公开(公告)号：US07553517B1

公开(公告)日：2009-06-30

申请号：US11226283

申请日：2005-09-15

申请人： Paul D. Jablonski ,  David E. Alman

发明人： Paul D. Jablonski ,  David E. Alman

IPC分类号： C23C16/06

CPC分类号： C23C10/30

摘要： A method of applying a cerium diffusion coating to a preferred nickel base alloy substrate has been discovered. A cerium oxide paste containing a halide activator is applied to the polished substrate and then dried. The workpiece is heated in a non-oxidizing atmosphere to diffuse cerium into the substrate. After cooling, any remaining cerium oxide is removed. The resulting cerium diffusion coating on the nickel base substrate demonstrates improved resistance to oxidation. Cerium coated alloys are particularly useful as components in a solid oxide fuel cell (SOFC).

摘要翻译： 已经发现了将铈扩散涂层应用于优选的镍基合金基底的方法。 将含有卤化物活化剂的氧化铈糊料施加到抛光的基材上，然后干燥。 工件在非氧化性气氛中被加热，以将铈扩散到衬底中。 冷却后，除去剩余的氧化铈。 在镍基底材上形成的铈扩散涂层表现出改进的耐氧化性。 铈涂层合金特别可用作固体氧化物燃料电池（SOFC）中的组分。

公开(公告)号：US09012032B1

公开(公告)日：2015-04-21

申请号：US14065726

申请日：2013-10-29

申请人： Paul D. Jablonski ,  Jeffrey A. Hawk

发明人： Paul D. Jablonski ,  Jeffrey A. Hawk

IPC分类号： B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  F01D5/28 ,  C23C30/00 ,  C23C16/40 ,  C23C4/10 ,  C23C14/08 ,  C23C28/04 ,  C23C28/02 ,  C23C4/08

CPC分类号： C23C4/073 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  C23C4/18 ,  C23C14/083 ,  C23C16/405 ,  C23C28/022 ,  C23C28/042 ,  C23C30/005 ,  F01D5/28 ,  F01D5/288 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12951 ,  Y10T428/12979 ,  Y10T428/264 ,  Y10T428/265

摘要： One or more embodiments relates to an MCrAlY bond coat comprising an MCrAlY layer in contact with a Y—Al2O3 layer. The MCrAlY layer is comprised of a γ-M solid solution, a β-MAl intermetallic phase, and Y-type intermetallics. The Y—Al2O3 layer is comprised of Yttrium atoms coordinated with oxygen atoms comprising the Al2O3 lattice. Both the MCrAlY layer and the Y—Al2O3 layer have a substantial absence of Y—Al oxides, providing advantage in the maintainability of the Yttrium reservoir within the MCrAlY bulk. The MCrAlY bond coat may be fabricated through application of a Y2O3 paste to an MCrAlY material, followed by heating in a non-oxidizing environment.

摘要翻译： 一个或多个实施方案涉及包含与Y-Al 2 O 3层接触的MCrAlY层的MCrAlY粘合涂层。 MCrAlY层由γ-M固溶体，金属间化合物相和Y型金属间化合物构成。 Y-Al 2 O 3层由与包含Al 2 O 3晶格的氧原子配位的钇原子组成。 MCrAlY层和Y-Al2O3层都基本上不存在Y-Al氧化物，提供了钇储层在MCrAlY体内的可维护性的优点。 MCrAlY粘合涂层可以通过将Y 2 O 3糊剂施加到MCrAlY材料，然后在非氧化环境中加热来制造。

公开(公告)号：US09556503B1

公开(公告)日：2017-01-31

申请号：US14871774

申请日：2015-09-30

申请人： Jeffrey A. Hawk ,  Paul D. Jablonski ,  Christopher J. Cowen

发明人： Jeffrey A. Hawk ,  Paul D. Jablonski ,  Christopher J. Cowen

IPC分类号： C22C38/44 ,  C22C38/54 ,  C22C38/52 ,  C22C38/48 ,  C22C38/46 ,  C22C38/04 ,  C22C38/02 ,  C22C38/00

CPC分类号： C22C38/54 ,  C21D6/00 ,  C21D6/002 ,  C21D6/02 ,  C21D8/00 ,  C21D8/005 ,  C21D8/0226 ,  C21D8/0263 ,  C21D2211/004 ,  C21D2211/008 ,  C22C38/00 ,  C22C38/001 ,  C22C38/002 ,  C22C38/02 ,  C22C38/04 ,  C22C38/40 ,  C22C38/44 ,  C22C38/46 ,  C22C38/48 ,  C22C38/52

摘要： The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, copper, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M23C6carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650° C.

