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1.发明授权
公开(公告)号：US5548050A
公开(公告)日：1996-08-20
申请号：US390737
申请日：1995-02-17
申请人： Nobuo Kushibiki , Yoko Sugata , Toshio Suzuki
发明人： Nobuo Kushibiki , Yoko Sugata , Toshio Suzuki
IPC分类号： C08G77/22 , C08G77/398 , C08G77/58 , C08G79/00
摘要： The invention is a method for the preparation of organic solvent-soluble polytitanosiloxanes that contain units with the formulas R.sup.1.sub.a R.sup.2.sub.(3-a) SiO.sub. 1/2 (M units), SiO.sub. 4/2 (Q units) and TiO.sub. 4/2. The method comprises hydrolyzing tetraalkyl titanate or a partial hydrolyzate-condensate thereof and tetraalkyl silicate or a partial hydrolyzate-condensate thereof using water in an amount which is less than 80% of the amount theoretically necessary for the hydrolysis of all the alkoxy groups, and reacting the cohydrolyzate-cocondensate with at least 1 silane compound with the formula R.sup.1.sub.a R.sup.2.sub.3-a) SiOR.sup.3, where in the preceding formulas, R.sup.1 is the hydrogen atom or a monovalent organic group, R.sup.2 is a monovalent organic group, R.sup.3 is the hydrogen atom or an acyl group having no more than 8 carbon atoms, and a is an integer with a value of 0 to 3.
摘要翻译： 本发明是一种制备有机溶剂可溶性聚钛硅氧烷的方法，其含有式R1aR2（3-a）SiO + E，1/2 + EE（M单元），SiO + E， EE（Q单位）和TiO + E，fra 4/2 + EE。 该方法包括使用水的四烷基钛酸盐或其部分水解产物 - 缩合物和四烷基硅酸盐或其部分水解产物 - 缩合物，其用量小于全部烷氧基水解所需理论量的80％，并使 与至少1个具有式R 1a R 23-a）SiOR 3的共 - 水缩合 - 缩合，其中在前述式中，R 1是氢原子或一价有机基团，R 2是一价有机基团，R 3是氢原子或 不大于8个碳原子的酰基，a是0-3的整数。
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2.发明授权Curable polytitanosiloxane compositions and method for preparing cured polytitanosiloxanes using said compositions 失效可固化聚钛硅氧烷组合物和使用所述组合物制备固化的聚钛硅氧烷的方法
公开(公告)号：US5596060A
公开(公告)日：1997-01-21
申请号：US414603
申请日：1995-03-31
申请人： Nobuo Kushibiki , Yoko Sugata , Toshio Suzuki
发明人： Nobuo Kushibiki , Yoko Sugata , Toshio Suzuki
IPC分类号： C08L83/05 , C08G77/58 , C08G79/00 , C08G79/14 , C08L83/07 , C09D183/14 , C09D185/00 , C08G77/08
CPC分类号： C09D183/14 , C08G79/00
摘要： This invention provides curable compositions comprising a polytitanosiloxane containing at least two alkenyl radicals per molecule and a crosslinking agent that is either 1) the combination of an organohydrogensiloxane containing at least two silicon-bonded hydrogen atoms per molecule and a platinum-containing catalyst or 2) an organic peroxide. This invention also provides a method for curing a polytitanosiloxane by reacting it with the crosslinking agent of the present compositions.
