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公开(公告)号：US09388351B2
公开(公告)日：2016-07-12
申请号：US14740483
申请日：2015-06-16
Applicant: PHILLIPS 66 COMPANY
Inventor： Yun Bao , Kristi A. Fjare , Edward L. Sughrue , TiePan Shi , Brian C. Dunn , Edgar Lotero
IPC: C07C29/141 , C10L1/18 , C07C29/10 , C07C29/17 , C10L1/182 , C07C29/145
CPC classification number: C10L1/18 , C07C29/103 , C07C29/141 , C07C29/145 , C07C29/175 , C10L1/02 , C10L1/1824 , C10L2200/0469 , C10L2270/023 , C10L2290/00
Abstract: Furfural is produced through hydrolysis of the hemi-cellulose in corn stover. Furfural may also be produced from other biomass. The direct conversion of furfural to mono-alcohols which can be blended with gasoline is an attractive chemical process for providing biomass into the liquid fuel supply. Examples of such alcohols include 1-butanol, 1-pentanol, 2-pentanol and tetrahydrofurfuryl alcohol. Preferred alcohols include C-4 and C-5 mono-alcohols that have suitable blending properties.
Abstract translation: 糠醛通过在玉米秸秆中水解半纤维素而产生。 糠醛也可以由其他生物质生产。 将糠醛直接转化成可与汽油混合的单醇是将有益生物质提供给液体燃料供应的有吸引力的化学方法。 这些醇的实例包括1-丁醇，1-戊醇，2-戊醇和四氢糠醇。 优选的醇包括具有合适掺合性质的C-4和C-5单醇。
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公开(公告)号：US20130327627A1
公开(公告)日：2013-12-12
申请号：US13914338
申请日：2013-06-10
Applicant: Phillips 66 Company
Inventor： Daren E. Daugaard , Samuel T. Jones , Alexandru Platon , Kening Gong , Edgar Lotero
IPC: C10G3/00
CPC classification number: C10G3/42 , C10B7/10 , C10B49/16 , C10B49/20 , C10B53/02 , C10B57/06 , C10G1/08 , Y02E50/14 , Y02P20/145 , Y02P30/20
Abstract: The present invention relates generally to the thermal conversion of biomass. Processes are disclosed for converting biomass to condensable vapor intermediates such as pyrolysis oil by means of catalytic pyrolysis in a reactor comprising at least one auger, where the catalyst also comprises a heat carrier. The intermediates produced may be further processed for production of renewable hydrocarbon fuels.
Abstract translation: 本发明一般涉及生物质的热转化。 公开了用于在包括至少一个螺旋钻的反应器中通过催化裂解将生物质转化为可冷凝蒸气中间体（例如热解油）的方法，其中催化剂还包含热载体。 生产的中间体可进一步加工以生产可再生碳氢燃料。
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公开(公告)号：US20140073823A1
公开(公告)日：2014-03-13
申请号：US14021021
申请日：2013-09-09
Applicant: Phillips 66 Company
Inventor： Mark A. Hughes , Johnathan T. Gorke , Samuel T. Jones , Tie-Pan Shi , Natalie A. Rebacz , Edgar Lotero
IPC: C10G1/00
CPC classification number: C10J3/52 , C10B49/16 , C10B53/02 , C10G1/002 , C10G1/02 , C10G2/32 , C10G3/42 , C10G3/55 , C10G2300/1011 , C10K1/30 , C10K3/02 , Y02E50/13 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the pyrolysis vapors.
Abstract translation: 本公开一般涉及新的生物质热解方法和系统，其减少焦化和其它污染物与热解蒸气的夹带。
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公开(公告)号：US20150073181A1
公开(公告)日：2015-03-12
申请号：US14465902
申请日：2014-08-22
Applicant: PHILLIPS 66 COMPANY
Inventor： Johnathan T. Gorke , Edgar Lotero
CPC classification number: C10G1/002 , C10B49/16 , C10B53/02 , C10G3/42 , C10G3/50 , C10G65/12 , Y02E50/14 , Y02P20/145 , Y02P30/20
Abstract: This disclosure relates to the fast pyrolysis of organic matter. More specifically, it relates to the catalytic modification of vapors created during the fast pyrolysis of organic matter to create transportation fuel or a transportation fuel component. At least a first portion of pyrolysis vapors is catalytically stabilized or converted, then combined with a portion of raw, unconverted bio-derived pyrolysis vapors at a temperature and pressure sufficient for molecules of the combined vapors to react and produce hydrocarbons of increased molecular weight that are suitable for use as a hydrocarbon transportation fuel or component thereof.