摘要翻译： 本公开提供了具有由铁，铬，钼，碳，锰，硅，镍，钒，铌，氮，钨，钴，钽，硼，铜和潜在附加元素组成的总体组成的抗蠕变合金。 在一个实施方案中，耐蠕变合金具有钼当量Mo（eq），为1.475至1.700wt。 ％，数量（C + N）为0.145〜0.205。 整体组成改善了微结构不稳定性的来源，如M23C6碳化物和MX沉淀物的粗化，减轻或消除了Laves和Z相的形成。 耐蠕变马氏体钢可以通过制备由整体组成组成的熔体，然后至少进行奥氏体化和回火来制造。 耐蠕变合金在约650℃的温度环境中表现出改善的高温蠕变强度。

公开(公告)号：US09181597B1

公开(公告)日：2015-11-10

申请号：US13868139

申请日：2013-04-23

申请人： Jeffrey A. Hawk ,  Paul D. Jablonski ,  Christopher J. Cowen

发明人： Jeffrey A. Hawk ,  Paul D. Jablonski ,  Christopher J. Cowen

IPC分类号： C22C38/44 ,  C21D8/00 ,  C21D6/00 ,  C22C38/00 ,  C22C38/02 ,  C22C38/04 ,  C22C38/46 ,  C22C38/48 ,  C22C38/52 ,  C22C38/54 ,  C22C38/40

CPC分类号： C22C38/54 ,  C21D6/00 ,  C21D6/002 ,  C21D6/004 ,  C21D6/005 ,  C21D6/008 ,  C21D6/02 ,  C21D8/00 ,  C21D8/005 ,  C21D8/0226 ,  C21D8/0263 ,  C21D2211/004 ,  C21D2211/008 ,  C22C38/00 ,  C22C38/001 ,  C22C38/02 ,  C22C38/04 ,  C22C38/40 ,  C22C38/44 ,  C22C38/46 ,  C22C38/48 ,  C22C38/52

摘要： The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M23C6 carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650° C.

摘要翻译： 本公开提供了具有由铁，铬，钼，碳，锰，硅，镍，钒，铌，氮，钨，钴，钽，硼和潜在的附加元素组成的总体组成的抗蠕变合金。 在一个实施方案中，耐蠕变合金具有钼当量Mo（eq），为1.475至1.700wt。 ％，数量（C + N）为0.145〜0.205。 整体组成改善了微观结构不稳定的来源，如M23C6碳化物和MX沉淀物的粗化，减轻或消除了Laves和Z相的形成。 耐蠕变马氏体钢可以通过制备由整体组成组成的熔体，然后进行至少奥氏体化和回火来制造。 耐蠕变合金在约650℃的温度环境中表现出改善的高温蠕变强度。

公开(公告)号：US5226947A

公开(公告)日：1993-07-13

申请号：US837038

申请日：1992-02-17

申请人： Paul D. Jablonski ,  David C. Larbalestier

发明人： Paul D. Jablonski ,  David C. Larbalestier

IPC分类号： B22F1/00 ,  H01L39/24

CPC分类号： H01L39/2406 ,  B22F1/0003 ,  Y10S420/901 ,  Y10S505/806 ,  Y10T428/12021

摘要： Superconductors formed by powder metallurgy have a matrix of niobium-titanium alloy with discrete pinning centers distributed therein which are formed of a compatible metal. The artificial pinning centers in the Nb-Ti matrix are reduced in size by processing steps to sizes on the order of the coherence length, typically in the range of 1 to 10 nm. To produce the superconductor, powders of body centered cubic Nb-Ti alloy and the second phase flux pinning material, such as Nb, are mixed in the desired percentages. The mixture is then isostatically pressed, sintered at a selected temperature and selected time to produce a cohesive structure having desired characteristics without undue chemical reaction, the sintered billet is reduced in size by deformation, such as by swaging, the swaged sample receives heat treatment and recrystallization and additional swaging, if necessary, and is then sheathed in a normal conducting sheath, and the sheathed material is drawn into a wire. The resulting superconducting wire has second phase flux pinning centers distributed therein which provide enhanced J.sub.ct due to the flux pinning effects.

摘要翻译： 通过粉末冶金形成的超导体具有铌 - 钛合金的基体，其中分散的钉扎中心由相容的金属形成。 在Nb-Ti基体中的人造钉扎中心的尺寸通过处理步骤而减小，其尺寸相干长度通常在1至10nm的范围内。 为了制造超导体，以体心立方Nb-Ti合金粉末和第二相磁通钉扎材料（例如Nb）以所需的百分比混合。 然后将混合物均匀压制，在选择的温度下选择时间烧结，以产生具有所需特性而没有不适当化学反应的粘结结构，烧结坯料通过变形例如通过模锻而减小尺寸，模锻样品接受热处理， 如果需要，再结晶和附加的模锻，然后将其包覆在正常的导电护套中，并且将护套材料拉成线材。 所得到的超导线具有分布在其中的第二相磁通钉扎中心，由于磁通钉扎效应而提供增强的Jct。

