Method for the production of composite materials
    3.
    发明授权
    Method for the production of composite materials 有权
    复合材料生产方法

    公开(公告)号:US09234098B2

    公开(公告)日:2016-01-12

    申请号:US13262755

    申请日:2010-04-01

    摘要: The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e. a conventional monomer which does not have a monomer unit A and is copolymerizable with the monomer unit B (embodiment 2).

    摘要翻译: 本发明涉及从a)至少一种无机或有机金属金属相制备纳米复合材料的方法; 和b)有机聚合物相; 包括至少一种单体M的聚合,所述单体M具有至少一个具有金属或半金属M的第一可聚合单体单元A和至少一个第二可聚合有机单体单元B,其通过共价化学键连接到可聚合单元A 在可聚合单体单元A和可聚合单元B两者都聚合并且A和B之间的键断裂聚合的聚合条件下,待聚合的单体M包含第一单体M1和至少一个第二单体M2,其至少不同 在单体M1(实施方案1)的单体单元A和B中的一种中,或要聚合的单体以及至少一种单体M至少一种除单体M以外的其它单体,即常规 不具有单体单元A并且可与单体单元B共聚的单体(实施方案2)。

    METHOD FOR THE PRODUCTION OF COMPOSITE MATERIALS
    4.
    发明申请
    METHOD FOR THE PRODUCTION OF COMPOSITE MATERIALS 有权
    复合材料生产方法

    公开(公告)号:US20120091400A1

    公开(公告)日:2012-04-19

    申请号:US13262755

    申请日:2010-04-01

    摘要: The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e. a conventional monomer which does not have a monomer unit A and is copolymerizable with the monomer unit B (embodiment 2).

    摘要翻译: 本发明涉及从a)至少一种无机或有机金属金属相制备纳米复合材料的方法; 和b)有机聚合物相; 包括至少一种单体M的聚合,所述单体M具有至少一个具有金属或半金属M的第一可聚合单体单元A和至少一个第二可聚合有机单体单元B,其通过共价化学键连接到可聚合单元A 在可聚合单体单元A和可聚合单元B两者都聚合并且A和B之间的键断裂聚合的聚合条件下,待聚合的单体M包含第一单体M1和至少一个第二单体M2,其至少不同 在单体M1(实施方案1)的单体单元A和B中的一种中,或要聚合的单体以及至少一种单体M至少一种除单体M以外的其它单体,即常规 不具有单体单元A并且可与单体单元B共聚的单体(实施方案2)。

    PROCESS FOR PRODUCING A PARTICULATE NANOCOMPOSITE MATERIAL
    6.
    发明申请
    PROCESS FOR PRODUCING A PARTICULATE NANOCOMPOSITE MATERIAL 失效
    生产颗粒状纳米复合材料的方法

    公开(公告)号:US20120052300A1

    公开(公告)日:2012-03-01

    申请号:US13319414

    申请日:2010-05-07

    摘要: The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process.The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3, or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, wherein the polymerization is performed in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from α) at least one surface-active substance and β) at least one particulate material.

    摘要翻译: 本发明涉及一种制备颗粒状纳米复合材料的方法,其中纳米复合材料的颗粒包含a)至少一种包含至少一种(半)金属M的无机或有机(半)金属相; 和b)至少一个有机聚合物相。 本发明还涉及通过该方法可获得的纳米复合材料。 该方法包括至少一种单体MM的聚合,所述单体MM具有至少一个具有金属或半金属M的第一阳离子可聚合单体单元A和至少一个第二可阳离子聚合的有机单体单元B,其通过 至少一个,例如 1,2,3或4共价化学键,在阳离子聚合条件下,可聚合单体单元A和可聚合单元B都聚合,其中A和B之间的键或键的断裂,其中聚合在 在至少一种聚合引发剂和选自α)至少一种表面活性物质和至少一种表面活性物质和至少一种颗粒物质的至少一种其它物质的存在下,纳米复合材料不溶解的非质子溶剂。

    METHOD FOR SEPARATING SUBSTANCE MIXTURES BY MEANS OF MULTIPHASE POLYMER FILMS
    7.
    发明申请
    METHOD FOR SEPARATING SUBSTANCE MIXTURES BY MEANS OF MULTIPHASE POLYMER FILMS 审中-公开
    通过多相聚合物薄膜分离物质混合物的方法

    公开(公告)号:US20120187045A1

    公开(公告)日:2012-07-26

    申请号:US13499460

    申请日:2010-09-27

    摘要: The present invention relates to a process for separating substance mixtures by means of a nonporous polymer film which has (a) at least one inorganic or organometallic phase and (b) at least one organic polymer phase, wherein the polymer film is obtainable by polymerizing at least one monomer which has at least one first polymerizable monomer segment A1 comprising at least one metal or semimetal M and at least one second polymerizable organic monomer segment A2 which is connected to the polymerizable monomer segment A1 via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer segment A1 and the polymerizable organic monomer segment A2 polymerize with breakage of the covalent chemical bond between A1 and A2. The present invention also relates to the use of the aforementioned polymer films for permeation, gas separation or pervaporation.

