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公开(公告)号：US6162867A
公开(公告)日：2000-12-19
申请号：US254916
申请日：1999-03-17
CPC分类号： C08L25/12 , C08L51/003 , C08L53/025 , Y10S525/902 , C08L2666/24 , C08L2666/02
摘要： The invention relates to thermoplastic molding compositions comprisingA) from 30 to 98% by weight of a graft copolymer comprisinga.sub.K) from 30 to 90% by weight of an elastomeric graft core,a.sub.S) from 10 to 70% by weight of a graft shell comprisinga.sub.S /1) from 50 to 100% by weight of a styrene compound or a C.sub.1 -C.sub.8 -alkyl acrylate or methacrylate, or a mixture thereof, anda.sub.S /2) from 0 to 50% by weight of one or more other monomers,B) from 1 to 50% by weight of a thermoplastic polymer andC) from 1 to 70% by weight of an elastomeric block copolymer prepared by anionic polymerization of the monomers with addition of a potassium compound soluble in non-polar solvents (Step 1) followed by hydrogenation of all or virtually all the olefinic double bonds of the polymer obtained in Step 1, as described in greater detail herein.
摘要翻译： PCT No.PCT / EP97 / 04912 Sec。 371日期1999年3月17日 102（e）1999年3月17日PCT 1997年9月9日PCT公布。 公开号WO98 / 12256 1998年3月26日本发明涉及热塑性模塑组合物，其包含A）30至98重量％的接枝共聚物，其包含aK = 30至90重量％的弹性体接枝芯，aS）10至70重量％ 包含50重量％至100重量％的苯乙烯化合物或丙烯酸或甲基丙烯酸C 1 -C 8烷基酯或其混合物的S / 1）的重量，S / 2）0至50重量％ 一种或多种其它单体，B）1至50重量％的热塑性聚合物和C）1至70重量％的通过单体的阴离子聚合制备的弹性体嵌段共聚物，加入可溶于非离子的钾化合物 - 极性溶剂（步骤1），随后氢化步骤1中获得的聚合物的所有或几乎所有的烯属双键，如本文更详细描述的。
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公开(公告)号：US5877258A
公开(公告)日：1999-03-02
申请号：US740212
申请日：1996-10-25
IPC分类号： B29C47/00 , B29C45/00 , B29C47/14 , C08F265/06 , C08L9/06 , C08L21/00 , C08L25/02 , C08L25/04 , C08L51/00 , C08L51/04 , C08L51/06 , C08L53/02 , C08L71/02
CPC分类号： C08L51/003 , C08L51/06 , C08L53/02 , Y10S525/902
摘要： Thermoplastic molding materials compriseA) from 30 to 98% by weight of a graft polymer ofa.sub.K) from 30 to 90% by weight of an elastomeric graft core, obtainable by copolymerization ofa.sub.K /1) from 80 to 99.99% by weight of a C.sub.1 -C.sub.10 -alkyl ester of acrylic acid,a.sub.K /2) from 0.01 to 20% by weight of a crosslinking monomer anda.sub.K /3) from 0 to 40% by weight of one or more further monomers, anda.sub.S) from 10 to 70% by weight of a graft shell ofa.sub.S /1) from 50 to 100% by weight of a styrene compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, and/or of a C.sub.1 -C.sub.8 -alkyl ester of acrylic acid or methacrylic acid, anda.sub.S /2) from 0 to 50% by weight of one or more further monomers,B) from 1 to 50% by weight of a thermoplastic polymer ofb.sub.1) from 50 to 100% by weight of styrene and/or .alpha.-methylstyrene,b.sub.2) from 0 to 50% by weight of acrylonitrile andb.sub.3) from 0 to 50% by weight of one or more further monomers, andC) from 1 to 70% by weight of a copolymer ofc.sub.1) from 30 to 90% by weight of styrene and/or .alpha.-methylstyrene,C.sub.2) from 10 to 70% by weight of butadiene andC.sub.3) from 0 to 30% by weight of one or more further monomers,in which all or virtually all of the olefinic double bonds have been hydrogenated.
