公开(公告)号：US20110177342A1

公开(公告)日：2011-07-21

申请号：US13003316

申请日：2009-06-26

申请人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Hidekatsu Hatanaka ,  Katsuya Eguchi ,  Dimitris Elias Katsoulis

发明人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Hidekatsu Hatanaka ,  Katsuya Eguchi ,  Dimitris Elias Katsoulis

IPC分类号： B32B27/08 ,  B32B27/38 ,  B32B9/00 ,  C23C16/34 ,  C23C16/40 ,  C23C14/06 ,  C23C14/22 ,  B05D5/00 ,  B05D3/00

CPC分类号： C08J7/045 ,  C08J2383/04 ,  C08L83/04 ,  Y10T428/31515 ,  Y10T428/31663 ,  C08L83/00

摘要： A cured organopolysiloxane resin film having gas barrier properties in which a layer of cured organopolysiloxane that contains an organic functional group, an organic group produced by the polymerization of polymerizable organic functional groups, or the hydrosilyl group or silanol group, is formed on a visible region-transparent film comprising cured organopolysiloxane resin yielded by hydrosilylation reaction-mediated crosslinking, and in which a silicon oxynitride layer, silicon nitride layer, or silicon oxide layer is formed on the aforementioned layer of cured organopolysiloxane. Also, a method of producing this cured organopolysiloxane resin film having gas barrier properties.

摘要翻译： 在具有气体阻隔性的固化有机聚硅氧烷树脂膜上形成含有有机官能团的固化有机聚硅氧烷，通过聚合性有机官能团聚合生成的有机基团或氢化硅烷基或硅烷醇基的可见区域 - 透明的膜包括通过氢化硅烷化反应介导的交联产生的固化的有机聚硅氧烷树脂，并且其中在上述固化的有机聚硅氧烷层上形成氧氮化硅层，氮化硅层或氧化硅层。 另外，制造具有阻气性的固化的有机聚硅氧烷树脂膜的方法。

公开(公告)号：US20090084428A1

公开(公告)日：2009-04-02

申请号：US12297358

申请日：2007-04-18

申请人： Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Lawrence M. Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin

发明人： Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Lawrence M. Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin

IPC分类号： H01L31/042

CPC分类号： H01L31/0322 ,  C08G77/12 ,  C08G77/16 ,  C08G77/20 ,  C08L83/04 ,  H01L31/072 ,  H01L31/0749 ,  Y02E10/541 ,  C08L83/00

摘要： A copper indium diselenide (CIS)-based photovoltaic device includes a CIS-based solar absorber layer including copper, indium, and selenium. The CIS-based photovoltaic device further includes a substrate including a silicone layer formed from a silicone composition and a metal foil layer. The substrate, due to the presence of the silicone layer and the metal foil layer, is both flexible and sufficiently able to withstand annealing temperatures in excess of 500° C. to obtain maximum efficiency of the device.

摘要翻译： 基于铜铟锡（CIS）的光伏器件包括包含铜，铟和硒的基于CIS的太阳能吸收层。 所述基于CIS的光电装置还包括由硅氧烷组合物和金属箔层形成的硅氧烷层的基板。 由于存在硅树脂层和金属箔层，衬底既柔软又足以承受超过500℃的退火温度，以获得器件的最大效率。

公开(公告)号：US08207442B2

公开(公告)日：2012-06-26

申请号：US11737119

申请日：2007-04-18

申请人： Lawrence M. Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin ,  Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Nicole R. Anderson ,  Herschel Henry Reese

发明人： Lawrence M. Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin ,  Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Nicole R. Anderson ,  Herschel Henry Reese

IPC分类号： H01L31/00

CPC分类号： H01L31/0392 ,  H01L31/03921 ,  H01L31/03928 ,  H01L31/046 ,  H01L31/0463 ,  H01L31/0749 ,  Y02E10/541

摘要： In an embodiment, one reinforced substrate for use in a photovoltaic device includes a polymer base material and a reinforcing structure bonded with the base material. The reinforced substrate presents a surface in a condition that is made-ready for deposition of thin film layers of the photovoltaic device. A thin film photovoltaic device includes the reinforced substrate, a back contact layer formed on the surface of the reinforced substrate, and a solar absorber layer formed on the back contact layer. A plurality of thin film photovoltaic devices may be formed on a common reinforced substrate. A process of producing a reinforced substrate includes combining a fluid base material and a fiber reinforcing structure to form an impregnated fiber reinforcement. The impregnated fiber reinforcement is cured to form the reinforced substrate, and the reinforced substrate is annealed.