    摘要翻译: 本发明涉及一种通过无孔聚合物膜分离物质混合物的方法,所述无孔聚合物膜具有(a)至少一种无机或有机金属相和(b)至少一种有机聚合物相,其中聚合物膜可通过在 至少一种具有至少一个第一可聚合单体链段A1的单体,其包含至少一种金属或半金属M和至少一个第二可聚合有机单体链段A2,其在聚合条件下通过共价化学键连接到可聚合单体链段A1 可聚合单体链段A1和可聚合有机单体链段A2都与A1和A2之间的共价化学键断裂聚合。 本发明还涉及上述聚合物膜用于渗透,气体分离或渗透蒸发的用途。

    Process for producing a particulate nanocomposite material
    9.
    发明授权
    Process for producing a particulate nanocomposite material 失效
    颗粒状纳米复合材料的制造方法

    公开(公告)号:US08680203B2

    公开(公告)日:2014-03-25

    申请号:US13319414

    申请日:2010-05-07

    IPC分类号: C07F7/00 C07F7/04

    摘要: The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process.The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3, or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, wherein the polymerization is performed in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from α) at least one surface-active substance and β) at least one particulate material.

    摘要翻译: 本发明涉及一种制备颗粒状纳米复合材料的方法,其中纳米复合材料的颗粒包含a)至少一种包含至少一种(半)金属M的无机或有机(半)金属相; 和b)至少一个有机聚合物相。 本发明还涉及通过该方法可获得的纳米复合材料。 该方法包括至少一种单体MM的聚合,所述单体MM具有至少一个具有金属或半金属M的第一阳离子可聚合单体单元A和至少一个第二阳离子可聚合有机单体单元B,其连接到可聚合单元A,经由 至少一个,例如 1,2,3或4共价化学键,在阳离子聚合条件下,可聚合单体单元A和可聚合单元B都聚合,其中A和B之间的键或键的断裂,其中聚合在 在至少一种聚合引发剂和选自α)至少一种表面活性物质和至少一种表面活性物质和至少一种颗粒物质的至少一种其它物质的存在下,纳米复合材料不溶解的非质子溶剂。

    NOVEL INITIATION PROCESS FOR POLYMERIZATION WITH ACTIVATION USING IONIC LIQUIDS
    10.
    发明申请
    NOVEL INITIATION PROCESS FOR POLYMERIZATION WITH ACTIVATION USING IONIC LIQUIDS 审中-公开
    使用离子液体进行活化聚合的新颖的方法

    公开(公告)号:US20130345380A1

    公开(公告)日:2013-12-26

    申请号:US14004170

    申请日:2012-03-07

    IPC分类号: C08F120/14

    摘要: The present invention relates to an innovative polymerization technique for (meth)acrylates and styrenes, in which the polymerization is initiated by isocyanates and special bases with imine structure and is activated/accelerated by addition of ionic liquids. With this new technique, which can be employed selectively, it is also possible to produce high molecular weight poly(meth)acrylates with in some cases narrow molecular weight distribution.The (meth)acrylate notation here denotes not only methacrylate, such as methyl methacrylate, ethyl methacrylate, etc., but also acrylate, such as methyl acrylate, ethyl acrylate, etc., for example, and also mixtures of both.

    摘要翻译: 本发明涉及一种用于(甲基)丙烯酸酯和苯乙烯的创新聚合技术,其中聚合由异氰酸酯和具有亚胺结构的特殊碱引发,并通过加入离子液体而活化/加速。 使用可以选择性地使用的这种新技术,也可以生产高分子量聚(甲基)丙烯酸酯,在某些情况下窄分子量分布。 这里,(甲基)丙烯酸酯符号不仅表示甲基丙烯酸酯,例如甲基丙烯酸甲酯,甲基丙烯酸乙酯等,也表示丙烯酸酯,例如丙烯酸甲酯,丙烯酸乙酯等,以及二者的混合物。