Abstract translation: 本公开涉及有机物的快速热解。 更具体地说，它涉及在快速热解有机物质期间产生的蒸气的催化改性以产生运输燃料或运输燃料组分。 至少热解蒸气的第一部分被催化稳定或转化，然后在一部分未转化的生物衍生的热解蒸气中，在合并蒸气的分子的温度和压力下反应并产生分子量增加的烃， 适用于烃运输燃料或其组分。
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公开(公告)号：US20150071836A1
公开(公告)日：2015-03-12
申请号：US14466353
申请日：2014-08-22
Applicant: PHILLIPS 66 COMPANY
Inventor： Johnathan T. Gorke , Edgar Lotero
CPC classification number: C10J3/82 , C10B49/16 , C10B53/02 , C10G1/002 , C10G3/50 , C10G45/02 , C10G47/00 , C10K3/02 , Y02E50/14 , Y02E50/32 , Y02P20/145 , Y02P30/20
Abstract: This disclosure relates to systems for the fast pyrolysis of organic matter. More specifically, it relates to systems for the catalytic modification of vapors created during the fast pyrolysis of organic matter to create transportation fuel or a transportation fuel component. The inventive systems either catalytically stabilize or convert at least a first portion of pyrolysis vapors, then combine them with a portion of raw, unconverted bio-derived pyrolysis vapors at a temperature and pressure sufficient for molecules of the combined vapors to react and produce hydrocarbons of increased molecular weight that are suitable for use as a hydrocarbon transportation fuel or component thereof.
Abstract translation: 本公开涉及用于快速热解有机物质的系统。 更具体地说，本发明涉及在快速热解有机物质期间产生的蒸气的催化改性体系，以产生运输燃料或运输燃料组分。 本发明的系统催化稳定或转化至少第一部分的热分解蒸气，然后将它们与一部分未转化的生物衍生的热解蒸气在足以使组合蒸气的分子充分反应并产生烃的 适用于烃运输燃料或其组分的分子量增加。
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Patent Agency Ranking
公开(公告)号：US20130327626A1
公开(公告)日：2013-12-12
申请号：US13914146
申请日：2013-06-10
Applicant: Phillips 66 Company
Inventor： Daren E. Daugaard , Samuel T. Jones , Alexandru Platon , Kening Gong , Edgar Lotero
IPC: C10G1/02
Abstract: The present invention relates generally to the thermal conversion of biomass. Processes are disclosed for converting algal biomass to condensable vapor intermediates such as pyrolysis oil by means of pyrolysis in a reactor comprising at least one auger. The intermediates may be further processed for production of renewable hydrocarbon fuels. The disclosed processes assist in preventing premature devolatization of algal biomass during pyrolysis, thereby increasing efficiency and commercial feasibility.
Abstract translation: 本发明一般涉及生物质的热转化。 公开了用于在包括至少一个螺旋钻的反应器中通过热解将藻类生物质转化成可冷凝蒸汽中间体（例如热解油）的方法。 可以进一步处理中间体以生产可再生烃燃料。 所公开的方法有助于防止藻类生物质在热解期间的过早脱挥发，从而提高效率和商业可行性。
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公开(公告)号：US10160912B2
公开(公告)日：2018-12-25
申请号：US14465902
申请日：2014-08-22
Applicant: PHILLIPS 66 COMPANY
Inventor： Johnathan T. Gorke , Edgar Lotero
Abstract: This disclosure relates to the fast pyrolysis of organic matter. More specifically, it relates to the catalytic modification of vapors created during the fast pyrolysis of organic matter to create transportation fuel or a transportation fuel component. At least a first portion of pyrolysis vapors is catalytically stabilized or converted, then combined with a portion of raw, unconverted bio-derived pyrolysis vapors at a temperature and pressure sufficient for molecules of the combined vapors to react and produce hydrocarbons of increased molecular weight that are suitable for use as a hydrocarbon transportation fuel or component thereof.
