公开(公告)号：US06559087B1

公开(公告)日：2003-05-06

申请号：US09536356

申请日：2000-03-27

申请人： Paulus De Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt

发明人： Paulus De Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt

IPC分类号： B01J3708

CPC分类号： B65G53/22 ,  B01J8/10 ,  B01J8/26 ,  B01J8/46 ,  B01J19/18 ,  B01J19/22 ,  B01J37/00 ,  B01J2219/00033 ,  B01J2219/00132 ,  C08F10/00 ,  Y10S526/905 ,  C08F4/24

摘要： A method for the treatment of catalyst or catalyst support material in an apparatus in which the treatment is carried out continuously in such a way that the physical and/or chemical conditions change during entry of the catalyst or catalyst support material into the apparatus and/or during exit thereof from the apparatus and/or the catalyst or catalyst support material is transported in the apparatus through zones (5, 6, 7) having different physical and/or chemical conditions.

摘要翻译： 一种在设备中处理催化剂或催化剂载体材料的方法，其中以使得催化剂或催化剂载体材料进入装置和/或其中的物理和/或化学条件改变的方式连续进行处理 在从装置出来时和/或催化剂或催化剂载体材料在装置中通过具有不同物理和/或化学条件的区域（5,6,7）输送。

公开(公告)号：US06649709B1

公开(公告)日：2003-11-18

申请号：US09555594

申请日：2000-05-31

申请人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

发明人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

IPC分类号： C08F234

CPC分类号： C08F10/02 ,  C08F4/24 ,  C08F2/34

摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

摘要翻译： 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合 在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床 包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物 特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

公开(公告)号：US07601303B1

公开(公告)日：2009-10-13

申请号：US09700367

申请日：1999-05-04

申请人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

发明人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

IPC分类号： B01J8/18

CPC分类号： B01J8/1827 ,  B01J8/44 ,  B01J2208/00256 ,  B01J2208/00274 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.

摘要翻译： 用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域 完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

公开(公告)号：US08034884B2

公开(公告)日：2011-10-11

申请号：US12554964

申请日：2009-09-07

申请人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

发明人： Rainer Karer ,  Kaspar Evertz ,  Wolfgang Micklitz ,  Hans-Jacob Feindt ,  Philipp Rosendorfer ,  Peter Kölle

IPC分类号： C08F2/00 ,  B01J8/18

CPC分类号： B01J8/1827 ,  B01J8/44 ,  B01J2208/00256 ,  B01J2208/00274 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.

摘要翻译： 用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域 完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

公开(公告)号：US06849699B2

公开(公告)日：2005-02-01

申请号：US10658916

申请日：2003-09-11

申请人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

发明人： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

IPC分类号： C08J5/18 ,  C08F2/34 ,  C08F4/02 ,  C08F4/24 ,  C08F4/69 ,  C08F10/02 ,  C08F210/02

CPC分类号： C08F10/02 ,  C08F4/24 ,  C08F2/34

摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢   ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢   ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

摘要翻译： 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合 在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床 包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物 特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

公开(公告)号：US06180729B2

公开(公告)日：2001-01-30

申请号：US09201084

申请日：1998-11-30

申请人： Armin Lange ,  Wolfgang Micklitz ,  Rainer Karer ,  Kaspar Evertz ,  Shahram Mihan ,  Hans-Jacob Feindt ,  Manfred Hecker ,  Peter Bauer ,  Philipp Rosendorfer

发明人： Armin Lange ,  Wolfgang Micklitz ,  Rainer Karer ,  Kaspar Evertz ,  Shahram Mihan ,  Hans-Jacob Feindt ,  Manfred Hecker ,  Peter Bauer ,  Philipp Rosendorfer

IPC分类号： C08F240

CPC分类号： C08F10/00 ,  C08F2/005 ,  C08F210/16 ,  Y02P20/584 ,  C08F2/34 ,  C08F2/40 ,  C08F2/007 ,  C08F2/002 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

摘要： In a continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or a mixture of ethylene or propene and C3-C8-&agr;-monoolefins is polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and a pressure of from 1 to 100 bar in the gas phase in a bed of finely divided polymer in the presence of a catalyst, where the reactor gas is circulated to remove the heat of polymerization, polymer deposits in the circulating gas line are prevented by metering a catalyst poison having a boiling point above the maximum temperature within the circulating gas line into this circulating gas line in at most such an amount that it does not significantly impair the productivity of the catalyst in the reactor.

摘要翻译： 在用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法中，其中乙烯，丙烯或乙烯或丙烯和C 3 -C 8-α-单烯烃的混合物在气相聚合反应器的聚合区中聚合 在催化剂存在下，在细分散的聚合物床中的气相中，在30至125℃和1至100巴的压力下，其中反应器气体循环以除去聚合热，聚合物沉积物 通过将沸点高于循环气体管线中的最高温度的催化剂毒物计量到该循环气体管线中，至多使其不显着损害反应器中催化剂的生产率的程度来防止循环气体管线 。

公开(公告)号：US07534341B2

公开(公告)日：2009-05-19

申请号：US10552853

申请日：2004-04-15

申请人： Rainer Karer ,  Kaspar Evertz ,  Peter Kölle ,  Hans-Jacob Feindt

发明人： Rainer Karer ,  Kaspar Evertz ,  Peter Kölle ,  Hans-Jacob Feindt

IPC分类号： C10G35/00 ,  C10G35/10

CPC分类号： B01J4/002 ,  B01J4/007 ,  B01J4/02 ,  B01J8/0035 ,  B01J8/004 ,  B01J8/1872 ,  B01J2208/00752 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2/00 ,  C08F2/01 ,  C08F2/34 ,  C08F2500/07 ,  C08F2500/12

摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.

