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1.发明授权公开(公告)号：US07268095B2
公开(公告)日：2007-09-11
申请号：US10533945
申请日：2003-11-03
CPC分类号： B01J31/2243 , B01J31/143 , B01J31/1616 , B01J31/1815 , B01J31/2204 , B01J31/2295 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07D277/42 , C07D277/82 , C07F7/003 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F4/64075 , C08F4/64141
摘要： A compound of the formula Ia or Ib; where, in the formula Ia, E1 is O, S, Se, Te, NR, CR2, or PR; E2, E3 are each CR, N, or P; E4 is N, or P; E5 is OH, SH, NHR, OR′, SR′, or NRR′; E6 is NH, PH, NR′, or PR′; R5, R6 are each hydrogen or a linear, branched or cyclic alkyl radical or an aryl radical; R1, R2, R3, R4 are each hydrogen, a linear, branched or cyclic alkyl radical, an aryl radical, a halogen or a nitro group; R is hydrogen, a linear, branched or cyclic alkyl radical; R′ is a linear, branched or cyclic alkyl radical; where at least one of the groups E5 and E6 contains a hydrogen atom; and in the formula Ib, the symbols E1, E4, E5, E6, R5, R6, R1, R2, R3, R4, R and R′ are as defined in formula Ia; and E′2 and E′3 are each O, S, Se, Te, NR, CR2, or PR.
摘要翻译： 式Ia或Ib的化合物; 其中，在式Ia中，E 1是O，S，Se，Te，NR，CR 2或PR; E 2，E 3各自为CR，N或P; E 4是N或P; E 5是OH，SH，NHR，OR'，SR'或NRR'; E 6是NH，PH，NR'或PR'; R 5，R 6各自为氢或直链，支链或环状烷基或芳基; R 1，R 2，R 3，R 4和R 4各自为氢，直链，支链或环状的烷基 自由基，芳基，卤素或硝基; R是氢，直链，支链或环状的烷基; R'是直链，支链或环状的烷基; 其中基团E 5和E 6中的至少一个含有氢原子; 在式Ib中，符号E 1，E 4，E 5，E 6，R 6， R 5，R 6，R 1，R 2，R 3，R 3， R 4和R'如式Ia中所定义; 和E'2和E'3各自各自为O，S，Se，Te，NR，CR 2或PR。
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公开(公告)号：US06846771B2
公开(公告)日：2005-01-25
申请号：US10359263
申请日：2003-02-06
IPC分类号： C07C259/18 , C07F7/00 , C07F7/28 , C07F9/00 , C07F13/00 , C07F15/00 , C07F15/04 , C08F4/602 , C08F4/76 , C08F4/80 , C08F10/00 , C08F12/00 , B01J31/38 , C08F4/44
CPC分类号： C07F13/005 , C07F7/003 , C07F9/005 , C07F15/0066 , C07F15/045 , Y10S526/905
摘要： Complexes of the formulae Ia and Ib where M=Ti, Zr, Hf, V, Nb, Ta, Cr, Ni, Pd, can be used for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译： 其中M = Ti，Zr，Hf，V，Nb，Ta，Cr，Ni，Pd的式Ia和Ib的络合物可用于烯烃的聚合和共聚，例如在悬浮聚合方法中，气相聚合方法 和本体聚合方法。
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公开(公告)号：US06969748B2
公开(公告)日：2005-11-29
申请号：US10961074
申请日：2004-10-12
IPC分类号： C07C259/18 , C07C43/04 , C07C257/22 , C07F15/00 , C07F15/04 , C08F2/00 , C08F4/70 , C08F4/80 , C08F10/00
CPC分类号： C07F15/0066 , C07F15/045
摘要： Complexes of the formula I where M═Ni, Pd; process for preparing the metal complexes and the use of the complexes obtainable in this way for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译： 式I的配合物，其中M-Ni，Pd; 用于制备金属络合物的方法以及以这种方式获得的络合物用于烯烃的聚合和共聚的用途，例如在悬浮聚合方法，气相聚合方法和本体聚合方法中。
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公开(公告)号：US06828454B2
公开(公告)日：2004-12-07
申请号：US10364380
申请日：2003-02-12
IPC分类号： C07F1502
CPC分类号： C07F15/0066 , C07F15/045
摘要： Complexes of the formula I where M═Ni, Pd; process for preparing the metal complexes and the use of the complexes obtainable in this way for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译： 式I的络合物，其中M = Ni，Pd; 用于制备金属络合物的方法以及以这种方式获得的络合物用于烯烃的聚合和共聚的用途，例如在悬浮聚合方法，气相聚合方法和本体聚合方法中。
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公开(公告)号：US06998269B2
公开(公告)日：2006-02-14
申请号：US10359239
申请日：2003-02-06
IPC分类号： G01N31/00
CPC分类号： C08F10/06 , B01J19/0046 , B01J2219/00722 , B01J2219/00738 , C08F4/65912 , C08F4/65916 , C08F110/06 , C40B40/14 , C08F4/65927
摘要： A method of determining the quality of polymerization catalysts comprises a) provision of the catalysts, b) polymerization of a monomer using these catalysts, c) isolation of the polymers obtained in b), d) characterization of the polymers, wherein the method is carried out in an assembly of n vessels in an essentially automated fashion, where the steps a) to d) are all carried out in parallel or are all carried out sequentially or some of the steps a) to d) are carried out in parallel and the remainder are carried out sequentially and n is a natural number greater than or equal to 2.
