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公开(公告)号：US09384902B2
公开(公告)日：2016-07-05
申请号：US14004283
申请日：2012-03-12
申请人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
发明人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
IPC分类号： H01G9/20
CPC分类号： H01G9/2018 , H01G9/2004 , H01G9/2027 , H01G9/2031 , H01G9/2059 , H01G9/2072 , H01L2251/306 , Y02E10/542
摘要： In order to increase the generation efficiency of a silicon dioxide solar cell, two conductive substrates are arranged so that the conductive surfaces thereof face each other, at least one of the substrates is disposed upon the substrate facing the light entry-side substrate, and an electrolyte is filled between the silicon dioxide particles compact and the light entry-side substrate. Silicon dioxide solar cells having this configuration exhibit a significantly increased short circuit current and open circuit voltage in comparison to solar cells in which the silicon dioxide and the electrolyte are mixed. This configuration can further be improved by disposing a titanium dioxide solar cell or a dye-sensitized titanium dioxide solar cell upon the light entry-side substrate to further increase the short circuit current and the open circuit voltage.
摘要翻译： 为了提高二氧化硅太阳能电池的发电效率，配置两个导电性基板，使其导电面彼此面对，至少一个基板设置在面向入光侧基板的基板上， 电解质填充在二氧化硅颗粒结合体和光入射侧基板之间。 与其中混合有二氧化硅和电解质的太阳能电池相比，具有这种结构的二氧化硅太阳能电池显示出显着增加的短路电流和开路电压。 通过将二氧化钛太阳能电池或染料敏化二氧化钛太阳能电池配置在入光侧基板上，能够进一步提高短路电流和开路电压，可以进一步提高该结构。
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公开(公告)号：US20130336846A1
公开(公告)日：2013-12-19
申请号：US13823380
申请日：2011-09-15
申请人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
发明人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
CPC分类号： B01J23/04 , B01D39/2003 , B01D2239/0428 , B01J23/02 , B01J35/004 , B01J35/06 , B01J37/0018 , B01J37/06 , C03C15/00
摘要： Provided is an inexpensive material having a photocatalytic action. A photocatalyst is obtained by halogenation-treating glass fibers containing silicon dioxide in its components. Fused quartz, soda-lime glass, non-alkali glass, and borosilicate glass may be used for the glass. Hydrofluoric acid, hydrochloric acid and hydrobromic acid may be used for the halogen acid, and hydrofluoric acid is most desirable. The glass can be particulate, fibrous or sheet form material. The glass exhibits a photocatalytic action even with visible light other than ultraviolet light, and also water repellent effect. The glass according to the invention is capable of decomposing organic substances, and therefore, it is used for window glass in buildings or in transportation such as automobiles, when formed in a plate shape, and for a filter in an air intake/exhaust apparatus, when formed in fibrous shape.
摘要翻译： 提供了具有光催化作用的廉价材料。 通过在其组分中对包含二氧化硅的玻璃纤维进行卤化处理来获得光催化剂。 玻璃可以使用熔融石英，钠钙玻璃，无碱玻璃和硼硅酸盐玻璃。 氢氟酸，盐酸和氢溴酸可用于卤素酸，氢氟酸是最理想的。 玻璃可以是颗粒状，纤维状或片状材料。 即使使用紫外线以外的可见光，玻璃也呈现光催化作用，并且具有防水效果。 根据本发明的玻璃能够分解有机物质，因此它被用于建筑物中的窗玻璃或汽车等运输中，当形成为板状时，以及用于进气/排气装置中的过滤器， 当形成纤维状时。
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公开(公告)号：US20120241684A1
公开(公告)日：2012-09-27
申请号：US13503558
申请日：2010-10-21
申请人： Nobuaki Komatsu , Tomoko Ito , Shin-ichiro Nanjo , Hiroki Nagai
发明人： Nobuaki Komatsu , Tomoko Ito , Shin-ichiro Nanjo , Hiroki Nagai
IPC分类号： H01L31/0224 , C01B33/12 , C01B35/10 , C01B33/113
CPC分类号： H01M14/005 , C25B1/003 , C25B11/0452
摘要： Provided is a photoelectric conversion material which is obtained through easy processing from a substance containing silicon oxide, which is inexpensive, imposes no burden on the environment, and is stable, as a component. Also provided are a photocell and a secondary photocell both using this material. Any of synthetic quartz, fused quartz glass, soda-lime glass, non-alkali glass, and borosilicate glass, which are compositions containing silicon oxide, is pulverized, immersed in an aqueous solution of halogen acid, washed with water, and dried. The resultant material is deposited on an electrode plate and this electrode plate is placed in water where an appropriate electrolyte is mixed. This electrode plate is electrically connected to an opposite electrode, and is used as a photoelectrode by irradiated with light. The material may be enclosed in a container, mixed with an organic electrolyte, having an extraction electrode and an opposite electrode, and a photocell is configured by irradiated with light through the extraction electrode.