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公开(公告)号：US09181506B2
公开(公告)日：2015-11-10
申请号：US14282302
申请日：2014-05-20
Applicant: PHILLIPS 66 COMPANY
Inventor： Edgar Lotero , Kristi A. Fjare , Cory B. Phillips , Alexandru Platon
Abstract: Carbohydrates as derived from plant biomass can be converted into mono-alcohols, diols, and/or bi-functional alcohols or into carboxylic acid derivatives. By catalytic transesterification of such carbohydrate derivatives, ester-type diesel-fuel blendstock components may be produced. More specifically, alkyl levulinates are catalytically trans-esterified with hydroxyl-functionalized compounds where both the alcohols and the alkyl levulinates are derived from biomass carbohydrates. Esters produced in this way show physicochemical characteristics that make them suitable for use as diesel fuel blendstock.
Abstract translation: 衍生自植物生物质的碳水化合物可以转化为单醇，二醇和/或双官能醇或羧酸衍生物。 通过这种碳水化合物衍生物的催化酯交换反应，可以生产酯型柴油 - 燃料共混物组分。 更具体地，烷基乙酰丙酸酯用羟基官能化化合物进行催化反式酯化，其中醇和烷基乙酰维生素都来源于生物质碳水化合物。 以这种方式生产的酯显示出使其适合用作柴油混合料的物理化学特性。
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公开(公告)号：US20140350292A1
公开(公告)日：2014-11-27
申请号：US14282302
申请日：2014-05-20
Applicant: PHILLIPS 66 COMPANY
Inventor： Edgar Lotero , Kristi A. Fjare , Cory B. Phillips , Alexandru Platon
IPC: C10L1/02
Abstract: Carbohydrates as derived from plant biomass can be converted into mono-alcohols, diols, and/or bi-functional alcohols or into carboxylic acid derivatives. By catalytic transesterification of such carbohydrate derivatives, ester-type diesel-fuel blendstock components may be produced. More specifically, alkyl levulinates are catalytically trans-esterified with hydroxyl-functionalized compounds where both the alcohols and the alkyl levulinates are derived from biomass carbohydrates. Esters produced in this way show physicochemical characteristics that make them suitable for use as diesel fuel blendstock.
Abstract translation: 衍生自植物生物质的碳水化合物可以转化为单醇，二醇和/或双官能醇或羧酸衍生物。 通过这种碳水化合物衍生物的催化酯交换反应，可以生产酯型柴油 - 燃料共混物组分。 更具体地，烷基乙酰丙酸酯用羟基官能化化合物进行催化反式酯化，其中醇和烷基乙酰维生素都来源于生物质碳水化合物。 以这种方式生产的酯显示出使其适合用作柴油混合料的物理化学特性。
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公开(公告)号：US20140110271A1
公开(公告)日：2014-04-24
申请号：US14047084
申请日：2013-10-07
Applicant: PHILLIPS 66 COMPANY
Inventor： Mahaprasad Kar , Sourabh Pansare , John T. Gorke , Edgar Lotero , Neal D. McDaniel , Danielle K. Smith , Dennis G. Schultz , Kristi A. Fjare , Bruce B. Randolph , Sikta Patnaik , Uchenna P. Paul , Madhu Anand
CPC classification number: C25B11/0415 , C25B1/02 , C25B11/0473
Abstract: The process describes performing electrolysis on an alkaline oxygenate mixture to produce hydrogen. In this process the electrolysis does not form any significant amounts of oxygen.
Abstract translation: 该方法描述了在碱性含氧化合物混合物上进行电解以产生氢。 在这个过程中，电解不会形成任何显着量的氧气。
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