摘要翻译： 将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中 至少一个计量点（10）。 根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入 这个地区。 由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

公开(公告)号：US20070037935A1

公开(公告)日：2007-02-15

申请号：US10552853

申请日：2004-04-15

申请人： Rainer Karer ,  Kaspar Evertz ,  Hans-Jacob Feindt

发明人： Rainer Karer ,  Kaspar Evertz ,  Hans-Jacob Feindt

IPC分类号： C08G85/00 ,  B32B27/04

CPC分类号： B01J4/002 ,  B01J4/007 ,  B01J4/02 ,  B01J8/0035 ,  B01J8/004 ,  B01J8/1872 ,  B01J2208/00752 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2/00 ,  C08F2/01 ,  C08F2/34 ,  C08F2500/07 ,  C08F2500/12

摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.

摘要翻译： 将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中 至少一个计量点（10）。 根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入 这个地区。 由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

公开(公告)号：US20120065335A1

公开(公告)日：2012-03-15

申请号：US13301495

申请日：2011-11-21

申请人： Jennifer Kipke ,  Shahram Mihan ,  Rainer Karer ,  Jörg Auffermann ,  Manfred Hecker ,  Paulus De Lange ,  Harald Schmitz

发明人： Jennifer Kipke ,  Shahram Mihan ,  Rainer Karer ,  Jörg Auffermann ,  Manfred Hecker ,  Paulus De Lange ,  Harald Schmitz

IPC分类号： C08L23/06

CPC分类号： C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/06 ,  C08L2666/02

摘要： A polyethylene composition, in particular suitable for the preparation of films, and a process for preparing the same are described. The polyethylene composition of the invention comprises from 50 to 89% by weight of a first polyethylene component comprising at least one multimodal polyethylene including a plurality of ethylene polymer fractions having distinct molecular weights and comonomer contents, at least one of said plurality of ethylene polymer fractions being prepared by the use of a single site catalyst, and from 50 to 11% by weight of a second polyethylene component comprising a low or medium density polyethylene.

摘要翻译： 描述了特别适用于制备薄膜的聚乙烯组合物及其制备方法。 本发明的聚乙烯组合物包含50至89重量％的第一聚乙烯组分，其包含至少一种多峰聚乙烯，其包含具有不同分子量和共聚单体含量的多种乙烯聚合物级分，所述多种乙烯聚合物级分中的至少一种 通过使用单中心催化剂制备，以及50至11重量％的包含低密度或中密度聚乙烯的第二聚乙烯组分。

公开(公告)号：US07781544B2

公开(公告)日：2010-08-24

申请号：US11667349

申请日：2005-11-09

申请人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

发明人： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus De Lange ,  Jörg Halpap ,  Cyrus Ahmadzade-Youssefi

IPC分类号： C08F2/00 ,  F27B15/08

CPC分类号： B01J8/1872 ,  B01J8/0055 ,  B01J8/24 ,  B01J2208/00256 ,  B01J2208/00274 ,  B04C5/081 ,  C08F6/02 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08F2/34

摘要： An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tube (5) extending essentially axially symmetrically down into the upper section and, if appropriate, the middle section for discharging the recycle gas which has been freed of the particles. According to the invention the ratio Hi of the distance hi from the lower end of the tube (5) extending downward into the cyclone to the intersection (6) of an imaginary extension of the wall of the downward-extending tube (5) with the wall of the middle section (3b) to the diameter di of the downward-extending tube (5) is from 3 to 8, in particular from 4 to 7.

摘要翻译： 用于烯烃聚合的装置，特别是乙烯，包括气相流化床反应器（1），连接到反应器的再循环气体管线（2），用于排出和再循环包含未聚合烯烃的循环气流和 旋风分离器（3）位于循环气体管线中，用于还原和沉淀夹带在来自反应器的再循环气体中的固体颗粒，其中旋风分离器包括具有基本垂直的中心轴线的上部分（3a），其上壁沿着 旋转对称体，并且设置有相对于中心轴偏心布置的旋风入口（4），邻接上部（3a）的中间部分（3b），并且其壁沿着旋转对称的体 用于排出邻近中间部分（3b）的循环气体沉淀的固体颗粒的下部（3c），并且其壁沿旋转方向延伸 对称体和管（5），其基本上轴向对称地延伸到上部，并且如果适当的话，中间部分用于排出已经没有颗粒的循环气体。 根据本发明，从管（5）的下端向下延伸到旋风分离器中的距离hi的距离hi与向下延伸的管（5）的壁的假想延伸部的交点（6） 中间部分（3b）的壁向下延伸管（5）的直径di为3至8，特别是4至7。