摘要翻译： 提供一种光电转换材料，其通过容易加工从含有氧化硅的物质获得，其便宜，对环境不施加负担，并且作为组分是稳定的。 还提供了使用这种材料的光电管和次级光电池。 将含有氧化硅的组合物的合成石英，熔融石英玻璃，钠钙玻璃，非碱玻璃和硼硅酸盐玻璃粉碎，浸入卤酸水溶液中，用水洗涤并干燥。 将所得材料沉积在电极板上，将该电极板置于混合适当电解质的水中。 该电极板与相对电极电连接，用光照射用作光电极。 该材料可以封闭在具有引出电极和相对电极的与有机电解质混合的容器中，并且光电池通过经由引出电极照射光而构成。
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公开(公告)号：US20140060630A1
公开(公告)日：2014-03-06
申请号：US14004283
申请日：2012-03-12
申请人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
发明人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai , Shin-ichiro Nanjo
IPC分类号： H01G9/20
CPC分类号： H01G9/2018 , H01G9/2004 , H01G9/2027 , H01G9/2031 , H01G9/2059 , H01G9/2072 , H01L2251/306 , Y02E10/542
摘要： In order to increase the generation efficiency of a silicon dioxide solar cell, two conductive substrates are arranged so that the conductive surfaces thereof face each other, at least one of the substrates is disposed upon the substrate facing the light entry-side substrate, and an electrolyte is filled between the silicon dioxide particles compact and the light entry-side substrate. Silicon dioxide solar cells having this configuration exhibit a significantly increased short circuit current and open circuit voltage in comparison to solar cells in which the silicon dioxide and the electrolyte are mixed. This configuration can further be improved by disposing a titanium dioxide solar cell or a dye-sensitized titanium dioxide solar cell upon the light entry-side substrate to further increase the short circuit current and the open circuit voltage.
摘要翻译： 为了提高二氧化硅太阳能电池的发电效率，配置两个导电性基板，使其导电面彼此面对，至少一个基板设置在面向入光侧基板的基板上， 电解质填充在二氧化硅颗粒结合体和光入射侧基板之间。 与其中混合有二氧化硅和电解质的太阳能电池相比，具有这种结构的二氧化硅太阳能电池显示出显着增加的短路电流和开路电压。 通过将二氧化钛太阳能电池或染料敏化二氧化钛太阳能电池配置在入光侧基板上，能够进一步提高短路电流和开路电压，可以进一步提高该结构。
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公开(公告)号：US09172124B2
公开(公告)日：2015-10-27
申请号：US13503558
申请日：2010-10-21
申请人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai
发明人： Nobuaki Komatsu , Tomoko Ito , Hiroki Nagai
CPC分类号： H01M14/005 , C25B1/003 , C25B11/0452
摘要： A photoelectric conversion material is obtained through easy processing from a substance containing silicon oxide, which is inexpensive, imposes no burden on the environment, and is stable, as a component. This material can be used in a photocell and a secondary photocell. Any of synthetic quartz, fused quartz glass, soda-lime glass, non-alkali glass, and borosilicate glass, which are compositions containing silicon oxide, is pulverized, immersed in an aqueous solution of halogen acid, washed with water, and dried. The resultant material is deposited on an electrode plate and this electrode plate is placed in water where an appropriate electrolyte is mixed. This electrode plate is electrically connected to an opposite electrode to provide a photoelectrode. The material may be enclosed in a container, mixed with an organic electrolyte, having an extraction electrode and an opposite electrode, to provide a photocell.
