固化焦烧性能的完全，低回复固化和可固化组合物。

    Process for producing brominated butyl rubber high in primary allylic bromine
    9.
    发明授权
    Process for producing brominated butyl rubber high in primary allylic bromine 失效
    溴代丁基橡胶生产高级初级烯丙基溴的方法

    公开(公告)号：US4649178A

    公开(公告)日：1987-03-10

    申请号：US656667

    申请日：1984-10-01

    申请人： Irwin J. Gardner ,  James V. Fusco

    发明人： Irwin J. Gardner ,  James V. Fusco

    IPC分类号： C08F8/22 ,  C08F8/20

    CPC分类号： C08F8/22

    摘要： A process for preparing a brominated butyl rubber high in Primary Allylic Bromine which comprises reacting the rubber in solution with elemental bromine at a temperature of about 65.degree. C. to about 130.degree. C. The process is preferably carried out under substantially anhydrous conditions.

    摘要翻译： 制备高级初级烯丙基溴的溴化丁基橡胶的方法，其包括使溶液中的橡胶与元素溴在约65℃至约130℃的温度下反应。该方法优选在基本上无水的条件下进行。