摘要翻译： 本发明提供可固化组合物，其包含每分子含有至少两个烯基的聚钛硅氧烷和交联剂，其为1）每分子含有至少两个与硅键合的氢原子的有机氢硅氧烷与含铂催化剂的组合，或2） 有机过氧化物。 本发明还提供了通过使本发明组合物的交联剂与聚钛氧硅烷反应来固化的方法。
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3.发明授权
公开(公告)号：US5739948A
公开(公告)日：1998-04-14
申请号：US730721
申请日：1996-10-08
申请人： Nobuo Kushibiki , Fumito Nishida , Takuya Ogawa , Toshio Suzuki
发明人： Nobuo Kushibiki , Fumito Nishida , Takuya Ogawa , Toshio Suzuki
CPC分类号： G02F1/0147
摘要： A refractive index modulation element made of a refractive index modulation material. The refractive index can be thermally modulated. The refractive index modulation material can be a silicone resin represented by the following formula R.sub.n SiO.sub.(4--n)/2,where the average value of n is 0.5 to 3 and where K is an aliphatic or aromatic group with 1 to 18 carbon atoms or other functional group. The silicone resin has a spectral transmission factor that on average is higher than 80%, within the wavelength range of 350 nm to 1,600 nm, and a refractive index temperature dependence of -0.001/.degree.C. to -0.00005/.degree.C.
摘要翻译： 由折射率调制材料制成的折射率调制元件。 折射率可以进行热调制。 折射率调制材料可以是由下式RnSiO（4-n）/ 2表示的有机硅树脂，其中n的平均值为0.5-3，其中K是具有1至18个碳原子的脂族或芳族基团或 其他功能组。 硅树脂的光谱透过率平均高于80％，在350nm至1600nm的波长范围内，折射率温度依赖性为-0.001 /℃至-0.00005 /℃。
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公开(公告)号：US5739199A
公开(公告)日：1998-04-14
申请号：US721788
申请日：1996-09-26
申请人： Katsuya Eguchi , Nobuo Kushibiki , Toshio Suzuki
发明人： Katsuya Eguchi , Nobuo Kushibiki , Toshio Suzuki
摘要： Cross-liked resins exhibiting a high level of optical transparency and little variation of refractive index with temperature are prepared using mixtures of two organosiloxane resins in combination with a reinforcing silica filler. The types and relative concentrations of hydrocarbon radicals in the resins are within specified limits to obtain the required optical properties and each resin contains groups that react with groups on the other resin to form a crosslinked network.
摘要翻译： 使用两种有机硅氧烷树脂与增强二氧化硅填料组合的混合物制备具有高水平的光学透明性和折射率随温度变化小的交叉树脂。 树脂中烃基的类型和相对浓度在规定的限度内，以获得所需的光学性能，并且每个树脂含有与另一树脂上的基团反应形成交联网络的基团。
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公开(公告)号：US07381470B2
公开(公告)日：2008-06-03
申请号：US10516840
申请日：2003-06-05
IPC分类号： B32B9/04
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08J5/18 , C08J2383/04 , C09D183/04 , C23C26/00 , Y10T428/31663 , C08L83/00
摘要： The present invention relates to a film made from a cross-linked polysiloxane obtained by subjecting a polysiloxane that has a specific chemical structure and contains at least two unsaturated aliphatic hydrocarbon groups in one molecule and an organosilicon compound with at least two hydrogen atoms directly bonded to silicon atoms in one molecule to cross-linking reaction in the presence of a platinum-type catalyst.The film provided by the invention possesses superior heat-resistant properties, has excellent permeability for light in the visible wavelength range, is characterized by low birefringence, and demonstrates physical properties suitable for practical application. By forming an inorganic substance layer on the aforementioned polysiloxane, it is possible to use the laminated film of the invention, e.g., as a transparent electrode film.
