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    Thermoplastic moulding compounds
    1.
    发明授权
    Thermoplastic moulding compounds 失效
    热塑性模塑料

    公开(公告)号：US6162867A

    公开(公告)日：2000-12-19

    申请号：US254916

    申请日：1999-03-17

    申请人： Norbert Guntherberg ,  Konrad Knoll ,  Martin Weber ,  Gerhard Lindenschmidt

    发明人： Norbert Guntherberg ,  Konrad Knoll ,  Martin Weber ,  Gerhard Lindenschmidt

    IPC分类号： C08J5/18 ,  C08L25/12 ,  C08L51/00 ,  C08L53/02

    CPC分类号： C08L25/12 ,  C08L51/003 ,  C08L53/025 ,  Y10S525/902 ,  C08L2666/24 ,  C08L2666/02

    摘要： The invention relates to thermoplastic molding compositions comprisingA) from 30 to 98% by weight of a graft copolymer comprisinga.sub.K) from 30 to 90% by weight of an elastomeric graft core,a.sub.S) from 10 to 70% by weight of a graft shell comprisinga.sub.S /1) from 50 to 100% by weight of a styrene compound or a C.sub.1 -C.sub.8 -alkyl acrylate or methacrylate, or a mixture thereof, anda.sub.S /2) from 0 to 50% by weight of one or more other monomers,B) from 1 to 50% by weight of a thermoplastic polymer andC) from 1 to 70% by weight of an elastomeric block copolymer prepared by anionic polymerization of the monomers with addition of a potassium compound soluble in non-polar solvents (Step 1) followed by hydrogenation of all or virtually all the olefinic double bonds of the polymer obtained in Step 1, as described in greater detail herein.

    摘要翻译： PCT No.PCT / EP97 / 04912 Sec。 371日期1999年3月17日 102（e）1999年3月17日PCT 1997年9月9日PCT公布。 公开号WO98 / 12256 1998年3月26日本发明涉及热塑性模塑组合物，其包含A）30至98重量％的接枝共聚物，其包含aK = 30至90重量％的弹性体接枝芯，aS）10至70重量％ 包含50重量％至100重量％的苯乙烯化合物或丙烯酸或甲基丙烯酸C 1 -C 8烷基酯或其混合物的S / 1）的重量，S / 2）0至50重量％ 一种或多种其它单体，B）1至50重量％的热塑性聚合物和C）1至70重量％的通过单体的阴离子聚合制备的弹性体嵌段共聚物，加入可溶于非离子的钾化合物 - 极性溶剂（步骤1），随后氢化步骤1中获得的聚合物的所有或几乎所有的烯属双键，如本文更详细描述的。

    Thermoplastic molding materials
    2.
    发明授权
    Thermoplastic molding materials 失效
    热塑性成型材料

    公开(公告)号：US5877258A

    公开(公告)日：1999-03-02

    申请号：US740212

    申请日：1996-10-25

    申请人： Norbert Guntherberg ,  Martin Weber ,  Freddy Gruber ,  Gerhard Lindenschmidt

    发明人： Norbert Guntherberg ,  Martin Weber ,  Freddy Gruber ,  Gerhard Lindenschmidt

    IPC分类号： B29C47/00 ,  B29C45/00 ,  B29C47/14 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02

