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    Gaseous phase fluidized-bed reactor
    2.
    发明授权
    Gaseous phase fluidized-bed reactor 失效
    气相流化床反应器

    公开(公告)号：US07601303B1

    公开(公告)日：2009-10-13

    申请号：US09700367

    申请日：1999-05-04

    申请人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    发明人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    IPC分类号： B01J8/18

    CPC分类号： B01J8/1827 ,  B01J8/44 ,  B01J2208/00256 ,  B01J2208/00274 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

    摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.

    摘要翻译： 用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域 完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

    Gaseous phase fluidized-bed reactor
    3.
    发明授权
    Gaseous phase fluidized-bed reactor 失效
    气相流化床反应器

    公开(公告)号：US08034884B2

    公开(公告)日：2011-10-11

    申请号：US12554964

    申请日：2009-09-07

    申请人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    发明人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    IPC分类号： C08F2/00 ,  B01J8/18

    CPC分类号： B01J8/1827 ,  B01J8/44 ,  B01J2208/00256 ,  B01J2208/00274 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

    摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.

    摘要翻译： 用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域 完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

    Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method
    4.
    发明授权
    Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
    气相流化床法和使用所述方法获得的乙烯均聚物和共聚物

    公开(公告)号：US06649709B1

    公开(公告)日：2003-11-18

    申请号：US09555594

    申请日：2000-05-31

    申请人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

    发明人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

    IPC分类号： C08F234

    CPC分类号： C08F10/02 ,  C08F4/24 ,  C08F2/34

    摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

    摘要翻译： 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合 在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床 包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物 特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

    GASEOUS PHASE FLUIDIZED-BED REACTOR
    5.
    发明申请
    GASEOUS PHASE FLUIDIZED-BED REACTOR 失效
    气相流化床反应器

    公开(公告)号：US20100056734A1

    公开(公告)日：2010-03-04

    申请号：US12554964

    申请日：2009-09-07

    申请人： Rainer KARER ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    发明人： Rainer KARER ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

    IPC分类号： C08F2/01

    CPC分类号： B01J8/1827 ,  B01J8/44 ,  B01J2208/00256 ,  B01J2208/00274 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

    摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.

    摘要翻译： 用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域 完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

    Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby
    6.
    发明授权
    Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
    气相流化床方法和由此制备的乙烯均聚物和共聚物

    公开(公告)号：US06849699B2

    公开(公告)日：2005-02-01

    申请号：US10658916

    申请日：2003-09-11

    申请人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

    发明人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

    IPC分类号： C08J5/18 ,  C08F2/34 ,  C08F4/02 ,  C08F4/24 ,  C08F4/69 ,  C08F10/02 ,  C08F210/02

    CPC分类号： C08F10/02 ,  C08F4/24 ,  C08F2/34

    摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢   ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢   ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

    摘要翻译： 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合 在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床 包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物 特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

    Method for the discontinuous thermal treatment of catalyst material
    8.
    发明授权
    Method for the discontinuous thermal treatment of catalyst material 失效
    催化剂材料不连续热处理方法

    公开(公告)号：US06683022B1

    公开(公告)日：2004-01-27

    申请号：US09536355

    申请日：2000-03-27

    申请人： Paulus De Lange ,  Michael Kämmerer ,  Thomas Brauch ,  Kaspar Evertz ,  Thomas Letzelter ,  Peter Kölle ,  Hans-Jacob Feindt

    发明人： Paulus De Lange ,  Michael Kämmerer ,  Thomas Brauch ,  Kaspar Evertz ,  Thomas Letzelter ,  Peter Kölle ,  Hans-Jacob Feindt

    IPC分类号： B01J2326

    CPC分类号： C08F10/00 ,  C08F4/24

    摘要： Method for the discontinuous thermal treatment of catalyst material comprising the steps (a) introducing the catalyst material into a reactor, (b) heating the catalyst material, (c) thermally treating the catalyst material in the reactor at the reactor temperature, (d) discharging the catalyst material from the reactor and (e) cooling the catalyst material, wherein the reactor temperature is kept constant during the steps (a) to (e), step (b) is carried out during and/or after step (a), step (e) is carried out during and/or after step (d), and step (c) is carried out after step (b) and before step (e). The method is used primarily for the calcination or activation of catalysts or catalyst supports which are used in polyolefin production.

    摘要翻译： 催化剂材料的不连续热处理方法，包括步骤（a）将催化剂材料引入反应器，（b）加热催化剂材料，（c）在反应器温度下热处理反应器中的催化剂材料，（d） 从反应器中排出催化剂材料，（e）冷却催化剂材料，其中步骤（a）至（e）中步骤（b）中步骤（a）至（e）期间反应器温度保持恒定在步骤（a）期间和/ 步骤（e）在步骤（d）期间和/或之后进行，步骤（c）在步骤（b）之后和步骤（e）之前进行。该方法主要用于催化剂的煅烧或活化 或用于聚烯烃生产的催化剂载体。

    Discontinuous metering of catalysts and process auxilliaries into a gas-phase fluidized-bed reactor
    9.
    发明授权
    Discontinuous metering of catalysts and process auxilliaries into a gas-phase fluidized-bed reactor 失效
    催化剂和工艺助剂不连续计量进入气相流化床反应器

    公开(公告)号：US07534341B2

    公开(公告)日：2009-05-19

    申请号：US10552853

    申请日：2004-04-15

    申请人： Rainer Karer ,  Kaspar Evertz ,  Peter Kölle ,  Hans-Jacob Feindt

    发明人： Rainer Karer ,  Kaspar Evertz ,  Peter Kölle ,  Hans-Jacob Feindt

    IPC分类号： C10G35/00 ,  C10G35/10

    CPC分类号： B01J4/002 ,  B01J4/007 ,  B01J4/02 ,  B01J8/0035 ,  B01J8/004 ,  B01J8/1872 ,  B01J2208/00752 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2/00 ,  C08F2/01 ,  C08F2/34 ,  C08F2500/07 ,  C08F2500/12

    摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.

    摘要翻译： 将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中 至少一个计量点（10）。 根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入 这个地区。 由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

    Discontinuous metering of catalysts and process auxiliaries into a gas-phase fluidized-bed reactor
    10.
    发明申请
    Discontinuous metering of catalysts and process auxiliaries into a gas-phase fluidized-bed reactor 失效
    催化剂和工艺助剂不连续计量进入气相流化床反应器

    公开(公告)号：US20070037935A1

    公开(公告)日：2007-02-15

    申请号：US10552853

    申请日：2004-04-15

    申请人： Rainer Karer ,  Kaspar Evertz ,  Hans-Jacob Feindt

    发明人： Rainer Karer ,  Kaspar Evertz ,  Hans-Jacob Feindt

    IPC分类号： C08G85/00 ,  B32B27/04

    CPC分类号： B01J4/002 ,  B01J4/007 ,  B01J4/02 ,  B01J8/0035 ,  B01J8/004 ,  B01J8/1872 ,  B01J2208/00752 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2/00 ,  C08F2/01 ,  C08F2/34 ,  C08F2500/07 ,  C08F2500/12

    摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.

    摘要翻译： 将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中 至少一个计量点（10）。 根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入 这个地区。 由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。