摘要翻译： 热塑性成型材料包括A）30至98重量％的aK的接枝聚合物，30重量％至90重量％的弹性体接枝核心，其通过aK / 1）的80至99.99重量％ 丙烯酸的C1-C10烷基酯，aK / 2）0.01至20重量％的交联单体和K / 3）0至40重量％的一种或多种另外的单体，aS）为10至 70重量％的aS / 1的接枝壳）50至100重量％的通式为“IMAGE”的苯乙烯化合物，其中R 1和R 2各自为氢或C 1 -C 8烷基，和/或 丙烯酸或甲基丙烯酸的C 1 -C 8烷基酯和1/2）0-50％重量的一种或多种其它单体，B）1至50重量％的热塑性聚合物，b1）50 至100重量％的苯乙烯和/或α-甲基苯乙烯，b2）0至50重量％的丙烯腈和b3）0至50重量％的一种或多种其它单体，和C）1至70重量％ 的c1）共聚物 30至90重量％的苯乙烯和/或α-甲基苯乙烯，C2）10至70重量％的丁二烯和C3）0至30重量％的一种或多种其它单体，其中全部或几乎全部 的烯属双键已被氢化。
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公开(公告)号：US5760134A
公开(公告)日：1998-06-02
申请号：US721539
申请日：1996-09-26
申请人： Norbert Guntherberg , Konrad Knoll , Martin Weber
发明人： Norbert Guntherberg , Konrad Knoll , Martin Weber
CPC分类号： C08L51/003 , C08L53/02 , Y10S525/902
摘要： Thermoplastic molding materials of A) from 30 to 98% by weight of a graft polymer of a.sub.c) from 30 to 90% by weight of an elastomeric graft core and a.sub.s) from 10 to 70% by weight of a graft shell, B) from 1 to 50% by weight of a thermoplastic polymer, C) from 1 to 70% by weight of an elastomeric block copolymer, and D) from 0 to 30% by weight of a polymer having a star-like structure.
摘要翻译： A）30至98重量％的交联聚合物（ac）为30至90重量％的弹性体接枝芯，以及10至70重量％的接枝壳，B）从 1至50重量％的热塑性聚合物，C）1至70重量％的弹性体嵌段共聚物，和D）0至30重量％的具有星形结构的聚合物。
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公开(公告)号：US06235839B1
公开(公告)日：2001-05-22
申请号：US09254917
申请日：1999-03-17
IPC分类号： C08L5100
CPC分类号： C08L51/003 , C08F265/04 , C08L25/12 , C08L53/02 , C08L2666/24
摘要： Thermoplastic molding compositions comprising A) a graft polymer comprising 1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and 2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, and B) a thermoplastic polymer comprising C) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.
摘要翻译： 包含A）接枝聚合物的热塑性成型组合物，其包含1）通过一种或多种丙烯酸C 1 -C 10烷基酯的共聚获得的弹性体接枝核心和具有交联效应的单体，和2）包含苯乙烯化合物或C 1 -C 8 烷基丙烯酸酯或甲基丙烯酸酯，或苯乙烯化合物和丙烯酸或甲基丙烯酸C 1 -C 8烷基酯的混合物，和B）包含C）弹性体嵌段共聚物的热塑性聚合物，其中所有或几乎所有的烯属双键已被氢化， 包含至少一个嵌段A，其形成硬质相并且在其聚合物链中包含乙烯基芳族单体和/或嵌段B的单元，所述单元形成第一弹性体（软）相并含有二烯单体，并且至少 一个弹性体嵌段B / A，其形成软相，并且在其聚合物链中随机含有乙烯基芳族单体和二烯的单元，其中嵌段A的玻璃化转变温度Tg高于25° 并且块B / A的相体积比低于25℃，并且选择块A与嵌段B / A的相体积比，使得整个嵌段共聚物中硬相的比例为1至40 体积比，二烯重量比小于50重量％。
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公开(公告)号：US20070167573A1
公开(公告)日：2007-07-19
申请号：US10596344
申请日：2004-12-14
申请人： Martin Stork , Martin Weber , Axel Gottschalk , Sven Riechers , Norbert Guntherberg , Wolfgang Fischer , Ludger Leber , Peter Ittemann , Stephan Jungling
发明人： Martin Stork , Martin Weber , Axel Gottschalk , Sven Riechers , Norbert Guntherberg , Wolfgang Fischer , Ludger Leber , Peter Ittemann , Stephan Jungling
IPC分类号： C08F8/00
CPC分类号： C08L51/04 , C08F257/02 , C08F279/02 , C08F285/00 , C08L25/12 , C08L33/12 , C08L35/06 , C08L51/00 , C08L51/003 , C08L55/02 , C08L2205/03 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2, the essence of the invention being that the first graft shell (C2) is obtainable by polymerizing a monomer mixture consisting of (C21) from 30 to 39% by weight, based on (C2), of a styrenic monomer, (C22) from 61 to 70% by weight, based on (C2), of a C1-C8-alkyl ester of methacrylic acid and (C23) from 0 to 3% by weight, based on (C2), of a crosslinking monomer, and also to processes for producing these molding compositions, to their use and to the moldings obtainable therefrom.