摘要翻译： 在一个实施例中，用于光伏器件的一个增强衬底包括聚合物基材和与基材结合的增强结构。 增强的基底呈现出一个表面，该表面被制备用于沉积光伏器件的薄膜层。 薄膜光伏器件包括增强衬底，形成在增强衬底的表面上的背接触层和形成在后接触层上的太阳能吸收层。 多个薄膜光伏器件可以形成在共同的增强衬底上。 制造增强基材的方法包括组合流体基材和纤维增强结构以形成浸渍的纤维增强材料。 浸渍的纤维增强材料被固化以形成增强的基底，并且加强的基底被退火。

公开(公告)号：US20080115827A1

公开(公告)日：2008-05-22

申请号：US11737119

申请日：2007-04-18

申请人： Lawrence M Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin ,  Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Nicole R. Anderson ,  Herschel Henry Reese

发明人： Lawrence M Woods ,  Joseph H. Armstrong ,  Rosine M. Ribelin ,  Thomas Duncan Barnard ,  Yukinari Harimoto ,  Hidekatsu Hatanaka ,  Maki Itoh ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu ,  Nicole R. Anderson ,  Herschel Henry Reese

IPC分类号： H01L31/0216 ,  B05D5/12

CPC分类号： H01L31/0392 ,  H01L31/03921 ,  H01L31/03928 ,  H01L31/046 ,  H01L31/0463 ,  H01L31/0749 ,  Y02E10/541

摘要： In an embodiment, one reinforced substrate for use in a photovoltaic device includes a polymer base material and a reinforcing structure bonded with the base material. The reinforced substrate presents a surface in a condition that is made-ready for deposition of thin film layers of the photovoltaic device. A thin film photovoltaic device includes the reinforced substrate, a back contact layer formed on the surface of the reinforced substrate, and a solar absorber layer formed on the back contact layer. A plurality of thin film photovoltaic devices may be formed on a common reinforced substrate. A process of producing a reinforced substrate includes combining a fluid base material and a fiber reinforcing structure to form an impregnated fiber reinforcement. The impregnated fiber reinforcement is cured to form the reinforced substrate, and the reinforced substrate is annealed.

摘要翻译： 在一个实施例中，用于光伏器件的一个增强衬底包括聚合物基材和与基材结合的增强结构。 增强的基底呈现出一个表面，该表面被制备用于沉积光伏器件的薄膜层。 薄膜光伏器件包括增强衬底，形成在增强衬底的表面上的背接触层和形成在后接触层上的太阳能吸收层。 多个薄膜光伏器件可以形成在共同的增强衬底上。 制造增强基材的方法包括组合流体基材和纤维增强结构以形成浸渍的纤维增强材料。 浸渍的纤维增强材料被固化以形成增强的基底，并且加强的基底被退火。

公开(公告)号：US07960030B2

公开(公告)日：2011-06-14

申请号：US11569104

申请日：2005-05-13

申请人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Katsuya Eguchi

发明人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Katsuya Eguchi

IPC分类号： B32B15/08 ,  B29C71/00 ,  C08F283/12 ,  C08J5/18

CPC分类号： C08J5/18 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08J2383/04 ,  C08K3/22 ,  C08L83/04 ,  Y10T156/1158 ,  Y10T428/31663 ,  C08L83/00

摘要： A free-standing film comprising a cured organopolysiloxane resin obtained by conducting a cross-linking reaction between (A) an organopolysiloxane resin represented by the following average siloxane unit formula: [R1aR23-aSiO1/2]v[R3SiO3/2]w (1) or [R1aR23-aSiO1/2]x[R3SiO3/2]y[SiO4/2]z (2) (where R1 designates univalent hydrocarbon groups of one or more than one type selected from alkyl groups having 1 to 4 carbon atoms and univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; R2 designate alkenyl groups having 2 to 6 carbon atoms; R3 designates alkyl groups with 1 to 4 carbon atoms or univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; at least 50 mole % of R3 groups being phenyl groups; “a” is 0, 1, or 2; 0.8≦w

摘要翻译： 通过在（A）由以下平均硅氧烷单元式：[R a R 23-a SiO 1/2/2] v [R 3 SiO 3/2] w（1）表示的有机聚硅氧烷树脂之间进行交联反应获得的固化的有机聚硅氧烷树脂， ）或[R1aR23-aSiO1 / 2] x [R3SiO3 / 2] y [SiO4 / 2] z（2）（其中R1表示一个或多于一种选自具有1至4个碳原子的烷基的一价烃基， 具有6至8个碳原子的单价芳族烃基; R 2表示具有2至6个碳原子的烯基; R 3表示具有1至4个碳原子的烷基或具有6至8个碳原子的单价芳族烃基;至少50摩尔％ R3为苯基;“a”为0,1或2;0.8≤n1E; w <1.0且v + w =​​ 1; 0

