Guard bed for the removal of sulfur and nickel from feeds previously
contacted with nickel containing sulfur adsorption catalysts
    1.
    发明授权
    Guard bed for the removal of sulfur and nickel from feeds previously contacted with nickel containing sulfur adsorption catalysts 失效
    保护床用于从先前与含镍硫吸附催化剂接触的原料中除去硫和镍

    公开(公告)号:US4446005A

    公开(公告)日:1984-05-01

    申请号:US419239

    申请日:1982-09-17

    IPC分类号: C10G25/00 C10G69/08

    CPC分类号: C10G25/00 C10G2400/02

    摘要: A back-end guard bed is located downstream of and in series with a nickel catalyst-containing sulfur trap to remove the organosulfur-nickel complex formed in the nickel catalyst-containing sulfur trap and passed along with the product therefrom during periods of hydrofiner upset, or such other periods when sulfur concentration, flow rate and operating temperature of the feed passed from the hydrofiner through the nickel catalyst-containing sulfur trap forms the organosulfur-nickel complex.

    摘要翻译: 后端保护床位于含镍催化剂的硫捕集器的下游并与其串联,以除去在含镍催化剂的硫捕集器中形成的有机硫 - 镍络合物,并在其中加氢产生水分流, 或者从氢化水剂通过含镍催化剂的硫捕集器通过的进料的硫浓度,流速和操作温度形成有机硫 - 镍络合物的其它时期。

    FCC for producing low emission fuels from high hydrogen and low nitrogen
and aromatic feeds
    2.
    发明授权
    FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds 失效
    FCC用于从高氢和低氮和芳香的饲料生产低排放燃料

    公开(公告)号:US5318692A

    公开(公告)日:1994-06-07

    申请号:US982916

    申请日:1992-11-30

    IPC分类号: C10G11/05 C10G11/18

    CPC分类号: C10G11/05

    摘要: A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is relatively low in nitrogen and aromatics and high in hydrogen content and the catalyst is a mixture of zeolite-Y and ZSM-5, or an amorphous acid catalytic material with ZSM-5, or a combination of all three. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

    摘要翻译: 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳族化合物相对较低,氢含量高,催化剂是沸石-Y和ZSM-5或具有ZSM-5的无定形酸催化材料或所有三种组合的混合物。 原料可以表征为具有小于约50wppm氮; 大于约13重量% %氢; 小于约7.5重量% %2+环芳烃芯; 并且不超过约15wt。 %芳香核心总体。

    Crystalline silica zeolite-containing catalyst
    3.
    发明授权
    Crystalline silica zeolite-containing catalyst 失效
    含结晶二氧化硅沸石的催化剂

    公开(公告)号:US4513090A

    公开(公告)日:1985-04-23

    申请号:US281860

    申请日:1981-07-09

    摘要: A catalyst is provided which comprises a crystalline silica zeolite, a hydrogenation component and a support. The catalyst may be a physical mixture of the zeolite and the supported hydrogenation component or a composite catalyst. Hydrocarbon hydroprocessing processes such as hydroconversion and hydrodesulfurization utilizing the catalyst are also provided. The catalyst is particularly suited for the simultaneous pour point reduction and hydrodesulfurization of hydrocarbonaceous oils.

    摘要翻译: 提供了包含结晶二氧化硅沸石,氢化组分和载体的催化剂。 催化剂可以是沸石和负载的氢化组分的物理混合物或复合催化剂。 还提供烃加氢处理如加氢转化和使用催化剂的加氢脱硫。 催化剂特别适用于同时进行降烃和烃油的加氢脱硫。

    Adsorbents for sulfur removal
    7.
    发明授权
    Adsorbents for sulfur removal 失效
    吸附剂用于除硫

    公开(公告)号:US4464252A

    公开(公告)日:1984-08-07

    申请号:US410250

    申请日:1982-08-23

    IPC分类号: C10G25/00 C10G29/04

    CPC分类号: C10G25/003

    摘要: A process wherein a regenerated, spent sulfided vanadium-containing Group VIII metal, Group VI-B metal, or Group VI-B/Group VIII metals containing catalyst is contacted with a stream of an oxygen-containing gas and the coke burned therefrom to regenerate the catalyst. The regenerated catalyst as such, or after reduction of the catalytic metals by contact with hydrogen, can be used as an adsorbent to remove essentially all of the sulfur from a naphtha feed which contains as much as 50 weight ppm sulfur, and greater.

