公开(公告)号：US07563741B2

公开(公告)日：2009-07-21

申请号：US10515319

申请日：2003-05-23

申请人： Oliver Brummer ,  Eric D. Carlson ,  Thomas Crevier ,  Yves Giraud ,  Anne-Marie La Pointe ,  Sébastien Sterin

发明人： Oliver Brummer ,  Eric D. Carlson ,  Thomas Crevier ,  Yves Giraud ,  Anne-Marie La Pointe ,  Sébastien Sterin

IPC分类号： B01J31/00 ,  B01J23/74

CPC分类号： C08G77/08 ,  C07F15/0086 ,  C08G77/12 ,  C08G77/20 ,  C08L83/04 ,  C08L83/00

摘要： This invention relates to silicone compositions which can be crosslinked, preferably into elastomers, by hydrosilylation of at least one PolyOrganoSiloxane -A- carrying unsaturated bonds, using at least one polyorganohydrosiloxane —B— in the presence of a carbene-based metal catalyst —C— as defined in the description and which optionally comprises at least one inhibitor -D- of the hydrosilylation reaction.

摘要翻译： 本发明涉及可通过使用至少一种聚有机氢硅氧烷-B-在卡宾基金属催化剂-C-的存在下，通过至少一种携带不饱和键的至少一种聚有机硅氧烷-A的氢化硅烷化来交联，优选为弹性体的硅氧烷组合物。 如说明书中所定义，并且任选地包含氢化硅烷化反应的至少一种抑制剂-D-。

公开(公告)号：US20060173150A1

公开(公告)日：2006-08-03

申请号：US10515319

申请日：2003-05-23

申请人： Oliver Brummer ,  Eric Carlson ,  Thomas Crevier ,  Yves Giraud ,  Anne-Marie La Pointe ,  Sebastien Sterin

发明人： Oliver Brummer ,  Eric Carlson ,  Thomas Crevier ,  Yves Giraud ,  Anne-Marie La Pointe ,  Sebastien Sterin

IPC分类号： B01J31/00 ,  C08G77/06

CPC分类号： C08G77/08 ,  C07F15/0086 ,  C08G77/12 ,  C08G77/20 ,  C08L83/04 ,  C08L83/00

摘要： This invention relates to silicone compositions which can be crosslinked, preferably into elastomers, by hydrosilylation of at least one PolyOrganoSiloxane -A- carrying unsaturated bonds, using at least one polyorganohydrosiloxane —B— in the presence of a carbene-based metal catalyst —C— as defined in the description and which optionally comprises at least one inhibitor -D- of the hydrosilylation reaction.

公开(公告)号：US06511714B2

公开(公告)日：2003-01-28

申请号：US09888617

申请日：2001-06-26

申请人： Paul Branlard ,  Frédéric Garnes ,  Yves Giraud ,  Christophe Guyot ,  Frédéric Magd

发明人： Paul Branlard ,  Frédéric Garnes ,  Yves Giraud ,  Christophe Guyot ,  Frédéric Magd

IPC分类号： B05D302

CPC分类号： C09D183/04 ,  C08L2666/14 ,  C08L2666/54 ,  C08L2666/04

摘要： The invention relates to a process for combating the appearance of mist (misting) during the coating of flexible supports with at least one liquid silicone (RTV polyaddition) composition which is a precursor of silicone coating(s) using a roll coating device operating at high speed. The targeted aim is to increase the speed of appearance of the misting and subsequently to improve the appearance, the coverage and the mechanical properties of the silicone coating and industrial hygiene. For this, use is made of a liquid coating composition obtained by mixing: a silicone phase comprising one or more POSs (A) and optionally one or more (crosslinking) compound(s) (B), the viscosity &eegr; of which at 25° C. is between 100 and 800 mPa·s; with 1 to 10% by weight of noncellulose antimist particles (talc, silica, kaolin, TiO2), the D50 (in &mgr;m) of which is: 0.01≦D50≦2; and optionally with a liquid (D)—water/solvent.