公开(公告)号：US20080318067A1

公开(公告)日：2008-12-25

申请号：US11569104

申请日：2005-05-13

申请人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Katsuya Eguchi

发明人： Maki Itoh ,  Michitaka Suto ,  Nobuo Kushibiki ,  Katsuya Eguchi

IPC分类号： B32B9/00 ,  C08G77/38 ,  B32B38/10

CPC分类号： C08J5/18 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08J2383/04 ,  C08K3/22 ,  C08L83/04 ,  Y10T156/1158 ,  Y10T428/31663 ,  C08L83/00

摘要： A free-standing film comprising a cured organopolysiloxane resin obtained by conducting a cross-linking reaction between (A) an organopolysiloxane resin represented by the following average siloxane unit formula: [R1aR23-aSiO1/2]v[R3SiO3/2]w (1) or [R1aR23-aSiO1/2]x[R3SiO3/2]y[SiO4/2]z (2) (where R1 designates univalent hydrocarbon groups of one or more than one type selected from alkyl groups having 1 to 4 carbon atoms and univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; R2 designate alkenyl groups having 2 to 6 carbon atoms; R3 designates alkyl groups with 1 to 4 carbon atoms or univalent aromatic hydrocarbon groups having 6 to 8 carbon atoms; at least 50 mole % of R3 groups being phenyl groups; “a” is 0, 1, or 2; 0.8≦w

摘要翻译： 通过在（A）由以下平均硅氧烷单元：[R1aR23-aSiO1 / 2] v [R3SiO3 / 2] w（1）表示的有机聚硅氧烷树脂之间进行交联反应获得的固化的有机聚硅氧烷树脂 ）或[R1aR23-aSiO1 / 2] x [R3SiO3 / 2] y [SiO4 / 2] z（2）（其中R1表示一个或多于一种选自具有1至4个碳原子的烷基的一价烃基， 具有6至8个碳原子的一价芳族烃基; R 2表示具有2至6个碳原子的烯基; R 3表示具有1至4个碳原子的烷基或具有6至8个碳原子的单价芳族烃基;至少50摩尔％ R3为苯基;“a”为0,1或2; 0.8 <= w <1.0且v + w =​​ 1; 0

公开(公告)号：US07381470B2

公开(公告)日：2008-06-03

申请号：US10516840

申请日：2003-06-05

申请人： Michitaka Suto ,  Dimitris Elias Katsoulis ,  Nobuo Kushibiki

发明人： Michitaka Suto ,  Dimitris Elias Katsoulis ,  Nobuo Kushibiki

IPC分类号： B32B9/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08J5/18 ,  C08J2383/04 ,  C09D183/04 ,  C23C26/00 ,  Y10T428/31663 ,  C08L83/00

摘要： The present invention relates to a film made from a cross-linked polysiloxane obtained by subjecting a polysiloxane that has a specific chemical structure and contains at least two unsaturated aliphatic hydrocarbon groups in one molecule and an organosilicon compound with at least two hydrogen atoms directly bonded to silicon atoms in one molecule to cross-linking reaction in the presence of a platinum-type catalyst.The film provided by the invention possesses superior heat-resistant properties, has excellent permeability for light in the visible wavelength range, is characterized by low birefringence, and demonstrates physical properties suitable for practical application. By forming an inorganic substance layer on the aforementioned polysiloxane, it is possible to use the laminated film of the invention, e.g., as a transparent electrode film.

摘要翻译： 本发明涉及一种由交联聚硅氧烷制成的薄膜，其通过使具有特定化学结构并在一个分子中含有至少两个不饱和脂族烃基的聚硅氧烷和至少两个氢原子的有机硅化合物直接键合到 一个分子中的硅原子在铂型催化剂存在下交联反应。 本发明提供的薄膜具有优异的耐热性能，对可见光波长范围的光具有极好的透过性，其特征在于双折射低，并表现出适用于实际应用的物理性能。 通过在上述聚硅氧烷上形成无机物质层，可以使用本发明的层压膜，例如作为透明电极膜。

公开(公告)号：US20110011447A1

公开(公告)日：2011-01-20

申请号：US12681521

申请日：2008-10-03

申请人： Yukinari Harimoto ,  Tetsuyuki Michino ,  Dimitris Elias Katsoulis ,  Nobuo Kushibiki ,  Michitaka Suto

发明人： Yukinari Harimoto ,  Tetsuyuki Michino ,  Dimitris Elias Katsoulis ,  Nobuo Kushibiki ,  Michitaka Suto

IPC分类号： H01L31/0216 ,  B05D3/04 ,  B05D3/02 ,  C08L83/06

CPC分类号： H01L21/316 ,  C09D183/04 ,  C23C18/1208 ,  C23C18/122 ,  C23C18/1241 ,  C23C18/1279 ,  C23C2222/20 ,  H01L21/02126 ,  H01L21/02216 ,  H01L21/02282 ,  H01L21/3122 ,  Y02E10/541

