摘要:
Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), where the symbols and indices have the following meanings: Aryl: is an aryl group having 4 to 14 carbon atoms; R′: is a substituent which is either in the labeled phenylene position 5 or 6 and is CN, F, Cl, N(R1R2) or a straight-chain, branched or cyclic alkyl, alkoxy or thioalkoxy group having 1 to 20 carbon atoms, in which, in addition, one or more H atoms may be replaced by F; R″: are identical or different and are CN, F, Cl or a straight-chain, branched or cyclic alkyl or alkoxy group having 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A− or —CONR4—, and where one or more H atoms may be replaced by F, or an aryl group having 4 to 14 carbon atoms, which may be substituted by one or more non-aromatic radicals R′; R1, R2, R3, R4 are identical or different and are H or an aliphatic or aromatic hydrocarbon radical having 1 to 20 carbon atoms; A−: is a singly charged anion or an equivalent thereof; and n: is 0, 1, 2, 3, 4 or 5, are suitable as electroluminescent material.
摘要翻译:包含至少20%式(I)的重复单元的聚(亚芳基亚乙烯基烯烃),其中符号和指数具有以下含义:芳基:具有4至14个碳原子的芳基; R'是 在标记的亚苯基位置5或6中,是CN,F,Cl,N(R 1 R 2)或具有1至20个碳原子的直链,支链或环烷基,烷氧基或硫代烷氧基, 其中,另外一个或多个H原子可被F取代; R“:相同或不同,为CN,F,Cl或具有1至20个碳的直链,支链或环状烷基或烷氧基 原子,其中一个或多个不相邻的CH 2基团可被-O - , - S - , - CO - , - COO - , - O-CO - , - NR 1 - , - (NR 2) R 3)+ - 或-CONR 4 - ,并且其中一个或多个H原子可以被F取代,或者可以被4〜14个碳原子的芳基取代,可以被 一个或多个非芳族基团R'; R 1,R 2,R 3,R 4相同或不同,为H或脂族或芳族氢 具有1至20个碳原子的羰基; A 1是单电荷阴离子或其等同物; 和n为0,1,2,3,4或5,适合作为电致发光材料。
摘要:
An electroluminescent device, comprising at least one organic light emitting layer (103) sandwiched between two electrode layers (102, 104), wherein the ratio r of the sheet resistances of the bottom electrode layer (102) and the top electrode layer (104) is 0.3
摘要翻译:一种电致发光器件,包括夹在两个电极层(102,104)之间的至少一个有机发光层(103),其中底部电极层(102)和顶部电极层(104)的薄层电阻的比率r 是0.3 <= r <= 3。
摘要:
Poly(p-arylene-vinylenes) comprising repeating units of the formula (I), where the symbols and indices have the following meanings: Y1, Y2, Y3: identical or different, CH, N; Aryl: an aryl group having from 4 to 14 carbon atoms; R′, R″: identical or different, each a straight-chain or branched or cyclic alkyl or alkoxy group having from 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A−, or —CONR4— and one or more H atoms may be replaced by F, or else CN, F, Cl or an aryl group having from 4 to 14 carbon atoms which may be substituted by one or more nonaromatic radicals R′; R1, R2, R3, R4: identical or different, aliphatic or aromatic hydrocarbon radicals having from 1 to 20 carbon atoms or else H; A−: a singly charged anion or its equivalent; m: 0, 1 or 2; n: 1, 2, 3, 4 or 5; are suitable as electroluminescence materials.
摘要:
In a process for preparing aryl oligoamines, an amine is reacted with an activated aromatic and a base in a temperature range from 0 to 150° C. in the presence of a palladium component and a phosphine ligand. The aryl oligoamines are obtained simply and in good yields.
摘要:
A process for preparing polymerizable biaryl derivatives comprises reacting an aromatic comprising a 6-membered ring which bears ester or benzylic OH groups in the 1,4 position with a second aromatic in a palladium-catalyzed cross-coupling reaction to give a biaryl and converting the ester or benzylic OH groups into polymerizable groups in one or more steps. The biaryls obtained are suitable for preparing polymers which are used as electroluminescence materials.
摘要:
The present invention relates to a process for producing particle-free solutions of polymeric semiconductors and to their use for producing layers of polymeric semiconductors in polymeric organic light-emitting diodes (PLEDs), organic integrated circuits (O-ICs), organic field effect transistors (OFETs), organic thin film transistors (OTFTs), organic solar cells (O-SCs) or organic laser diodes (O-lasers).
摘要:
A process for preparing polymerizable biaryl derivatives comprises reacting an aromatic comprising a 6-membered ring which bears ester or benzylic OH groups in the 1,4 position with a second aromatic in a palladium-catalyzed cross-coupling reaction to give a biaryl and converting the ester or benzylic OH groups into polymerizable groups in one or more steps. The biaryls obtained are suitable for preparing polymers which are used as electroluminescence materials.
摘要:
The present invention describes novel polymers, their use as organic semiconductors and/or electroluminescent materials, and electro-luminescent devices containing polymers of this type.
摘要:
The invention relates to conjugated polymers containing triptycene units. The polymers according to the invention are on the one hand homopolymers comprising a recurring unit containing a triptycenylene radical, and copolymers comprising two or more different recurring units, which may contain a triptycenylene radical or an arylene, heteroarylene, vinylene and ethynylene radical. The polymers according to the invention are employed as electroluminescent materials.
摘要:
Triptycene derivatives, and their use for opto-electronic applications, in particular as electroluminescent materials Triptycene devices of the formula (I) where the symbols in the formula have the following meanings: K1, K2 and K3 are identical or different and are mono- or polycyclic systems, which may, if desired, contain heteroatoms, preferably N, S and/or O, and; X and Y are identical or different and are CR1, N, P, As or SiR2; R1 are identical or different and are H, halogen, pseudohalogen or a hydrocarbon radical having 1 to 30 carbon atoms, which may also, if desired, contain heteroatoms, preferably —O—, —N— and/or —S—; R2 are identical or different and are a hydrocarbon radical having 1 to 30 carbon atoms, which may also, if desired, contain heteroatoms, preferably —O—, —N— and/or —S—, are suitable for use in electroluminescent devices.
摘要翻译:特氟萘衍生物及其在光电应用中的应用,特别是作为电致发光材料式(I)的单氯化物装置,其中式中的符号具有以下含义:K1,K2和K3相同或不同,并且是单环或多环 系统,如果需要,其可以含有杂原子,优选N,S和/或O,X和Y相同或不同,为CR1,N,P,As或SiR2; R1相同或不同,为H, 卤素,假卤素或具有1至30个碳原子的烃基,如果需要,它也可以含有杂原子,优选-O-,-N-和/或-S-; R 2相同或不同,是具有 如果需要,也可以含有1至30个碳原子,优选含有杂原子,优选-O-,-N-和/或-S-,适用于电致发光器件。