公开(公告)号：US09428825B1

公开(公告)日：2016-08-30

申请号：US13363486

申请日：2012-02-01

申请人： Paul D. Jablonski ,  Jeffrey A. Hawk

发明人： Paul D. Jablonski ,  Jeffrey A. Hawk

IPC分类号： B05D3/02 ,  B32B15/20

CPC分类号： C23C4/073 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  C23C4/18 ,  C23C14/083 ,  C23C16/405 ,  C23C28/022 ,  C23C28/042 ,  C23C30/005 ,  F01D5/28 ,  F01D5/288 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/1266 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12951 ,  Y10T428/12979 ,  Y10T428/264 ,  Y10T428/265

摘要： One or more embodiments relates to a method of producing an MCrAlY bond coat comprising an MCrAlY layer in contact with a Y—Al2O3 layer. The MCrAlY layer is comprised of a γ-M solid solution, a β-MAl intermetallic phase, and Y-type intermetallics. The Y—Al2O3 layer is comprised of Yttrium atoms coordinated with oxygen atoms comprising the Al2O3 lattice. The method comprises depositing an MCrAlY material on a substrate, applying an Y2O3 paste, and heating the substrate in a non-oxidizing atmosphere at a temperature between 400-1300° C. for a time sufficient to generate the Y—Al2O3 layer. Both the MCrAlY layer and the Y—Al2O3 layer have a substantial absence of Y2O3, YAG, and YAP phases.

摘要翻译： 一个或多个实施方案涉及制备包含与Y-Al 2 O 3层接触的MCrAlY层的MCrAlY粘合涂层的方法。 MCrAlY层由γ-M固溶体，β-MA1金属间相和Y型金属间化合物构成。 Y-Al 2 O 3层由与包含Al 2 O 3晶格的氧原子配位的钇原子组成。 该方法包括在衬底上沉积MCrAlY材料，施加Y 2 O 3糊剂，并在400-1300℃的温度下在非氧化性气氛中加热衬底足以产生Y-Al 2 O 3层的时间。 MCrAlY层和Y-Al2O3层都基本上没有Y2O3，YAG和YAP相。

公开(公告)号：US08317944B1

公开(公告)日：2012-11-27

申请号：US13282211

申请日：2011-10-26

申请人： Paul D. Jablonski ,  David Alman ,  Omer Dogan ,  Gordon Holcomb ,  Christopher Cowen

发明人： Paul D. Jablonski ,  David Alman ,  Omer Dogan ,  Gordon Holcomb ,  Christopher Cowen

IPC分类号： C22C38/00

CPC分类号： C21D6/002 ,  C21D6/02 ,  C21D2211/004 ,  C21D2211/008 ,  C22C38/02 ,  C22C38/04 ,  C22C38/22 ,  C22C38/24 ,  C22C38/26 ,  C22C38/28 ,  C23C12/02

摘要： One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 μm) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

摘要翻译： 一个或多个实施方案涉及在高达650℃的使用温度下表现出改进的蠕变强度和抗氧化性的高温钛合金的9Cr-1 Mo钢.9Cr-1 Mo钢具有回火马氏体组织，并且是 由大（0.5-3μm）的主碳化钛和小（5-50nm）的二次碳化钛组成。 约1：1.5至约1.5：1。 9 Cr-1 Mo钢可以使用示例性的奥氏体化，快速冷却和回火步骤制造，而无需后续的热加工要求。 在所考察的温度和时间条件下，9Cr-1 Mo钢在总体质量增益，屈服强度和断裂时间方面均优于ASTM P91和ASTM P92。

公开(公告)号：US08246767B1

公开(公告)日：2012-08-21

申请号：US12209488

申请日：2008-09-12

申请人： Paul D. Jablonski ,  David Alman ,  Omer Dogan ,  Gordon Holcomb ,  Christopher Cowen

发明人： Paul D. Jablonski ,  David Alman ,  Omer Dogan ,  Gordon Holcomb ,  Christopher Cowen

IPC分类号： C21D6/02

CPC分类号： C21D6/002 ,  C21D6/02 ,  C21D2211/004 ,  C21D2211/008 ,  C22C38/02 ,  C22C38/04 ,  C22C38/22 ,  C22C38/24 ,  C22C38/26 ,  C22C38/28 ,  C23C12/02

摘要： The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

摘要翻译： 本发明涉及一种高温，钛合金的9Cr-1 Mo钢的组成和热处理，其在高达650℃的使用温度下具有改进的蠕变强度和抗氧化性。组合和热处理的新颖组合产生 含有大的初级碳化钛和小的二次碳化钛的热处理材料。 主要的碳化钛有助于蠕变强度，而二次碳化钛在成品钢中保持较高水平的铬，以提高耐氧化性，并通过阻止位错通过晶体结构的运动来加强钢。 经热处理的材料与常规使用的高温钢（例如ASTM P91和ASTM P92）相当的成本提供了改进的性能，并且仅需要由奥氏体化，快速冷却，回火和最终冷却组成的热处理， 在奥氏体温度范围内工作。