摘要翻译： 通过从含有氧化硅的物质的容易加工获得光电转换材料，其成本低廉，对环境没有负担，并且作为组分是稳定的。 该材料可用于光电池和次级光电池。 将含有氧化硅的组合物的合成石英，熔融石英玻璃，钠钙玻璃，非碱玻璃和硼硅酸盐玻璃粉碎，浸入卤酸水溶液中，用水洗涤并干燥。 将所得材料沉积在电极板上，并将该电极板放置在其中混合适当电解质的水中。 该电极板电连接到相对电极以提供光电极。 该材料可以封闭在与具有引出电极和相对电极的有机电解质混合的容器中，以提供光电池。
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6.发明授权公开(公告)号：US09515312B2
公开(公告)日：2016-12-06
申请号：US14368376
申请日：2012-12-21
IPC分类号： H01M4/00 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , C01G53/00 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/02
CPC分类号： H01M4/131 , C01G53/50 , C01P2002/22 , C01P2002/72 , C01P2002/74 , C01P2004/03 , H01M4/485 , H01M4/502 , H01M4/505 , H01M4/523 , H01M4/525 , H01M10/0525 , H01M2004/028 , Y02E60/122
摘要： A lithium secondary battery (10) includes a positive electrode active material of lithium transition metal oxide which contains at least a nickel element and a manganese element as transition metals and for which, with respect to a diffraction peak A located at a diffraction angle 20 of 17° to 20° and a diffraction peak B located at a diffraction angle 2Θ of 43° to 46° from X-ray diffraction measurements, when the integrated intensity ratio is R1=IA/IB, the peak intensity ratio is RH=HA/HB, and the ratio between the integrated intensity ratio R1 and the peak intensity ratio RH is SF=RH/R1>> the SF satisfies 1.1≦SF≦2.2.
摘要翻译： 锂二次电池（10）包括锂过渡金属氧化物的正极活性物质，其至少包含镍元素和锰元素作为过渡金属，并且对于衍射峰A，位于衍射角20的衍射角 17°〜20°的衍射峰B和衍射角2θ为43°〜46°的X射线衍射测定时的衍射峰B，当积分强度比为R1 = IA / IB时，峰强度比为RH = HA / HB，积分强度比R1与峰值强度比RH之比为SF = RH / R1 >> SF满足1.1≤SS≤2.2。
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公开(公告)号：US09263729B2
公开(公告)日：2016-02-16
申请号：US13522758
申请日：2010-01-21
申请人： Hiroki Nagai , Masahiro Morita , Yukihiro Okada
发明人： Hiroki Nagai , Masahiro Morita , Yukihiro Okada
IPC分类号： H01M4/13 , H01M4/131 , H01M4/62 , H01M10/052 , H01M4/02
CPC分类号： H01M4/13 , H01M4/131 , H01M4/625 , H01M10/052 , H01M2004/021 , Y02E60/122 , Y02P70/54 , Y02T10/7011 , Y10T29/49108
摘要： A lithium secondary battery of the present invention has a positive electrode is provided with a positive electrode mix layer that includes a positive electrode active material and a conductive material. The positive electrode mix layer has two peaks, large and small, of differential pore volume over a pore size ranging from 0.01 μm to 10 μm in a pore distribution curve measured by a mercury porosimeter. A pore size of the smaller peak B of the differential pore volume is smaller than a pore size of the larger peak A of the differential pore volume.