摘要翻译： 本发明涉及一种使用至少一种液体硅氧烷（RTV加聚）组合物涂覆柔性载体的雾（雾）的外观的方法，该液体硅氧烷（RTV加聚）组合物是使用在高温下操作的辊涂装置的硅氧烷涂层的前体 速度。 目标是提高雾化的出现速度，从而改善硅胶涂层的外观，覆盖和机械性能以及工业卫生。 为此，使用通过混合获得的液体涂料组合物：包含一种或多种POS（A）和任选的一种或多种（交联）化合物（B）的硅氧烷相，其粘度et在25° C为100至800mPa.s;具有1至10重量％的非纤维素抗微粒（滑石粉，二氧化硅，高岭土，TiO 2），D50（母体）为：0.01 <= D50 <= 2; 和任选用液体（D） - 水/溶剂。

公开(公告)号：US06284829B1

公开(公告)日：2001-09-04

申请号：US09590803

申请日：2000-06-09

申请人： Bernard Dalbe ,  Yves Giraud

发明人： Bernard Dalbe ,  Yves Giraud

IPC分类号： C08K318

CPC分类号： C08K3/22 ,  C08K3/36 ,  C08L83/04

摘要： The polyorganosiloxane composition resulting in a silicone elastomer of high thermal conductivity, which can reach and even exceed 1.2 W/m.K, the elastomer retaining an elongation at break of greater than 30%, comprises at least one functional polyorganosiloxane which crosslinks by a polyaddition or polycondensation reaction or by the radical route, optionally a polyorganohydrosiloxane, a catalyst, optionally a reinforcing filler and a filler intended to increase the thermal conductivity which is present in the composition in the proportion of 35 to 70% by volume with respect to the total composition, this filler comprising at least two groups of particles of very different mean diameters, a first group having a mean particle diameter of between 10 and 40 mm, present in a predominant amount in the filler, and a second group having a mean particle diameter of less than 5 mm.

摘要翻译： 该聚有机硅氧烷组合物产生导热性高的有机硅弹性体，其可以达到甚至超过1.2W / mK，保持断裂伸长率大于30％的弹性体包括至少一种通过加聚或缩聚交联的官能聚有机硅氧烷 反应或通过自由基途径，任选的聚有机氢硅氧烷，催化剂，任选的增强填料和用于增加组合物中相对于总组合物的35至70体积％的比例存在的热导率的填料， 该填料包含至少两组平均直径非常不同的颗粒组，平均粒径在10至40mm之间的第一组以占主要量的填料形式存在，第二组的平均粒径较小 超过5毫米。

公开(公告)号：US08216321B2

公开(公告)日：2012-07-10

申请号：US11547401

申请日：2005-03-30

申请人： Martial Deruelle ,  Yves Giraud

发明人： Martial Deruelle ,  Yves Giraud

IPC分类号： C08L83/04 ,  D06B19/00

CPC分类号： D06M15/643 ,  D06M15/277

摘要： Crosslinkable liquid composition which can crosslink to give a hydrophobic and/or oleophobic silicone elastomer coating, comprising a polyorganosiloxane (POS) resin A exhibiting, per molecule, on the one hand, at least two different siloxyl units chosen from those of M, D, T and Q types, one of the units being a T unit or a Q unit, and, on the other hand, at least three hydrolysable/condensable groups of OH and/or OR1 types, where R1 is a linear or branched C1 to C6, preferably C1 to C3, alkyl radical, a system for promoting attachment B and a polyfluoroacrylate F. Use of this composition to form a silicone elastomer sheath around the constituent yarns, fibers and/or filaments of a textile material and to confer long-lasting oleophobicity and/or hydrophobicity properties.