    摘要翻译: 一种方法,其中将再生的废硫化钒的VIII族金属,VI-B族金属或含有VI-B / VIII族金属的催化剂与含氧气体流和从其燃烧的焦炭接触以再生 催化剂。 再生的催化剂本身,或者通过与氢接触还原催化金属,可以用作吸附剂,以从含有多达50重量ppm硫的石脑油进料中基本上除去所有硫。

    Reforming with multimetallic catalysts
    8.
    发明授权
    Reforming with multimetallic catalysts 失效
    用多金属催化剂重整

    公开(公告)号:US4282086A

    公开(公告)日:1981-08-04

    申请号:US79577

    申请日:1979-09-27

    摘要: A process for desensitizing a hypersensitive, high activity reforming catalyst for suppression of hydrogenolysis which is particularly acute during the early portion of the period that the catalyst is placed on stream, i.e., at the startup of a reactor. The catalyst is constituted of a composite which includes a Group VIII nobel metal hydrogenation-dehydrogenation component, notably platinum, and iridium or rhenium, or both, and sulfurous acid or sulfuric acid, or both. Hydrogenolysis is suppressed by use of the catalyst during reforming.

    摘要翻译: 一种用于抑制氢解的过敏,高活性重整催化剂的脱敏方法,其在催化剂放置在流动的时期的早期部分,即在反应器启动时,其特别急剧。 该催化剂由包含第VIII族诺贝尔金属氢化脱氢组分,特别是铂,铱或铼,或两者以及亚硫酸或硫酸或两者的复合材料构成。 在重整过程中通过使用催化剂来抑制氢解。

    Reforming with multimetallic catalysts
    9.
    发明授权
    Reforming with multimetallic catalysts 失效
    用多金属催化剂重整

    公开(公告)号:US4213881A

    公开(公告)日:1980-07-22

    申请号:US969548

    申请日:1978-12-14

    摘要: A process for desensitizing a hypersensitive, high activity reforming catalyst for suppression of hydrogenolysis which is particularly acute during the early portion of the period that the catalyst is placed on stream, i.e., at the startup of a reactor. The catalyst is constituted of a composite which includes a Group VIII noble metal hydrogenation-dehydrogenation component, notably platinum, and iridium or rhenium, or both, selenium, and sulfurous acid or sulfuric acid, or both. Hydrogenolysis is suppressed by use of the catalyst during reforming.

    摘要翻译: 一种用于抑制氢解的过敏,高活性重整催化剂的脱敏方法,其在催化剂放置在流动的时期的早期部分,即在反应器启动时,其特别急剧。 该催化剂由包含VIII族贵金属加氢脱氢组分,特别是铂,铱或铼,或二者同时含有硒,亚硫酸或硫酸的复合材料构成。 在重整过程中通过使用催化剂来抑制氢解。

    Reforming with multimetallic catalysts
    10.
    发明授权
    Reforming with multimetallic catalysts 失效
    用多金属催化剂重整

    公开(公告)号:US4169043A

    公开(公告)日:1979-09-25

    申请号:US950805

    申请日:1978-10-12

    CPC分类号: B01J27/0573 C10G35/09

    摘要: A process for desensitizing a hypersensitive, high activity reforming catalyst for suppression of hydrogenolysis which is particularly acute during the early portion of the period that the catalyst is placed on stream, i.e., at the startup of a reactor. The catalyst is constituted of a composite which includes a Group VIII noble metal hydrogenation-dehydrogenation component, notably platinum, iridium, and selenium. Hydrogenolysis is suppressed by incorporating within such reforming catalyst at the time of its preparation an element, or a compound or salt of selenium. In another of its aspects the present invention embodies a reforming catalyst or catalyst composite comprising a refractory or inorganic oxide support material, particularly alumina, a Group VIII noble metal hydrogenation-dehydrogenation component, notably platinum, to which iridium, and selenium, have been added to promote the activity and selectivity of the catalysts, and said catalyst is prepared by a method wherein selenium is introduced into and deposited throughout said support. Suitably, the reforming catalyst, or composite also contains a halogen component, particularly chlorine and preferably the selenium component is introduced into the support, or catalyst, by impregnating with a solution comprising an element, salt, acid or compound of selenium.

    摘要翻译: 一种用于抑制氢解的过敏,高活性重整催化剂的脱敏方法,其在催化剂放置在流动的时期的早期部分,即在反应器启动时,其特别急剧。 催化剂由包含VIII族贵金属氢化脱氢组分,特别是铂,铱和硒的复合材料构成。 通过在其制备时在这种重整催化剂中引入元素或硒的化合物或盐来抑制氢解。 在其另一方面,本发明体现了包含耐火材料或无机氧化物载体材料,特别是氧化铝的重整催化剂或催化剂复合物,已加入铱和硒的第VIII族贵金属氢化脱氢组分,特别是铂 以促进催化剂的活性和选择性,并且所述催化剂通过其中将硒引入并沉积在所述载体上的方法制备。 合适地,重整催化剂或复合材料还含有卤素组分,特别是氯,优选通过用包含元素,盐,酸或硒化合物的溶液浸渍将硒组分引入载体或催化剂中。