摘要:
Non-isocyanate single stage coating compositions are disclosed. The composition is especially useful in air-dry systems and comprises a co-reactant having active hydrogen functionality, at least one anhydride functional co-reactant and a novel carbodiimide compound.
摘要:
Reactive diluents are formed by reaction of a compound having at least two glycidyl ester groups and a compound having at least one hydroxyl and/or carboxyl group. The diluents are useful in coating compositions together with crosslinking agents and optional other vehicle components.
摘要:
Novel reactive carbodiimide compounds and their method of preparation are disclosed. These reactive carbodiimide compounds are especially useful in automotive paint compositions and more particularly in low volatile organic content (VOC) automotive paint compositions.
摘要:
Improved basecoat--clearcoat paint coating compositions which may be ambient cured are disclosed. The coating compositions comprise:1) a hydroxyl functional coreactant,2) at least one anhydride functional coreactant and,3) a carbodiimide compound.The improved compositions cure at a rate especially useful as refinish paint compositions.
摘要:
Disclosed are amine functional cellulose ester resins and methods of making the same. The amine functional cellulose ester resins comprise at least one repeat unit of the structure: wherein R1, R2, and R3 are selected independently from the group consisting of hydrogen, R4C═O, and wherein at least one of R1, R2, and R3 is hydrogen, at least one of R1, R2, and R3 is R4C═O, and at least one of R1, R2, or R3 have the structure R4 is selected from the group consisting of C1-C20 alkyl groups, C1-C20 phenyl groups, C1-C20 napthyl groups, and C1-C20 alkenyl groups, L is a divalent linking group and R6 is selected from the group consisting of H and compounds having at least one secondary amine group, tertiary amine group, and mixtures thereof.
摘要:
The present invention provides a coating composition comprising no more than 2.00% by weight nonvolatile of Si-containing compounds, based on the total nonvolatile weight of the coating composition, and from 0.25 to no more than 5.0% by weight of a volatile linear siloxane of the formula: (R)3—Si—O—((R)2—Si—O)y—Si—(R)3 wherein R is H or an alkyl group of from 1 to 3 carbon atoms and y is a number from 0 to 6, based on the total nonvolatile weight of the coating composition. The invention also provides a method of providing a cured coating composition having an improved distinctness of image as well as a method of coating a substrate. The compositions of the invention have improved resistance to visual defects believed to be caused by surface contamination, such as “fisheyes” or “cratering” and “telegraphing”.
摘要:
A coating system comprises a substrate and a cured film disposed on the substrate and formed from a coating composition. The coating composition comprises a solvent component and a resin. The resin comprises a reaction product of a polyolefin and an oligomer or polymer. The polyolefin, different from the oligomer or polymer, has a functional group that is reactive with the oligomer or polymer and the functional group is selected from acrylate, methacrylate, carboxyl, hydroxyl, epoxide, anhydride and isocyanate functional groups. The oligomer or polymer and the polyolefin are at least partially immiscible in solution at ambient temperature. The oligomer or polymer is grafted with the polyolefin to form the resin.
摘要:
Disclosed are a method of dispersing a pigment, a pigment dispersion, a coating composition comprising said pigment dispersion, an method of making a coating composition, and a method of improving the appearance of a coating composition. The pigment dispersion of the invention requires at least one pigment subjected to an action to decrease the average particle size of the pigment in the presence of an amine functional cellulose ester resin. The amine functional cellulose ester resins comprise at least one repeat unit of the structure: wherein R1, R2, and R3 are selected independently from the group consisting of hydrogen, R4C═O, and wherein at least one of R1, R2, and R3 is hydrogen, at least one of R1, R2, and R3 is R4C═O, and at least one of R1, R2, or R3 have the structure R4 is selected from the group consisting of C1-C20 alkyl groups, C1-C20 phenyl groups, C1-C20 napthyl groups, and C1-C20 alkenyl groups, L is a divalent linking group and R6 is selected from the group consisting of H and compounds having at least one secondary amine group, tertiary amine group, and mixtures thereof.
摘要:
Scratch resistance and/or reflow of a refinish topcoat is improved by preparing the topcoat from a refinish topcoat coating composition comprising an unsaturated fatty acid ester polyol that does not undergo oxidative cure when the applied refinish topcoat coating composition is cured.
摘要:
The invention is directed to a block copolymer with the following representative structure:R.sub.1 --X--[[R.sub.2 --N.dbd.C.dbd.N--R.sub.2 --].sub.n [--X--R.sub.3 --X].sub.p --[R.sub.2 --N.dbd.C.dbd.N--R.sub.2 ].sub.r ].sub.m X--R.sub.1Where:m=1 to 20n=1 to 20p=0 or 1R.sub.1 =A monomeric or polymeric species containing only one functional group reactive with an isocyanate group. This species may also have another reactive functional group that is not reactive with a carbodiimide functionality such as an alkoxy silane.R.sub.2 =The radical from any available aliphatic, cycloaliphatic or shielded aromatic diiocyanate.R.sub.3 =Preformed polymer blocks such as a polyester, polyacrylate, polyurethane, polyether, polyethylene, polycarbonate, polyurea polysiloxane or similar hybrids.X=any combination of: ##STR1## The copolymer may be used in various automotive paint compositions. The resin may be prepared by first synthesizing the desired blocks, the polycarbodiimide blocks and the modifying blocks, then link them together. The resin may also be prepared by forming the polycarbodiimide directly onto the modifying blocks. The latter approach is the preferred one. The modifying blocks are prepared in the conventional manner for the chemistry and the choice of the modifying blocks depend on the application. For proper topcoat wetting, it is desired that some portion of the modifying blocks be highly polar.
摘要翻译:本发明涉及具有以下代表性结构的嵌段共聚物:R1-X - [[R2-N = C = N-R2-] n [-X-R3-X] p- [R2-N = C = N -R2] r] mX-R1其中:m = 1至20n = 1至20p = 0或1 R1 =仅含有一个与异氰酸酯基团反应的官能团的单体或聚合物质。 该物质还可以具有不与碳二亚胺官能团反应的另一反应性官能团,例如烷氧基硅烷。 R2 =来自任何可用的脂族,脂环族或屏蔽芳族二异氰酸酯的基团。 R3 =预成型聚合物嵌段如聚酯,聚丙烯酸酯,聚氨酯,聚醚,聚乙烯,聚碳酸酯,聚脲聚硅氧烷或类似的混合物。 X =任何组合:共聚物可用于各种汽车涂料组合物中。 树脂可以通过首先合成所需的嵌段,聚碳二亚胺嵌段和改性嵌段,然后将它们连接在一起来制备。 也可以通过将聚碳化二亚胺直接形成到改性嵌段上来制备树脂。 后一种方法是首选方法。 修改块以常规的化学方式制备,并且修改块的选择取决于应用。 为了适当的顶涂润湿,希望部分改性嵌段是极性极性的。