摘要翻译： 可交联以产生疏水和/或疏油硅氧烷弹性体涂层的可交联液体组合物，其包含每分子表现出至少两种选自M，D， T和Q类型，其中一个单元是T单元或Q单元，另一方面是OH和/或OR1类型的至少三个可水解/可缩合的基团，其中R 1是直链或支链C 1至C 6 ，优选C1至C3烷基，用于促进附着物B的系统和聚氟丙烯酸酯F.使用该组合物在纺织材料的组成纱线，纤维和/或长丝周围形成硅氧烷弹性体护套，并赋予持久的 疏油性和/或疏水性。

公开(公告)号：US08012593B2

公开(公告)日：2011-09-06

申请号：US11979553

申请日：2007-11-05

申请人： Martial Deruelle ,  Yves Giraud

发明人： Martial Deruelle ,  Yves Giraud

IPC分类号： B32B25/20

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/46 ,  C08G77/70 ,  C08G77/80 ,  C08K5/057 ,  C09D183/04 ,  D06M15/643 ,  Y10T428/2915 ,  Y10T428/31663 ,  C08L83/00 ,  C08L2666/28 ,  C08L2666/14 ,  C08L2666/44

摘要： Crosslinkable liquid silicone compostions suited, on curing, for the long-lasting protective and/or applicational coating/treatment of textile substrates, for example, for imparting softness, hydrophobicity, oleophobicity, hydrophilicity or antistatic properties thereto, comprise a formulation of (a) at least one particular polyorganosiloxane (POS) resin, (B) at least one metal alkoxide and/or polyalkoxide, or combination thereof with at least one optionally alkoxylated organosilane and/or at least one organosilicon compound bearing at least one epoxy, amino, ureido, isocyanato and/or isocyanurate substituent, (C) at least one functional coreactant therefor, (D), optionally, at least one nonreactive additive and (E), also optionally, at least one auxiliary agent other than an additive (D).

摘要翻译： 适用于固化时用于织物基材的持续保护和/或涂敷/处理的交联液体硅氧烷组合物，例如赋予其柔软度，疏水性，疏油性，亲水性或抗静电性能，包括（a） 至少一种特定的聚有机硅氧烷（POS）树脂，（B）至少一种金属醇盐和/或聚烷氧化物，或其与至少一种任选烷氧基化的有机硅烷和/或至少一种带有至少一个环氧基，氨基，脲基的有机硅化合物 ，异氰酸酯基和/或异氰脲酸酯取代基，（C）至少一种功能性共反应物，（D），任选的至少一种非反应性添加剂和（E），还任选地至少一种除添加剂（D）以外的助剂。

公开(公告)号：US07972705B2

公开(公告)日：2011-07-05

申请号：US12068245

申请日：2008-02-04

申请人： Paul Branlard ,  Martial Deruelle ,  Yves Giraud ,  Nadia Martin

发明人： Paul Branlard ,  Martial Deruelle ,  Yves Giraud ,  Nadia Martin

IPC分类号： B32B25/20

CPC分类号： C09D183/04 ,  D06M15/643 ,  D06M15/65 ,  D06N3/128 ,  Y10T428/31663

摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.

摘要翻译： 在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性， 保持对水的不渗透性。 能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面， 通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。 本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

公开(公告)号：US20080293876A1

公开(公告)日：2008-11-27

申请号：US12068245

申请日：2008-02-04

申请人： Paul Branlard ,  Martial Deruelle ,  Yves Giraud ,  Nadia Martin

发明人： Paul Branlard ,  Martial Deruelle ,  Yves Giraud ,  Nadia Martin

IPC分类号： C08L83/04

CPC分类号： C09D183/04 ,  D06M15/643 ,  D06M15/65 ,  D06N3/128 ,  Y10T428/31663

摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.