摘要： A method of forming a ceramic silicon oxide type coating and a method of producing an inorganic base material having this coating, by coating an organohydrogensiloxane/hydrogensiloxane copolymer on the surface of an inorganic base material and converting the coating into a ceramic silicon oxide type coating by heating to high temperatures in an inert gas or an oxygen-containing inert gas (oxygen gas less than 20 volume %). A coating-forming agent comprising an organohydrogensiloxane/hydrogensiloxane copolymer or its solution. A semiconductor device comprising at least a semiconductor layer formed on a silicon oxide type coating on an inorganic substrate.

摘要翻译： 一种形成陶瓷氧化硅类涂层的方法以及具有该涂层的无机基材的制造方法，通过在无机基材的表面上涂布有机氢硅氧烷/氢硅氧烷共聚物，并将该涂层转化为陶瓷氧化硅类涂层 在惰性气体或含氧惰性气体（氧气小于20体积％）中加热至高温。 包含有机氢硅氧烷/氢硅氧烷共聚物或其溶液的涂层形成剂。 一种半导体器件，其至少包括在无机基板上的氧化硅类型的涂层上形成的半导体层。

公开(公告)号：US20130012087A1

公开(公告)日：2013-01-10

申请号：US13520359

申请日：2011-01-07

申请人： Maki Itoh ,  Michitaka Suto ,  Bizhong Zhu ,  Dimitris Elias Katsoulis ,  Ludmil Zambov

发明人： Maki Itoh ,  Michitaka Suto ,  Bizhong Zhu ,  Dimitris Elias Katsoulis ,  Ludmil Zambov

IPC分类号： B32B27/04 ,  C23C14/06 ,  C23C16/40 ,  B05D3/06 ,  C23C16/34 ,  C23C16/30

CPC分类号： C09D183/04 ,  C08J5/24 ,  C08J2383/04 ,  Y10T428/31663 ,  Y10T442/2098

摘要： A cured organopolysiloxane resin film having gas barrier properties comprising a fiber-reinforced film made of a hydrosilylation-cured organopolysiloxane resin and having a transparent inorganic layer selected from silicon oxynitride layer, silicon nitride layer, and silicon oxide layer formed on the fiber-reinforced film wherein a layer of cured organopolysiloxane that contains an organic functional group, silanol group, hydrosilyl group, or an organic group produced by the polymerization of polymerizable organic functional groups is interposed between said fiber-reinforced film and inorganic layer. Also, a method of producing this cured organopolysiloxane resin film having gas barrier properties.

摘要翻译： 具有阻气性的固化的有机聚硅氧烷树脂膜包含由氢化硅烷化固化的有机聚硅氧烷树脂制成的纤维增强膜，并且具有选自形成在纤维增强膜上的氧氮化硅层，氮化硅层和氧化硅层的透明无机层 其中含有有机官能团，硅烷醇基，氢化硅烷基或通过可聚合有机官能团的聚合制备的有机基团的固化的有机聚硅氧烷层被插入在所述纤维增强膜和无机层之间。 另外，制造具有阻气性的固化有机聚硅氧烷树脂膜的方法。

公开(公告)号：US08092910B2

公开(公告)日：2012-01-10

申请号：US11794924

申请日：2006-02-01

申请人： Debbie Bailey ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu

发明人： Debbie Bailey ,  Dimitris Elias Katsoulis ,  Michitaka Suto ,  Bizhong Zhu

IPC分类号： B32B27/28

CPC分类号： C08J5/04 ,  C08J5/24 ,  C08J2383/04 ,  C08J2383/14 ,  C09D183/04 ,  C09D183/14 ,  Y10T428/31598 ,  C08L83/00

摘要： A method of preparing a reinforced silicone resin film, the method comprising the steps of impregnating a fiber reinforcement in a hydrosilylation-curable silicone composition comprising a silicone resin, and heating the impregnated fiber reinforcement at a temperature sufficient to cure the silicone resin, wherein the reinforced silicone resin film comprises from 10 to 99% (w/w) of the cured silicone resin and the film has a thickness of from 15 to 500 μm; and a reinforced silicone resin film prepared according to the method.

摘要翻译： 一种制备增强硅树脂薄膜的方法，该方法包括以下步骤：将纤维增强物浸渍在包含硅树脂的氢化硅烷化可固化的硅氧烷组合物中，并在足以固化硅树脂的温度下加热浸渍的纤维增强体，其中 增强的有机硅树脂膜包含10至99％（w / w）的固化的有机硅树脂，并且该膜具有15至500μm的厚度; 和根据该方法制备的增强硅树脂膜。