摘要翻译： 本发明涉及热塑性模塑组合物，其包含（A）基于甲基丙烯酸甲酯聚合物的组分（A），（B）和（C）的总和为30至69重量％的混合物，（B） 基于通过聚合苯乙烯类单体和乙烯基氰获得的共聚物的组分（A），（B）和（C）的总和的30至69重量％，和（C）1至40重量％ 以（C）为基准，从（C）得到的（C）成分（A），（B）和（C））的总和为基于（C）为60〜90重量％ 1,3-二烯和苯乙烯单体，（C）基于（C）的5-20重量％（C），第一接枝壳和（C）5-20重量％的（C3） ，由（甲基）丙烯酸烷基酯聚合物组成的第二接枝壳，条件是（C2）与（C3）的比例在2:1至1:2的范围内，本发明的本质是 第一接枝壳（C2）可以通过聚合由（C） 21），基于（C2），基于（C2）的苯乙烯类单体（C22）为30〜39重量％，基于（C2）为61〜70重量％的C 1〜 甲基丙烯酸的C 8 - 烷基酯和（C 23）0-3重量％，基于（C2）的交联单体，以及制备这些模塑组合物的方法， 使用和可从其获得的模制品。
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公开(公告)号：US5969016A
公开(公告)日：1999-10-19
申请号：US772127
申请日：1996-12-20
申请人： Martin Weber , Robert Weiss , Norbert Guntherberg , Klemens Massonne , Joachim Seibring , Guenther Zimmer
发明人： Martin Weber , Robert Weiss , Norbert Guntherberg , Klemens Massonne , Joachim Seibring , Guenther Zimmer
摘要： Molding materials containA) from 5 to 97.9% by weight of at least one polycarbonate having a weight average molecular weight (M.sub.w) of from 10,000 to 64,000 g/mol,B) from 1 to 93.9% by weight of at least one graft copolymer,C) from 1 to 93.9% by weight of at least one copolymerc.sub.1) at least one vinylaromatic compound of the general formula I ##STR1## where R is hydrogen or C.sub.1 -C.sub.8 -alkyl, R.sup.1 is C.sub.1 -C.sub.8 -alkyl and n is an integer from 0 to 3, or of a C.sub.1 -C.sub.8 -alkyl acrylate, a C.sub.1 -C.sub.8 -alkyl C.sub.1 -C.sub.8 -alkylacrylate or a mixture thereof and c.sub.2) acrylonitrile, C.sub.1 -C.sub.8 -alkylacrylonitrile or a mixture thereof,D) from 0.01 to 10% by weight of at least one polyhydroxyether of at least one aliphatic or aromatic diol with epihalohydrin,E) from 1 to 25% by weight of at least one halogen-free phosphorus compound andF) from 0 to 50% by weight of additives.
摘要翻译： 成型材料包含A）5至97.9重量％的至少一种重均分子量（Mw）为10,000至64,000g / mol的聚碳酸酯，B）1至93.9重量％的至少一种接枝共聚物 C）1至93.9重量％的至少一种共聚物c1）至少一种通式I的乙烯基芳族化合物，其中R是氢或C 1 -C 8烷基，R 1是C 1 -C 8 - 烷基，n是整数 丙烯酸C1-C8烷基酯，丙烯酸C1-C8-烷基酯或其混合物，和c2）丙烯腈，C1-C8烷基丙烯腈或其混合物，D）为0.01〜 10重量％的至少一种至少一种脂族或芳族二醇与表卤代醇的聚羟基醚，E）1至25重量％的至少一种无卤素磷化合物和F）0至50重量％的添加剂 。
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7.发明授权Graft copolymers of polyarylene ethers, polyamides and copolymers which contain cyclic, .alpha.,.beta.-unsaturated dicarboxylic anhydrides as polymerized units 失效含有环状α，β-不饱和二羧酸酐作为聚合单元的聚芳醚，聚酰胺和共聚物的接枝共聚物
公开(公告)号：US5907010A
公开(公告)日：1999-05-25
申请号：US820279
申请日：1997-03-18
申请人： Martin Weber , Norbert Guntherberg
发明人： Martin Weber , Norbert Guntherberg
IPC分类号： C08L35/00 , C08F283/06 , C08G65/48 , C08G81/02 , C08L51/08 , C08L71/00 , C08L71/10 , C08L77/00 , C08L39/04
CPC分类号： C08G81/025 , C08G65/48 , C08L71/00
摘要： Graft copolymers are obtainable by reactingA) polyarylene ethers,B) polyamides andC) copolymers which contain cyclic, .alpha.,.beta.-unsaturated dicarboxylic anhydridesand are used for the preparation of thermoplastic molding materials or as compatibilizers for polymer blends based on polyarylene ethers and polyamides.
