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    Analysis method
    1.
    发明授权
    Analysis method 失效
    分析方法

    公开(公告)号：US07456021B2

    公开(公告)日：2008-11-25

    申请号：US10758900

    申请日：2004-01-16

    申请人： Patrick Brant ,  Burkhard Endeward ,  Hans Thomann ,  Yuan-Ju Chen ,  Terry John Burkhardt

    发明人： Patrick Brant ,  Burkhard Endeward ,  Hans Thomann ,  Yuan-Ju Chen ,  Terry John Burkhardt

    IPC分类号： G01N31/10

    CPC分类号： G01N21/6408 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  G01N21/274 ,  G01N2201/127 ,  Y10S502/522 ,  C08F4/65927

    摘要： Disclosed herein is a method for determining the presence of an activated catalyst site in a catalyst system comprising a catalyst precursor and an activator, wherein the catalyst system is capable of providing a luminescence, the method comprising: performing a time resolved luminescence analysis on a reference analyte comprising the catalyst precursor that is not in combination with the activator, and performing a time resolved luminescence analysis on a sample analyte comprising the catalyst precursor in combination with the activator, determining a reference emission energy and a reference lifetime each associated with a maximum emission intensity in the reference output values; determining a sample emission energy and a sample lifetime each associated with a maximum emission intensity in the sample output values; and comparing the values to determine if the sample comprises an activated catalyst site. Use of the above method in relation to an activation index is also disclosed.

    摘要翻译： 本文公开了一种用于确定催化剂体系中活化催化剂位点的存在的方法，其包括催化剂前体和活化剂，其中所述催化剂体系能够提供发光，所述方法包括：对参考物进行时间分辨发光分析 分析物，其包含不与活化剂组合的催化剂前体，并且对包含催化剂前体的样品分析物与活化剂组合进行时间分辨发光分析，确定参考发射能量和参考寿命，每个与最大发射相关联 参考输出值的强度; 确定每个与样本输出值中的最大发射强度相关联的样本发射能量和采样寿命; 并比较这些值以确定样品是否包含活化的催化剂位点。 还公开了关于活化指数的上述方法的使用。

    Analysis method
    2.
    发明申请
    Analysis method 失效
    分析方法

    公开(公告)号：US20050158864A1

    公开(公告)日：2005-07-21

    申请号：US10758900

    申请日：2004-01-16

    申请人： Patrick Brant ,  Burkhard Endeward ,  Hans Thomann ,  Yuan-Ju Chen ,  Terry Burkhardt

    发明人： Patrick Brant ,  Burkhard Endeward ,  Hans Thomann ,  Yuan-Ju Chen ,  Terry Burkhardt

    IPC分类号： C08F4/659 ,  C08F10/00 ,  G01N21/27 ,  G01N21/64 ,  G01N31/10

    CPC分类号： G01N21/6408 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  G01N21/274 ,  G01N2201/127 ,  Y10S502/522 ,  C08F4/65927

    摘要： Disclosed herein is a method for determining the presence of an activated catalyst site in a catalyst system comprising a catalyst precursor and an activator, wherein the catalyst system is capable of providing a luminescence, the method comprising: performing a time resolved luminescence analysis on a reference analyte comprising the catalyst precursor that is not in combination with the activator, and performing a time resolved luminescence analysis on a sample analyte comprising the catalyst precursor in combination with the activator, determining a reference emission energy and a reference lifetime each associated with a maximum emission intensity in the reference output values; determining a sample emission energy and a sample lifetime each associated with a maximum emission intensity in the sample output values; and comparing the values to determine if the sample comprises an activated catalyst site. Use of the above method in relation to an activation index is also disclosed.

    摘要翻译： 本文公开了一种用于确定催化剂体系中活化催化剂位点的存在的方法，其包括催化剂前体和活化剂，其中所述催化剂体系能够提供发光，所述方法包括：对参考物进行时间分辨发光分析 分析物，其包含不与活化剂组合的催化剂前体，并且对包含催化剂前体的样品分析物与活化剂组合进行时间分辨发光分析，确定参考发射能量和参考寿命，每个与最大发射相关联 参考输出值的强度; 确定每个与样本输出值中的最大发射强度相关联的样本发射能量和采样寿命; 并比较这些值以确定样品是否包含活化的催化剂位点。 还公开了关于活化指数的上述方法的使用。

    Fullerene-polymer compositions
    4.
    发明授权
    Fullerene-polymer compositions 失效
    富勒烯聚合物组合物

    公开(公告)号：US5281653A

    公开(公告)日：1994-01-25

    申请号：US797525

    申请日：1991-11-25

    申请人： Hans Thomann ,  Patrick Brant ,  John P. Dismukes ,  David J. Lohse ,  Jyi-Faa Hwang ,  Edward N. Kresge

    发明人： Hans Thomann ,  Patrick Brant ,  John P. Dismukes ,  David J. Lohse ,  Jyi-Faa Hwang ,  Edward N. Kresge

    IPC分类号： C08K3/02 ,  C08K3/04 ,  C08L101/00 ,  C08K5/01

    CPC分类号： C08K3/04 ,  Y10S977/753

    摘要： The present invention relates to novel compositions of matter comprising fullerenes and polymers, wherein the fullerenes are combined with the polymer in an amount sufficient to result in a change or modification in the viscoelastic properties of the resulting composition from that of the unmodified polymer typically within the range of from about 0.01 wt. % to about 85 wt. %. Also included in the present invention is the process for making the novel fullerene-polymer compositions and the products produced by the process disclosed therein. The novel compositions show changes in the viscoelastic properties in comparison to the unmodified polymer, and hence, have utility in any application in which the unmodified polymer may be used, but wherein the application would benefit from the resulting change in the viscoelastic properties.