摘要翻译： 本发明涉及一种由交联聚硅氧烷制成的薄膜，其通过使具有特定化学结构并在一个分子中含有至少两个不饱和脂族烃基的聚硅氧烷和至少两个氢原子的有机硅化合物直接键合到 一个分子中的硅原子在铂型催化剂存在下交联反应。 本发明提供的薄膜具有优异的耐热性能，对可见光波长范围的光具有极好的透过性，其特征在于双折射低，并表现出适用于实际应用的物理性能。 通过在上述聚硅氧烷上形成无机物质层，可以使用本发明的层压膜，例如作为透明电极膜。
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公开(公告)号：US06592945B2
公开(公告)日：2003-07-15
申请号：US09798123
申请日：2001-03-02
申请人： Masaaki Suzuki , Maria Teresa de los Arcos de Pedro , Yoshinori Nakata , Yoshiho Imai , Munehiro Yamaguchi , Nobuo Kushibiki , Kikuko Takeuchi
发明人： Masaaki Suzuki , Maria Teresa de los Arcos de Pedro , Yoshinori Nakata , Yoshiho Imai , Munehiro Yamaguchi , Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： B05D302
CPC分类号： C08L83/04 , B82Y30/00 , C08G77/06 , C08J3/203 , C08J2383/04 , C08K3/01 , C08K3/08 , C08K2201/011 , C09D183/04 , Y10T428/31663 , C08L2666/54
摘要： The present invention provides a nanoparticle dispersed structure featuring a polymer having a crosslinked structure that is chemically inert with respect to the nanoparticles and that is effective in suppressing diffusion, and provides a method for manufacturing this nanoparticle dispersion.
摘要翻译： 本发明提供一种纳米颗粒分散结构，其特征在于具有相对于纳米颗粒具有化学惰性的交联结构的聚合物，并且有效抑制扩散，并提供了制造该纳米颗粒分散体的方法。
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7.发明授权Method of manufacturing a cohydrolyzed polysiloxane charge transporting material 失效共水解聚硅氧烷电荷输送材料的制备方法
公开(公告)号：US5712360A
公开(公告)日：1998-01-27
申请号：US743262
申请日：1996-11-04
申请人： Hideki Kobayashi , Nobuo Kushibiki
发明人： Hideki Kobayashi , Nobuo Kushibiki
摘要： The invention provides a method for manufacturing a polysiloxane resin with charge transporting properties by uniformly bonding charge transporting groups in effective concentration within a polysiloxane resin. The charge transporting groups are formed in the resin by cohydrolyzing and condensing silane monomers with an aromatically substituted tertiary amine which has been modified by substitution of one or more of the aromatic rings with a hydrocarbon group containing a silyl group bearing hydrolyzable substituents. Tertiary amines have ionization potentials of 4.5 to 6.2 volts.
摘要翻译： 本发明提供一种通过在聚硅氧烷树脂内有效浓度均匀地结合电荷输送基团来制造具有电荷输送性能的聚硅氧烷树脂的方法。 通过将硅烷单体与芳族取代的叔胺进行共水解和缩合而形成电荷输送基团，该芳族取代的叔胺通过用含有含有可水解取代基的甲硅烷基的烃基取代一个或多个芳环而被改性。 叔胺的电离电位为4.5至6.2伏特。
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公开(公告)号：US5231520A
公开(公告)日：1993-07-27
申请号：US376745
申请日：1989-07-06
CPC分类号： G03H1/18 , G03F7/001 , G03H1/02 , G03H1/0248 , G03H1/182 , G03H2001/0264 , G03H2260/12
摘要： A volume phase type hologram has a diffraction lattice recorded in a poly(N-vinyl carbazole) polymer layer where the diffraction lattice is recorded throughout the thickness direction of the polymer layer. A method for preparing the volume phase type hologram has the steps of exposing a photosensitive polymer layer provided on a substrate to an interference pattern; subjecting the polymer layer having been exposed to a first development treatment with a first organic solvent; and peeling the polymer layer off the substrate and subjecting the polymer to a second development treatment with a second organic solvent preferentially from the face that had been in contact with the substrate.