摘要翻译： 接枝共聚物可以通过使A）聚亚芳基醚，B）聚酰胺和C）含有环状α，β-不饱和二羧酸酐的共聚物反应获得，并且用于制备热塑性成型材料或用作基于聚亚芳基醚和聚亚芳基醚的聚合物共混物的增容剂 聚酰胺。
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公开(公告)号：US06518361B1
公开(公告)日：2003-02-11
申请号：US09647674
申请日：2000-10-03
IPC分类号： C08L2512
CPC分类号： C08F265/04 , C08L51/003 , C08F212/08 , C08L2666/04
摘要： Thermoplastic molding compositions are made from A) from 20 to 98% by weight of a particulate graft polymer and a non-elastomeric graft shell B) from 0.5 to 78.5% by weight of a thermoplastic styrene polymer or copolymer C) from 1 to 79% by weight of a second styrene copolymer and D) from 0.5 to 30% by weight of an isobutene polymer.
摘要翻译： 热塑性模塑组合物由以重量计为20％至98％的颗粒接枝聚合物和非弹性体接枝壳B）0.5至78.5重量％的热塑性苯乙烯聚合物或共聚物C）制成，1至79重量％ 第二苯乙烯共聚物和D）0.5至30重量％的异丁烯聚合物。
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9.发明授权Thermoplastic molding compositions based on acrylonitrile-styrene-acrylate polymers 失效基于丙烯腈 - 苯乙烯 - 丙烯酸酯聚合物的热塑性模塑组合物公开(公告)号：US06531543B1
公开(公告)日：2003-03-11
申请号：US09913121
申请日：2001-08-09
IPC分类号： C08L5100
CPC分类号： C08L23/08 , C08F265/04 , C08L23/22 , C08L25/14 , C08L51/003 , C08L51/06 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： Thermoplastic molding compositions, comprising (A) from 20 to 99% by weight of at least one graft copolymer, (B) from 1 to 80% by weight of a copolymer obtained from at least one alpha-olefin and from at least one polar comonomer, with the proviso that the monomers used are not vinyl acetate or any vinylaromatic monomer, and (C) from 0 to 80% by weight of a thermoplastic polymer, obtained by polymerizing a monomer mixture, of (c1) from 50 to 100% by weight of at least one vinylaromatic monomer and/or of a C1-C8-alkyl (meth)acrylate, and (c2) 0 to 50% by weight of at least one monofunctional comonomer, and (D) from 0.5 to 30% by weight of a (co)polymer made from (d1) from 50 to 100% by weight of isobutene and (d2) from 0 to 50% by weight of one or more other monomers, process of preparing same and their uses.
摘要翻译： 热塑性模塑组合物，其包含（A）20至99重量％的至少一种接枝共聚物，（B）1至80重量％的由至少一种α-烯烃和至少一种极性共聚单体获得的共聚物 条件是使用的单体不是乙酸乙烯酯或任何乙烯基芳族单体，和（C）0至80重量％的热塑性聚合物，通过聚合单体混合物获得（c1）为50-100％的（c1）为50-100％ 至少一种乙烯基芳族单体和/或（甲基）丙烯酸C 1 -C 8烷基酯和（c 2）0至50重量％的至少一种单官能共聚单体的重量，和（D）0.5至30重量％ 由（d1）制备的（共）聚合物，其为50至100重量％的异丁烯和（d2）0至50重量％的一种或多种其它单体，其制备方法及其用途。
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10.发明授权公开(公告)号：US06177517B1
公开(公告)日：2001-01-23
申请号：US08849901
申请日：1997-06-18
IPC分类号： C08L3102
CPC分类号： B32B27/08 , B32B27/302 , B32B27/32 , B32B27/34 , B32B27/36 , C08L53/02 , C08L2666/02
摘要： Thermoplastic molding masses made of thermoplastic polymers obtained by mixed graft polymerization and having a glass transition temperature above 20 C., and of special rubber-elastic block copolymers, are characterized by a balanced spectrum of properties.
摘要翻译： 通过混合接枝聚合获得的玻璃化转变温度高于20℃的热塑性聚合物和特殊的橡胶弹性嵌段共聚物制成的热塑性成型体的特征在于平衡的性质。
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