    CPC分类号： C08L51/003 ,  C08L51/06 ,  C08L53/02 ,  Y10S525/902

    摘要： Thermoplastic molding materials compriseA) from 30 to 98% by weight of a graft polymer ofa.sub.K) from 30 to 90% by weight of an elastomeric graft core, obtainable by copolymerization ofa.sub.K /1) from 80 to 99.99% by weight of a C.sub.1 -C.sub.10 -alkyl ester of acrylic acid,a.sub.K /2) from 0.01 to 20% by weight of a crosslinking monomer anda.sub.K /3) from 0 to 40% by weight of one or more further monomers, anda.sub.S) from 10 to 70% by weight of a graft shell ofa.sub.S /1) from 50 to 100% by weight of a styrene compound of the general formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, and/or of a C.sub.1 -C.sub.8 -alkyl ester of acrylic acid or methacrylic acid, anda.sub.S /2) from 0 to 50% by weight of one or more further monomers,B) from 1 to 50% by weight of a thermoplastic polymer ofb.sub.1) from 50 to 100% by weight of styrene and/or .alpha.-methylstyrene,b.sub.2) from 0 to 50% by weight of acrylonitrile andb.sub.3) from 0 to 50% by weight of one or more further monomers, andC) from 1 to 70% by weight of a copolymer ofc.sub.1) from 30 to 90% by weight of styrene and/or .alpha.-methylstyrene,C.sub.2) from 10 to 70% by weight of butadiene andC.sub.3) from 0 to 30% by weight of one or more further monomers,in which all or virtually all of the olefinic double bonds have been hydrogenated.

    摘要翻译： 热塑性成型材料包括A）30至98重量％的aK的接枝聚合物，30重量％至90重量％的弹性体接枝核心，其通过aK / 1）的80至99.99重量％ 丙烯酸的C1-C10烷基酯，aK / 2）0.01至20重量％的交联单体和K / 3）0至40重量％的一种或多种另外的单体，aS）为10至 70重量％的aS / 1的接枝壳）50至100重量％的通式为“IMAGE”的苯乙烯化合物，其中R 1和R 2各自为氢或C 1 -C 8烷基，和/或 丙烯酸或甲基丙烯酸的C 1 -C 8烷基酯和1/2）0-50％重量的一种或多种其它单体，B）1至50重量％的热塑性聚合物，b1）50 至100重量％的苯乙烯和/或α-甲基苯乙烯，b2）0至50重量％的丙烯腈和b3）0至50重量％的一种或多种其它单体，和C）1至70重量％ 的c1）共聚物 30至90重量％的苯乙烯和/或α-甲基苯乙烯，C2）10至70重量％的丁二烯和C3）0至30重量％的一种或多种其它单体，其中全部或几乎全部 的烯属双键已被氢化。

    Thermoplastic moulding compounds
    3.
    发明授权
    Thermoplastic moulding compounds 失效
    热塑性模塑料

    公开(公告)号：US06235839B1

    公开(公告)日：2001-05-22

    申请号：US09254917

    申请日：1999-03-17

    申请人： Norbert Güntherberg ,  Martin Weber ,  Konrad Knoll ,  Gerhard Lindenschmidt

    发明人： Norbert Güntherberg ,  Martin Weber ,  Konrad Knoll ,  Gerhard Lindenschmidt

    IPC分类号： C08L5100

    CPC分类号： C08L51/003 ,  C08F265/04 ,  C08L25/12 ,  C08L53/02 ,  C08L2666/24

    摘要： Thermoplastic molding compositions comprising A) a graft polymer comprising 1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and 2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, and B) a thermoplastic polymer comprising C) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.

    摘要翻译： 包含A）接枝聚合物的热塑性成型组合物，其包含1）通过一种或多种丙烯酸C 1 -C 10烷基酯的共聚获得的弹性体接枝核心和具有交联效应的单体，和2）包含苯乙烯化合物或C 1 -C 8 烷基丙烯酸酯或甲基丙烯酸酯，或苯乙烯化合物和丙烯酸或甲基丙烯酸C 1 -C 8烷基酯的混合物，和B）包含C）弹性体嵌段共聚物的热塑性聚合物，其中所有或几乎所有的烯属双键已被氢化， 包含至少一个嵌段A，其形成硬质相并且在其聚合物链中包含乙烯基芳族单体和/或嵌段B的单元，所述单元形成第一弹性体（软）相并含有二烯单体，并且至少 一个弹性体嵌段B / A，其形成软相，并且在其聚合物链中随机含有乙烯基芳族单体和二烯的单元，其中嵌段A的玻璃化转变温度Tg高于25° 并且块B / A的相体积比低于25℃，并且选择块A与嵌段B / A的相体积比，使得整个嵌段共聚物中硬相的比例为1至40 体积比，二烯重量比小于50重量％。