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9.发明申请Cured Organopolysiloxane Resin Film Having Gas Barrier Properties and Method Of Producing The Same 审中-公开具有阻气性的固化有机聚硅氧烷树脂膜及其制造方法公开(公告)号：US20110177342A1
公开(公告)日：2011-07-21
申请号：US13003316
申请日：2009-06-26
申请人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Hidekatsu Hatanaka , Katsuya Eguchi , Dimitris Elias Katsoulis
发明人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Hidekatsu Hatanaka , Katsuya Eguchi , Dimitris Elias Katsoulis
IPC分类号： B32B27/08 , B32B27/38 , B32B9/00 , C23C16/34 , C23C16/40 , C23C14/06 , C23C14/22 , B05D5/00 , B05D3/00
CPC分类号： C08J7/045 , C08J2383/04 , C08L83/04 , Y10T428/31515 , Y10T428/31663 , C08L83/00
摘要： A cured organopolysiloxane resin film having gas barrier properties in which a layer of cured organopolysiloxane that contains an organic functional group, an organic group produced by the polymerization of polymerizable organic functional groups, or the hydrosilyl group or silanol group, is formed on a visible region-transparent film comprising cured organopolysiloxane resin yielded by hydrosilylation reaction-mediated crosslinking, and in which a silicon oxynitride layer, silicon nitride layer, or silicon oxide layer is formed on the aforementioned layer of cured organopolysiloxane. Also, a method of producing this cured organopolysiloxane resin film having gas barrier properties.
摘要翻译： 在具有气体阻隔性的固化有机聚硅氧烷树脂膜上形成含有有机官能团的固化有机聚硅氧烷，通过聚合性有机官能团聚合生成的有机基团或氢化硅烷基或硅烷醇基的可见区域 - 透明的膜包括通过氢化硅烷化反应介导的交联产生的固化的有机聚硅氧烷树脂，并且其中在上述固化的有机聚硅氧烷层上形成氧氮化硅层，氮化硅层或氧化硅层。 另外，制造具有阻气性的固化的有机聚硅氧烷树脂膜的方法。
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10.发明授权Free films made of cured organopolysiloxane resins, process for production thereof, and laminated films 有权由固化的有机聚硅氧烷树脂制成的游离膜，其制造方法和层压膜公开(公告)号：US07960030B2
公开(公告)日：2011-06-14
申请号：US11569104
申请日：2005-05-13
申请人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
发明人： Maki Itoh , Michitaka Suto , Nobuo Kushibiki , Katsuya Eguchi
IPC分类号： B32B15/08 , B29C71/00 , C08F283/12 , C08J5/18
CPC分类号： C08J5/18 , C08G77/12 , C08G77/20 , C08G77/70 , C08J2383/04 , C08K3/22 , C08L83/04 , Y10T156/1158 , Y10T428/31663 , C08L83/00
摘要： A free-standing film comprising a cured organopolysiloxane resin obtained by conducting a cross-linking reaction between (A) an organopolysiloxane resin represented by the following average siloxane unit formula: [R1aR23-aSiO1/2]v[R3SiO3/2]w (1) or [R1aR23-aSiO1/2]x[R3SiO3/2]y[SiO4/2]z (2) (where R1 designates univalent hydrocarbon groups of one or more than one type selected from alkyl groups having 1 to 4 carbon atoms and univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; R2 designate alkenyl groups having 2 to 6 carbon atoms; R3 designates alkyl groups with 1 to 4 carbon atoms or univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; at least 50 mole % of R3 groups being phenyl groups; “a” is 0, 1, or 2; 0.8≦w
摘要翻译： 通过在（A）由以下平均硅氧烷单元式：[R a R 23-a SiO 1/2/2] v [R 3 SiO 3/2] w（1）表示的有机聚硅氧烷树脂之间进行交联反应获得的固化的有机聚硅氧烷树脂， ）或[R1aR23-aSiO1 / 2] x [R3SiO3 / 2] y [SiO4 / 2] z（2）（其中R1表示一个或多于一种选自具有1至4个碳原子的烷基的一价烃基， 具有6至8个碳原子的单价芳族烃基; R 2表示具有2至6个碳原子的烯基; R 3表示具有1至4个碳原子的烷基或具有6至8个碳原子的单价芳族烃基;至少50摩尔％ R3为苯基;“a”为0,1或2;0.8≤n1E; w <1.0且v + w = 1; 0
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