摘要:
The invention concerns a crosslinkable composition of functionalized polyolefin powder comprising a functionalized polyolefin (A) having an MFI of at least 20 (190° C. 2.16 kg), a product (B) having a function for crosslinking (A), the composition having a grain size distribution between 100 and 400 &mgr;m. Said composition is useful for slush moulding, for thermoforming sheets or injection on an insert.
摘要:
A thermosetting composition consists essentially of a mixture of (A) a polymer containing acid anhydride groups, (B) a molecular sieve being partially loaded with at least one amine, and (C) a filler capable of releasing water upon heating at a temperature above the processing temperature of the mixture of (A), (B) and (C). The processing temperature is chosen so as to be below the desorption temperature of the amine from the molecular sieve. The composition is particularly useful in making hot melt adhesives and sheetings of electric cables.
摘要:
The invention concerns a mixture comprising by weight, the total being 100%, 1 to 100% if a polyamide block copolymer consisting of a basic polyolefin chain and on an average at least a polyamide graft wherein: the grafts are fixed to the basic chain by the radicals of an unsaturated monomer (X) having a function capable of reacting with a polyamide with amine terminal, the radicals of the unsaturated monomer (X) are fixed to the basic chain by grafting or copolymerization from its double bond; 99 to 0% of a flexible polyolefin with elastic modulus in flexure less than 50 MPa at 23° C. and having a crystalline melting point ranging between 60° C. and 100° C. Said mixtures are useful for making films, tanks, geomembrane protective fabrics produced by extrusion, products obtained by calendering, thermocladding/forming, protective films for electric cables and skins using slush molding technique.
摘要:
The present invention relates to a coextrusion binder comprising: 5 to 35 parts of a polymer (A) which itself consists of a blend of 80 to 20 parts of a metallocene polyethylene (A1) of relative density between 0.865 and 0.915 and of 20 to 80 parts of a non-metallocene LLDPE polyethylene (A2), the blend of (A1) and (A2) being cografted by an unsaturated carboxylic acid; 95 to 65 parts of a polyethylene (B) chosen from ethylene homopolymers or copolymers and elastomers; the blend of (A) and (B) being such that: the content of grafted unsaturated carboxylic acid is between 30 and 100 000 ppm, the MFI or melt flow index (ASTM D 1238 standard: 190° C./2.16 kg) is between 0.1 and 10 g/10 min. The present invention also relates to a multilayer structure.
摘要翻译:共挤出粘合剂本发明涉及一种共挤出粘合剂,其包含:5-35份聚合物(A),其本身由80至20份相对密度为0.865至0.915和20至80的茂金属聚乙烯(A1)的共混物 部分非金属茂LLDPE聚乙烯(A2),(A1)和(A2)的共混物由不饱和羧酸共同接枝; 95-65份选自乙烯均聚物或共聚物和弹性体的聚乙烯(B); (A)和(B)的共混物使得:接枝不饱和羧酸的含量为30-10000ppm,MFI或熔体流动指数(ASTM D 1238标准:190℃/ 2.16kg)为 介于0.1和10g / 10分钟之间。本发明还涉及一种多层结构。
摘要:
The present invention relates to a process for the preparation of graft thermoplastic polymers in which at least one thermoplastic polymer (A) is grafted with a functional monomer in the presence of a substance which inhibits or reduces the crosslinking or the depolymerization of (A).This substance may be a stable nitroxide radical.Graft polymers are useful as compatibilizing agents in mixtures of polymers and as coextrusion binders. The invention also relates to multilayer structures including these binders.
摘要:
The subject of the invention is a metallized film produced using a multilayer structure comprising a tie layer comprising: 5 to 50% by weight of a blend (A) comprising: 5 to 100% of a cografted blend of polymers (C1) and (C2), consisting of 90 to 20% by weight of a metallocene polyethylene (C1) of density between 0.865 and 0.915 and of 10 to 80% by weight of a polymer (C2) which is either a non-metallocene LLDPE or a polypropylene homopolymer or copolymer, and 95 to 0% by weight of a polyethylene (D) chosen from polyethylene homopolymers or copolymers and elastomers; the blend (A) being such that: the content of grafting monomer grafted is between 30 and 105 ppm; the MFI or meltflow index (ASTM D 1238, at 190° C./2.16 kg) is between 0.1 and 30 g/10 min; 50 to 95% by weight of a polypropylene homopolymer or copolymer (B).
摘要:
The invention relates to a mixture which is useful as a coextrusion binder, comprising: at least (A) one polyethylene or one ethylene copolymer, at least (B) chosen from (B1) polypropylene or a propylene copolymer, (B2) poly(1-butene) homo- or copolymer, and (B3) polystyrene homo- or copolymer, the mixture of (A) and (B) being grafted with a functional monomer, this grafted mixture itself optionally being diluted in at least one polyolefin (C) or in at least one polymer (D) of elastomeric nature or in a mixture of (C) and (D). The invention also relates to polyolefin/binder/polyamide, EVOH, polyester or metal structures. The invention is useful for making packaging.
摘要:
A subject matter of the invention is a coextrusion tie, which comprises: 5 to 35% by weight of a polymer (A) itself composed of a blend of 80 to 20% by weight of a metallocene polyethylene (A1) with a density of between 0.863 and 0.915 and of 20 to 80% by weight of a non-metallocene LLDPE polyethylene (A2) with a density of between 0.900 and 0.950, the blend of polymers (A1) and (A2) being cografted; 95 to 65% by weight of metallocene polyethylene (B) homo- or copolymer, the comonomer of which comprises 3 to 20 carbon atoms, preferably 4 to 8 carbon atoms, the density of which is between 0.863 and 0.915 and the MFI of which is between 0.5 and 30, preferably between 3 and 15, g/10 min; the total forming 100%, the blend of (A) and (B) being such that its MFI is between 0.1 and 15, preferably between 1 and 13, g/10 min.
摘要:
The present invention relates to a process for manufacturing a transparent article with gas-barrier properties by coextrusion blow-molding, the said article comprising at least a structure of the type: layer of EVOH/tie layer/layer of glycolised copolyester and relates to a multilayer structure comprising a coextrusion tie layer adhering to a layer of glycolised polyester copolymer. The said tie comprises a blend of metallocene polyethylene, non-metallocene LLDPE, both of which are co-grafted, and non-grafted polyethylene. The invention also relates to articles comprising such a structure, in particular hollow bodies.
摘要:
A coextrusion binder and a multilayer structure containing the binding wherein the binder contains a composition comprising (I) syndiotactic polypropylene and (II) at least one polymer being: (A), a polyethylene or a copolymer of ethylene, (B), any of (B1) isotactic polypropylene homopolymer of copolymer, (B2) poly(1-butene) homo- or copolymer or (B3) polystyrene homo- or copolymer, and a blend of (A) and (B), said composition being grafted with a functional monomer such that each of I and II is at least partially grafted with said functional monomer.