    Thermoplastic molding compositions based on acrylonitrile-styrene-acrylate polymers
    5.
    发明授权
    Thermoplastic molding compositions based on acrylonitrile-styrene-acrylate polymers 失效
    基于丙烯腈 - 苯乙烯 - 丙烯酸酯聚合物的热塑性模塑组合物

    公开(公告)号：US06531543B1

    公开(公告)日：2003-03-11

    申请号：US09913121

    申请日：2001-08-09

    申请人： Norbert Güntherberg ,  Martin Weber ,  Gerhard Lindenschmidt ,  Hans Peter Rath

    发明人： Norbert Güntherberg ,  Martin Weber ,  Gerhard Lindenschmidt ,  Hans Peter Rath

    IPC分类号： C08L5100

    CPC分类号： C08L23/08 ,  C08F265/04 ,  C08L23/22 ,  C08L25/14 ,  C08L51/003 ,  C08L51/06 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

    摘要： Thermoplastic molding compositions, comprising (A) from 20 to 99% by weight of at least one graft copolymer, (B) from 1 to 80% by weight of a copolymer obtained from at least one alpha-olefin and from at least one polar comonomer, with the proviso that the monomers used are not vinyl acetate or any vinylaromatic monomer, and (C) from 0 to 80% by weight of a thermoplastic polymer, obtained by polymerizing a monomer mixture, of (c1) from 50 to 100% by weight of at least one vinylaromatic monomer and/or of a C1-C8-alkyl (meth)acrylate, and (c2) 0 to 50% by weight of at least one monofunctional comonomer, and (D) from 0.5 to 30% by weight of a (co)polymer made from (d1) from 50 to 100% by weight of isobutene and (d2) from 0 to 50% by weight of one or more other monomers, process of preparing same and their uses.

    摘要翻译： 热塑性模塑组合物，其包含（A）20至99重量％的至少一种接枝共聚物，（B）1至80重量％的由至少一种α-烯烃和至少一种极性共聚单体获得的共聚物 条件是使用的单体不是乙酸乙烯酯或任何乙烯基芳族单体，和（C）0至80重量％的热塑性聚合物，通过聚合单体混合物获得（c1）为50-100％的（c1）为50-100％ 至少一种乙烯基芳族单体和/或（甲基）丙烯酸C 1 -C 8烷基酯和（c 2）0至50重量％的至少一种单官能共聚单体的重量，和（D）0.5至30重量％ 由（d1）制备的（共）聚合物，其为50至100重量％的异丁烯和（d2）0至50重量％的一种或多种其它单体，其制备方法及其用途。

    Process for producing laminated sheets or films and moldings having UV-stability and thermal aging resistance
    7.
    发明授权
    Process for producing laminated sheets or films and moldings having UV-stability and thermal aging resistance 失效
    用于生产具有UV稳定性和耐热老化性的层压片或薄膜和模制品的方法

    公开(公告)号：US06589378B2

    公开(公告)日：2003-07-08

    申请号：US09885358

    申请日：2001-06-21

    申请人： Achim Grefenstein ,  Gerhard Lindenschmidt ,  Carsten Netze ,  Doris Zeltner

    发明人： Achim Grefenstein ,  Gerhard Lindenschmidt ,  Carsten Netze ,  Doris Zeltner

