摘要:
Homogeneous, random interpolymers of ethylene and lesser amounts by weight of olefinically-unsaturated comonomers are prepared in a substantially constant environment, substantially steady-state reaction mixture, in a well-stirred autoclave reactor, in continuous single-phase operation, using elevated synthesis conditions wherein the temperature and pressure are elevated to an amount high enough to approach, reach, or surpass the molecular weight distribution boundary.
摘要:
A homogeneous, random interpolymer of ethylene and an alpha-olefinically unsaturated carboxylic acid or ester having a melt flow rate in the range of about 0.1 to about 300 g/10 minutes, as determined by ASTM D-1238 (190.degree. C./2160 g), is improved during its manufacture when made in a substantially constant environment in a stirred autoclave under substantially steady-state conditions of temperature, pressure, and flow rates, said temperature and pressure being sufficient to produce a single phase reaction, using a free-radical initiator, said improvement being obtained by the use of a minor amount of a telogenic modifier in the reaction mixture, the process being further characterized by the use of either, or both, of (a) a temperature which is lower than that which would be required without the presence of the telogen, or (b) a pressure which is higher than that which would be required without the presence of the modifier.
摘要:
A homogeneous, random interpolymer of ethylene and an alpha-olefinically unsaturated carboxylic acid or ester having a melt flow rate in the range of about 0.1 to about 300 g/10 minutes, as determined by ASTM D-1238 (190.degree. C./2160 g), is improved during its manufacture when made in a substantially constant environment in a stirred autoclave under substantially steady-state conditions of temperature, pressure, and flow rates, said temperature and pressure being sufficient to produce a single phase reaction, using a free-radical initiator, said improvement being obtained by the use of a minor amount of a telogenic modifier in the reaction mixture, the process being further characterized by the use of either, or both, of (a) a temperature which is lower than that which would be required without the presence of the telogen, or (b) a pressure which is higher than that which would be required without the presence of the modifier.
摘要:
A process for extruding a thermoplastic composition at higher drawdown rates with less neck-in and greater resistance to draw resonance as well as processes for extrusion coating a substrate and for making an extrusion-cast film are disclosed. The thermoplastic composition is made of at least one substantially linear ethylene polymer used alone or in combination with at least one high-pressure ethylene polymer and/or with at least one heterogeneous linear olefin polymer.
摘要:
Film layers made from formulated polymer compositions are disclosed. Film layers made from such formulated compositions have surprisingly good (for example, low) water vapor transmission rates and are particularly useful for packaging dry goods such as cereal. The polymer compositions preferably have at least one homogeneous ethylene homopolymer and at least one heterogeneously branched ethylene polymer. The homogeneous ethylene homopolymer has a molecular weight much higher than that of the heterogeneously branched ethylene polymer, although the density of each is preferably higher than about 0.95 g/cm3.
摘要翻译:公开了由配制的聚合物组合物制成的薄膜层。 由这种配制的组合物制成的薄膜层具有惊人的良好(例如,低)水蒸汽透过率,并且特别适用于包装诸如谷物的干货。 聚合物组合物优选具有至少一种均匀的乙烯均聚物和至少一种非均匀支化的乙烯聚合物。 均匀的乙烯均聚物的分子量远高于非均匀支化的乙烯聚合物的分子量,尽管它们的密度优选高于约0.95g / cm 3。
摘要:
A mixing system is disclosed comprising at least one extensional flow mixer comprising: a generally open and hollow body having a contoured outer surface and having: a single entrance port and a single exit port; a means for compressing a bulk stream flowing through the generally open and hollow body in a direction of flow and at least one injected additive stream introduced at the single entrance port in the direction of flow; and a means for broadening the bulk stream and the at least one injected additive stream such that an interfacial area between the bulk stream and the at least one injected additive stream is increased as the bulk stream and the at least one injected additive stream flow through the generally open and hollow body in the direction of flow to promote mixing of the bulk stream and the at least one injected additive stream, a flow conductor having an axis and having a generally open and hollow flow mixer body secured therein; and a primary additive stream injector positioned at the entrance port of the generally open and hollow flow mixer body, wherein the primary additive stream injector injects an additive stream into the interior of the flow mixer in the direction of flow when the bulk stream is flowing through the generally open and hollow flow mixer body to allow compression and broadening of the bulk stream and the additive stream together to facilitate mixing of the bulk stream and the primary additive stream at an exit of the extensional flow mixer, wherein the extensional flow mixer is followed by at least one of helical static mixing elements that is at least one half flow conductor diameter downstream of the exit of the extensional flow mixer.
摘要:
A process and thermoplastic composition for high line speed extrusion without high neck-in and draw resonance are disclosed. The thermoplastic composition is made of at least one ethylene polymer having a Dow Rheology Index (DRI) of at least 0.1 or, alternately, at least one substantially linear ethylene polymer, used alone or in combination with at least one high-pressure ethylene polymer and/or with at least one heterogeneous linear olefin polymer.
摘要:
The invention provides a mixing system comprising the following: A) at least one extensional flow mixer comprising: a generally open and hollow body having a contoured outer surface and having: a single entrance port and a single exit port; a design for compressing a bulk stream, and a design for broadening the bulk stream and the at least one injected additive stream; B) a flow conductor; and C) a primary additive stream injector, as described herein; and wherein the extensional flow mixer is followed by D) a first helical static mixing element that is at least one half “flow conductor diameter (D1)” downstream of the exit port of the extensional flow mixer; and wherein the mixing system comprises at least four helical static mixing elements, placed such that the leading edge of the first helical static mixing element is located perpendicular to the main axis (major axis) of the exit port of the extensional flow mixer.
摘要:
The invention provides a mixing system comprising the following: A) at least one extensional flow mixer comprising: a generally open and hollow body having a contoured outer surface and having: a single entrance port and a single exit port; a means for compressing a bulk stream flowing through the generally open and hollow body in a direction of flow, and at least one injected additive stream introduced at the single entrance port in the direction of flow; and a means for broadening the bulk stream and the at least one injected additive stream, such that an interfacial area between the bulk stream and the at least one injected additive stream is increased as the bulk stream and the at least one injected additive stream flow through the generally open and hollow body in the direction of flow to promote mixing of the bulk stream and the at least one injected additive stream; B) a flow conductor having an axis and having a generally open and hollow flow mixer body cured therein; and C) a primary additive stream injector positioned at the entrance port of the generally open and hollow flow mixer body, wherein the primary additive stream injector injects an additive stream into the interior of the flow mixer in the direction of flow, when the bulk stream is flowing through the generally open and hollow flow mixer body, to allow for compression and broadening of the bulk stream and the additive stream together within the extensional flow mixer, to facilitate mixing of the bulk stream and the primary additive stream at an exit of the extensional flow mixer; and wherein the extensional flow mixer is followed by D) at least one helical static mixing element that is at least one half “flow conductor diameter (D1)” downstream of the exit of the extensional flow mixer.
摘要:
The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.