摘要翻译： 本发明的锂二次电池具有正极，其具有包括正极活性物质和导电性材料的正极混合层。 在通过水银孔率计测量的孔分布曲线中，正电极混合层在0.01μm至10μm的孔径范围内具有大的和小的不同孔体积的峰。 不同孔体积的较小峰B的孔径小于微孔体积的较大峰A的孔径。
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公开(公告)号：US09209459B2
公开(公告)日：2015-12-08
申请号：US13879042
申请日：2010-10-15
申请人： Hiroki Nagai , Masahiro Morita , Takashi Iwao
发明人： Hiroki Nagai , Masahiro Morita , Takashi Iwao
CPC分类号： H01M4/485 , H01M4/131 , H01M4/505 , H01M4/525 , Y02E60/122
摘要： A secondary battery 100 includes a positive electrode current collector 221 and a positive electrode mixture layer 223 which is coated over the positive electrode current collector 221. The positive electrode mixture layer 223 includes a positive electrode active material 610, an electrically conductive material 620, and a binder 630. In addition, the positive electrode active material 610 has secondary particles 910 formed by an aggregation of a plurality of primary particles of a lithium transition metal oxide, a hollow portion 920 formed in the secondary particle 910, and through holes 930 penetrating the secondary particles 910 so as to connect the hollow portion 920 and the outside. A ratio (Vbc/Va) of an inner volume Vbc of holes formed inside the positive electrode mixture layer 223 to an apparent volume Va of the positive electrode mixture layer 223 satisfies 0.25≦(Vbc/Va). In addition, in a section of the positive electrode mixture layer 223, a ratio (Vb/Vc) of an inner volume Vb of holes B formed inside the positive electrode active material 610 to an inner volume Vc of holes C formed outside the positive electrode active material 610 satisfies 0.05≦(Vb/Vc)≦2.5.
摘要翻译： 二次电池100包括正极集电体221和涂覆在正极集电体221上的正极合剂层223.正极合剂层223包括正极活性物质610，导电材料620和 粘合剂630.另外，正极活性物质610具有通过多次锂过渡金属氧化物的一次粒子，形成在二次粒子910中的中空部920的聚集而形成的二次粒子910和穿透 二次粒子910，以便连接中空部分920和外部。 正极合剂层223内形成的孔的内部体积Vbc与正极合剂层223的表观体积Va的比（Vbc / Va）满足0.25＆lt; nlE;（Vbc / Va）。 另外，在正极合剂层223的截面中，形成在正极活性物质610内的孔B的内部容积Vb与形成在正极外侧的孔C的内部容积Vc的比（Vb / Vc） 活性物质610满足0.05＆nlE;（Vb / Vc）＆nlE; 2.5。
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公开(公告)号：US09196891B2
公开(公告)日：2015-11-24
申请号：US13531085
申请日：2012-06-22
摘要： An electrode is provided with a metal terminal extending from a battery module main body, a bolt which has an expanded section configuring a retaining section at a rear end portion and penetrates the metal terminal upward, and an insulating body which insulates the metal terminal and the battery module case one from the other. The insulating body is provided with a drop preventing section which abuts at least a lower surface of the expanded section of the bolt and prevents the bolt from dropping from the metal terminal.
摘要翻译： 电极设置有从电池模块主体延伸的金属端子，螺栓，该螺栓具有在后端部处构成保持部并且向上穿过金属端子的膨胀部，以及绝缘体，其将金属端子和 电池模块一个从另一个。 绝缘体设置有防止突出部的至少下表面的防滴落部，防止螺栓从金属端子落下。
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公开(公告)号：US09196889B2
公开(公告)日：2015-11-24
申请号：US12522005
申请日：2008-01-11
摘要： An electrode is provided with a metal terminal extending from a battery module main body, a bolt which has an expanded section configuring a retaining section at a rear end portion and penetrates the metal terminal upward, and an insulating body which insulates the metal terminal and the battery module case one from the other. The insulating body is provided with a drop preventing section which abuts at least a lower surface of the expanded section of the bolt and prevents the bolt from dropping from the metal terminal.
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