摘要翻译： 确定聚合催化剂质量的方法
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公开(公告)号：US06683018B1
公开(公告)日：2004-01-27
申请号：US09622211
申请日：2000-08-14
申请人： Marc Oliver Kristen , Laurent Deloux , Peter Kölle , Ulrich Moll , Ursula Rief
发明人： Marc Oliver Kristen , Laurent Deloux , Peter Kölle , Ulrich Moll , Ursula Rief
IPC分类号： B01J3100
CPC分类号： B01J31/1616 , B01J31/2295 , B01J37/0203 , B01J2531/48 , C08F4/61908 , C08F4/61912 , C08F10/00 , C08F210/16 , C08F4/61916 , C08F210/14 , C08F2500/17
摘要： A process for the preparation of a supported catalyst system, an inorganic carrier material being reacted with a metal compound of the formula M1(R1)r(R2)5(R3)t(R4)u I in the presence of an inert solvent in a first step and, in a subsequent step, the suspension thus obtained being reacted with a metallocene complex and a compound forming metallocenium ions, in which process the solvent is not removed after the first step and the subsequent step is carried out without isolation of the pretreated carrier material thus obtained.
摘要翻译： 一种制备负载型催化剂体系的方法，无机载体材料与第一步惰性溶剂的存在下的金属化合物反应，在随后的步骤中，将由此获得的悬浮液与茂金属 络合物和形成金属茂离子的化合物，其中在第一步骤之后不除去溶剂，并且在不分离由此获得的预处理载体材料的情况下进行随后的步骤。
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公开(公告)号：US06359086B1
公开(公告)日：2002-03-19
申请号：US09341517
申请日：1999-07-13
申请人： Marc Oliver Kristen , Patrik Müller , Ulrich Moll , Peter Kölle
发明人： Marc Oliver Kristen , Patrik Müller , Ulrich Moll , Peter Kölle
IPC分类号： C08F442
CPC分类号： B01J31/143 , B01D53/28 , B01J31/12 , B01J31/1616 , B01J31/165 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/61916 , C08F2500/17
摘要： A free-flowing solid which does not self-ignite, comprising: a) at least one support component, b) at least one chemical compound which per se is self-igniting, c) at least one inert liquid and d) further components.
摘要翻译： 一种不自燃的自由流动的固体，包括：a）至少一种载体组分，b）至少一种本身是自燃的化合物，c）至少一种惰性液体，和d）其它组分。
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公开(公告)号：US06946568B2
公开(公告)日：2005-09-20
申请号：US10467169
申请日：2002-02-06
IPC分类号： C07D215/14 , C07C251/24 , C07D207/335 , C07D213/30 , C07F7/00 , C07F9/00 , C08F4/62 , C08F4/625 , C08F4/76 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/44
CPC分类号： C08F10/02 , C07F7/003 , C07F9/005 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2500/17 , C08F210/14 , C08F4/64048 , C08F4/6812
摘要： Complexes of the formulae Ia and Ib where M=Ti, Zr, Hf, V, Nb or Ta, can be used for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译： 其中M = Ti，Zr，Hf，V，Nb或Ta的式Ia和Ib的络合物可用于烯烃的聚合和共聚，例如在悬浮聚合方法，气相聚合方法和本体聚合方法中。
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公开(公告)号：US06812306B2
公开(公告)日：2004-11-02
申请号：US10312880
申请日：2003-01-02
IPC分类号： C08F480
CPC分类号： C08F110/02 , C07F15/006 , C07F15/04 , C08F10/00 , C08F4/80 , C08F2500/03 , C08F4/7016
摘要： Metal compounds of the formula I, where M is selected from among Ni and Pd in the oxidation state +II can be used for the polymerization or copolymerization of olefins. Supported catalysts for the polymerization and copolymerization of olefins can be obtained by application of one or more of the above-described ionic metal compounds to a support.
摘要翻译： 式I的金属化合物，其中M选自氧化态+ II的Ni和Pd可用于烯烃的聚合或共聚。 用于烯烃聚合和共聚的载体催化剂可以通过将一种或多种上述离子金属化合物应用于载体来获得。
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10.发明授权公开(公告)号：US06812305B2
公开(公告)日：2004-11-02
申请号：US10240273
申请日：2002-09-30
申请人： Marc Oliver Kristen , Gerhard Hauck
发明人： Marc Oliver Kristen , Gerhard Hauck
IPC分类号： G08F4602
CPC分类号： C08F110/02 , C08F10/00 , C08F2500/17 , C08F4/7042
摘要： A catalyst system for the polymerization of olefins is prepared by initially charging one or more compounds of the formula I a or I b, subsequently adding a molecularly defined activator of the formulae II a to c [(L—H)]+[(M′)Q1Q2Q3Q4]− II a [(CAr3)]+[(M′)Q1Q2Q3Q4]− II b [(M′)Q1Q2Q3] II c and finally adding an alkylating agent selected from among LiR11, MgR11R12 and AlR12R13R14.
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