摘要翻译： 在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性， 保持对水的不渗透性。 能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面， 通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。 本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

公开(公告)号：US5661192A

公开(公告)日：1997-08-26

申请号：US722541

申请日：1996-09-27

申请人： Yves Giraud

发明人： Yves Giraud

IPC分类号： C08G77/14 ,  C08J9/08 ,  C08K3/26

CPC分类号： C08J9/08 ,  C08G77/14 ,  C08K3/26 ,  C08J2383/04

摘要： In an organopolysiloxane composition giving rise to elastomer foam, including at least one polyacyloxyorganopolysiloxane obtained by functionalization, with a polyacyloxysilane, of at least one reactive oil which is a polyhydroxylated polysiloxane intended to react in the presence of water to form the elastomer with formation of acid of formula R'COOH, in which R' denotes a hydrocarbon radical free from aliphatic unsaturation and which has from 1 to 15 carbon atoms, a blowing agent and optionally water, the blowing agent is at least one acidic or neutral carbonate of an alkali or alkaline-earth metal, which, by reacting with the acid R'COOH, gives carbon dioxide and preferably water.Objects, especially seals, thus obtained and kit for static mixing.

摘要翻译： 在产生弹性体泡沫的有机聚硅氧烷组合物中，包括至少一种通过官能化获得的聚酰氧基有机聚硅氧烷与聚酰氧基硅烷，至少一种反应性油是多羟基化聚硅氧烷，其旨在在水存在下反应形成弹性体，形成酸 式R'COOH，其中R'表示不具有脂族不饱和键且具有1至15个碳原子的烃基，发泡剂和任选的水，所述发泡剂是至少一种酸或中性的碱的碳酸盐或 碱土金属通过与酸R'COOH反应得到二氧化碳，最好是水。 由此得到的物体，特别是密封件，并用于静态混合。

公开(公告)号：US20070298320A1

公开(公告)日：2007-12-27

申请号：US10553062

申请日：2004-03-23

申请人： Georges Barrandon ,  Catherine George ,  Carroll Vergelati ,  Yves Giraud

发明人： Georges Barrandon ,  Catherine George ,  Carroll Vergelati ,  Yves Giraud

IPC分类号： C08L83/04 ,  C08L83/06 ,  H01B1/12

CPC分类号： H01M10/0565 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/46 ,  C08L83/04 ,  H01M6/181 ,  H01M6/188 ,  H01M10/0525 ,  C08L83/00

摘要： The field of the present invention relates to the field of batteries and of polymer electrolytes for batteries and more particularly to the field of lithium batteries. The invention relates to a composition which can be polymerized and/or crosslinked by dehydrocondensation for a battery electrolyte comprising: a) at least one organohydropolysiloxane (POS) (A) having, per molecule, at least 2 hydrogen atoms directly bonded to silicon atoms; b) at least one organohydroxypolysiloxane (POS) (B) having, per molecule, at least 2 —OH groups directly bonded to silicon atoms; c) an effective amount of a dehydrocondensation catalyst (C); and d) at least one electrolyte salt (D); with the condition that the POS (A) and/or the POS (B) comprise(s), per molecule, at least one siloxyl unit comprising at least one group directly bonded to a silicon atom comprising a polyoxyalkylene (Poa) ether functional group.

摘要翻译： 本发明的领域涉及用于电池的电池和聚合物电解质的领域，更具体地涉及锂电池领域。 本发明涉及一种可通过电解质电解质脱水缩聚进行聚合和/或交联的组合物，包括：a）至少一种有机氢聚硅氧烷（POS）（A），每分子具有至少2个与硅原子键合的氢原子; b）至少一种有机羟基聚硅氧烷（POS）（B），每分子具有至少2个与硅原子键合的-OH基团; c）有效量的脱氢缩合催化剂（C）; 和d）至少一种电解质盐（D）; 条件是每个分子中POS（A）和/或POS（B）包含（s）至少一个含有至少一个直接键合到硅原子的基团的甲硅烷氧基单元，包括聚氧化烯（Poa）醚官能团 。