    IPC分类号： B32B3100

    CPC分类号： C08L25/12 ,  B32B27/08 ,  C08L51/003 ,  Y10T156/1044 ,  Y10T428/31909 ,  C08L2666/24 ,  C08L2666/04

    摘要： A process for producing a UV-stable laminated structure having thermal aging resistance includes coextruding the following layers in a single-stage operation, or laminating the following layers onto one another in a heatable roll nip: a substrate layer made up of a graft copolymer and a styrene and/or (meth)acrylate/(meth)acrylonitrile copolymer, and optionally containing a polycarbonate and a fibrous and/or particulate filler; and a transparent top layer of polymethyl methacrylate. In another embodiment, an interlayer of e.g., impact-modified polymethyl methacrylate or polycarbonate, is coextruded or laminated between the transparent top layer and the substrate layer to produce a UV-stable laminated structure. An adhesion layer containing an adhesion promoter can be coextruded or laminated on the outer surface of the substrate layer. A molding is produced by thermoforming the UV-stable laminated structure, which is advantageously backsprayed or back-cast with the substrate layer or a polyurethane foam. The molding can take the form of an automotive exterior bodywork component.

    摘要翻译： 一种具有耐热老化性的UV稳定层压结构体的制造方法包括在单级操作中共挤出以下层，或者在可加热辊压区中将以下层层叠在一起：由接枝共聚物和 苯乙烯和/或（甲基）丙烯酸酯/（甲基）丙烯腈共聚物，任选地含有聚碳酸酯和纤维和/或颗粒填料; 和透明的聚甲基丙烯酸甲酯顶层。在另一个实施方案中，将例如冲击改性的聚甲基丙烯酸甲酯或聚碳酸酯的中间层共挤出或层压在透明顶层和基底层之间以产生UV稳定的层压结构。 含有粘合促进剂的粘合层可以共挤出或层压在基材层的外表面上。通过热成型UV稳定层压结构制备模制品，其有利地用基材层或聚氨酯泡沫体反喷或回浇 。 模制件可以采取汽车外部车身部件的形式。

    Molding materials containing styrene/acrylonitrile copolymers and ethylene oxide/propylene oxide three-block copolymers
    8.
    发明授权
    Molding materials containing styrene/acrylonitrile copolymers and ethylene oxide/propylene oxide three-block copolymers 失效
    含有苯乙烯/丙烯腈共聚物和环氧乙烷/环氧丙烷三嵌段共聚物的成型材料

    公开(公告)号：US4291134A

    公开(公告)日：1981-09-22

    申请号：US138536

    申请日：1980-04-09

    申请人： Jurgen Hambrecht ,  Gerhard Lindenschmidt ,  Walter Regel

    发明人： Jurgen Hambrecht ,  Gerhard Lindenschmidt ,  Walter Regel

    IPC分类号： C08L25/00 ,  C08G65/08 ,  C08L25/12 ,  C08L33/00 ,  C08L33/02 ,  C08L71/00 ,  C08L71/02

    CPC分类号： C08G65/08 ,  C08L25/12 ,  C08L71/02

    摘要： Molding materials containing styrene-acrylonitrile copolymers, in which an additional essential ingredient is from 0.1 to 2.0% by weight, based on the copolymer, of a three-block polymer X-Y-X, where X is a terminal ethylene oxide block and Y is a central propylene oxide block. The proportion of terminal ethylene oxide blocks X, based on block copolymer, is from 5 to 20% by weight, while the central propylene oxide block Y has a number-average mean molecular weight of from 700 to 3,000 and its proportion is from 80 to 95% by weight, based on block copolymer. The number-average molecular weight of the sum of the two terminal blocks X is from 140 to 1,000.The novel molding materials may be used for the manufacture of moldings, since the three-block copolymer X-Y-X advantageously influences the processing characteristics of styrene-acrylonitrile copolymers, and in particular broadens the range of conditions under which they may be injection-molded, without adversely affecting the mechanical properties of the styrene-acrylonitrile copolymers. Accordingly, the injection molding scrap rate can be kept very low.