    摘要翻译： 本发明涉及包含富勒烯和聚合物的新型物质组合物，其中富勒烯与聚合物结合的量足以导致所得组合物的粘弹性性质与未改性聚合物的粘弹性性质的改变或改性， 范围为约0.01重量％ ％至约85重量％ ％。 本发明还包括制备新型富勒烯聚合物组合物和通过其中公开的方法制备的产品的方法。 与未改性的聚合物相比，该新型组合物显示出粘弹性性能的变化，因此在可以使用未改性聚合物的任何应用中具有实用性，但是其应用将受益于所得到的粘弹性质的变化。

    Diblock copolymers prepared by cross metathesis
    8.
    发明授权
    Diblock copolymers prepared by cross metathesis 有权
    通过交叉复分解制备的二嵌段共聚物

    公开(公告)号：US08940839B2

    公开(公告)日：2015-01-27

    申请号：US13072383

    申请日：2011-03-25

    申请人： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    发明人： John R. Hagadorn ,  Charles J. Ruff ,  Renuka N. Ganesh ,  Patrick Brant

    IPC分类号： C08G61/04 ,  C08L65/00

    CPC分类号： C08G61/04 ,  C08G2261/419 ,  C08L65/00

    摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

    摘要翻译： 本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体， 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度 在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

    Catalysts and methods of use thereof to produce vinyl terminated polymers
    10.
    发明授权
    Catalysts and methods of use thereof to produce vinyl terminated polymers 有权
    催化剂及其制备乙烯基封端聚合物的方法

    公开(公告)号：US08455597B2

    公开(公告)日：2013-06-04

    申请号：US13072280

    申请日：2011-03-25

    申请人： Donna J. Crowther ,  Patrick Brant ,  Carlos U. De Gracia ,  Jacqueline A. Lovell

    发明人： Donna J. Crowther ,  Patrick Brant ,  Carlos U. De Gracia ,  Jacqueline A. Lovell

    IPC分类号： C08F4/6592 ,  C08F4/643 ,  C08F110/06 ,  B01J31/22

    CPC分类号： C08F4/65912 ,  B01J31/12 ,  B01J31/14 ,  B01J31/2295 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/16 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/76 ,  C08F110/06 ,  C08F210/06 ,  Y10S526/943 ,  C08F210/16 ,  C08F2500/03 ,  C08F10/06 ,  C08F4/65927

    摘要： This invention relates to a homogenous process for making a vinyl terminated propylene polymer, wherein the process comprises: contacting, propylene, under polymerization conditions, with a catalyst system comprising an activator and at least one metallocene compound, where the metallocene compound is represented by the formula: where: M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, (two X's may form a part of a fused ring or a ring system); each R1 is, independently, a C1 to C10 alkyl group; each R2 is, independently, a C1 to C10 alkyl group; each R3 is, independently, hydrogen; each R4, R5, and R6, is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, a heteroatom or heteroatom containing group; T is a bridging group; each R7 is, independently, hydrogen, halogen, or a C1 to C20 hydrocarbyl, and two R7 can form a cyclic structure including aromatic, partially saturated, or saturated cyclic or fused ring system; and further provided that any of adjacent R4, R5, and R6 groups may form a fused ring or multicenter fused ring system where the rings may be aromatic, partially saturated or saturated.

    摘要翻译： 本发明涉及一种用于制备乙烯基封端的丙烯聚合物的均匀方法，其中该方法包括：在聚合条件下使丙烯与包含活化剂和至少一种金属茂化合物的催化剂体系接触，其中茂金属化合物由 式：其中：M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤化物，二烯，胺，膦，醚及其组合（两个X的 可形成稠环或环系的一部分）; 每个R 1独立地为C 1至C 10烷基; 每个R 2独立地为C 1至C 10烷基; 每个R 3独立地是氢; 每个R 4，R 5和R 6独立地是氢或取代或未取代的烃基，含杂原子或杂原子的基团; T是一个桥接组; 每个R 7独立地是氢，卤素或C 1至C 20烃基，并且两个R 7可以形成包括芳族，部分饱和或饱和的环状或稠环体系的环状结构; 并且进一步规定相邻的R 4，R 5和R 6基团中的任何一个可以形成稠合环或多中心稠环体系，其中所述环可以是芳族的，部分饱和的或饱和的。