    摘要翻译： 含有苯乙烯 - 丙烯腈共聚物的成型材料，其中另外的基本成分为基于共聚物的0.1至2.0重量％的三嵌段聚合物XYX，其中X为末端环氧乙烷嵌段，Y为中心丙烯 氧化物块。 基于嵌段共聚物的末端环氧乙烷嵌段X的比例为5〜20重量％，中心环氧丙烷嵌段Y的数均分子量为700〜3000，其比例为80〜 95重量％，基于嵌段共聚物。 两个端基X之和的数均分子量为140〜1000。 新型成型材料可用于制造模制品，因为三嵌段共聚物XYX有利地影响苯乙烯 - 丙烯腈共聚物的加工特性，并且特别地扩大了它们可以注射成型的条件的范围，而不会有不利 影响苯乙烯 - 丙烯腈共聚物的机械性能。 因此，注射成型废品率可以保持非常低。

    Crosslinking agents for emulsion polymers
    9.
    发明授权
    Crosslinking agents for emulsion polymers 失效
    乳液聚合物交联剂

    公开(公告)号：US6103821A

    公开(公告)日：2000-08-15

    申请号：US230743

    申请日：1998-02-01

    申请人： Michael Fischer ,  Gerhard Lindenschmidt ,  Graham Edmund Mc Kee ,  Bernhard Rosenau ,  Herbert Naarmann

    发明人： Michael Fischer ,  Gerhard Lindenschmidt ,  Graham Edmund Mc Kee ,  Bernhard Rosenau ,  Herbert Naarmann

    IPC分类号： C08F2/16 ,  C08F2/22 ,  C08F265/04

    CPC分类号： C08F265/04

    摘要： Compounds of the general formula (I):H(--CH.sub.2 --CR.sup.1 R.sup.2).sub.m (--CH.sub.2 --CR.sup.1 R.sup.3).sub.n --H (I)whereR.sup.1 is H or methyl,R.sup.2 is --C(O)--Y--R.sup.4, where R.sup.4 is H, methyl, ethyl or allyl,R.sup.3 is --C(O)--Y--allyl andY is O or NH,orR.sup.1 is H or C.sub.1 -C.sub.20 -alkyl,R.sup.2 is H andR.sup.3 is (--CH.sub.2 --CR.sup.5 .dbd.CR.sup.6 --CH.sub.2).sub.p --H, where R.sup.5 and R.sup.6 independently are each H,methyl, ethyl or chlorine and p is 1-100,orR.sup.1 is H,R.sup.2 is OH or O-allyl andR.sup.3 is O-allyl,orR.sup.1 is H,R.sup.2 is OH or R.sup.3 andR.sup.3 is (meth)acrylate, --O--C(O)--CH.dbd.CH--COOH or --O--C(O)--CH.sub.2 --C(.dbd.CH.sub.2)--COOH,and m is an integer from 5 to 500,000 and n is an integer from 2 to 100,000, are used as crosslinking agents in particulate emulsion polymers having a glass transition temperature below 0.degree. C. and a mean particle size of from 50 to 1000 nm.

    摘要翻译： PCT No.PCT / EP97 / 04127 Sec。 371日期1999年2月1日 102（e）1999年2月1日PCT 1997年7月29日PCT公布。 出版物WO98 / 05695 日期：1998年2月12日通式（I）的化合物：其中R 1为H或甲基，R 2为-C（O）-Y-R 4的H（-CH 2 -CR 1 R 2）m（-CH 2 -CR 1 R 3）n H 其中R 4是H，甲基，乙基或烯丙基，R 3是-C（O）-Y-烯丙基，Y是O或NH，或R 1是H或C 1 -C 20烷基，R 2是H，且R 3是（-CH 2 -CR5 = CR6-CH2）pH，其中R5和R6各自独立地为H，甲基，乙基或氯，p为1-100，或R1为H，R2为OH或O-烯丙基，R3为O-烯丙基，或 R1为H，R2为OH或R3，R3为（甲基）丙烯酸酯，-OC（O）-CH = CH-COOH或-OC（O）-CH2-C（= CH2）-COOH，m为整数 5至500,000，n为2至100,000的整数，用作玻璃化转变温度低于0℃，平均粒度为50至1000nm的颗粒状乳液聚合物中的交联剂。