公开(公告)号：US5410051A

公开(公告)日：1995-04-25

申请号：US79184

申请日：1993-06-17

申请人： Peter S. Forgione ,  William A. Henderson ,  Balwant Singh ,  Yuhshi Luh

发明人： Peter S. Forgione ,  William A. Henderson ,  Balwant Singh ,  Yuhshi Luh

IPC分类号： C07D251/70 ,  C08F290/14 ,  C08F299/06 ,  C08L75/16 ,  C09D4/06 ,  C09J4/06 ,  C09J175/16 ,  C07D251/54 ,  C07D487/04

CPC分类号： C09J175/16 ,  C07D251/70 ,  C08F290/14 ,  C08F299/06 ,  C08L75/16 ,  C09D4/06 ,  C09J4/06

摘要： Disclosed are novel nitrogen containing heterocyclic compounds and novel vinyl terminated polyurethane/polyamide polymers together with the use of both of these compounds in a novel adhesive and coating composition. The nitrogen containing heterocyclic compounds of the invention contain two vinyl-terminated substituents and at least one carbamylmethyl substituent and have a nucleus selected from melamine, oligomers of melamine, benzoguanamine, and oligomers of benzoguanamine, glycoluril and oligomers of glycoluril, cyclohexylguanamine, oligomers of cyclohexylguanamine, acetoguanamine, and oligomers of acetoguanamine. The vinyl terminated polyurethane compounds of the invention have a molecular weight of from about 3000 to about 80000, and contain at least two vinyl end groups.

摘要翻译： 公开了新颖的含氮杂环化合物和新颖的乙烯基封端的聚氨酯/聚酰胺聚合物，以及在新的粘合剂和涂料组合物中使用这两种化合物。 本发明的含氮杂环化合物含有两个乙烯基封端的取代基和至少一个氨甲酰甲基取代基，并具有选自三聚氰胺，三聚氰胺，苯并胍胺的低聚物，苯并胍胺，甘脲和甘脲的低聚物，环己基胍胺，环己基胍胺的低聚物 ，乙酰胍胺和乙酰胍胺的低聚物。 本发明的乙烯基封端的聚氨酯化合物的分子量为约3000至约80000，并含有至少两个乙烯基端基。

公开(公告)号：US5175201A

公开(公告)日：1992-12-29

申请号：US264661

申请日：1988-10-31

申请人： Peter S. Forgione ,  Yuhshi Luh ,  Balwant Singh ,  William A. Henderson, Jr.

发明人： Peter S. Forgione ,  Yuhshi Luh ,  Balwant Singh ,  William A. Henderson, Jr.

IPC分类号： C07D251/70 ,  C07D521/00 ,  C08F290/00 ,  C08F290/14 ,  C08F299/00 ,  C09D4/06 ,  C09D157/12 ,  C09J4/06 ,  C09J157/12

CPC分类号： C09D4/06 ,  C07D251/70 ,  C08F290/14 ,  C09J4/06 ,  Y10S525/92

摘要： Disclosed are novel nitrogen containing heterocyclic compounds and novel vinyl terminated polyurethane/polyamide polymers together with the use of both of these compounds in a novel adhesive and coating composition. The nitrogen containing heterocyclic compounds of the invention contain two vinyl-terminated substituents and at least one carbamylmethyl substituent and have a nucleus selected from melamine, oligomers of melamine, benzoguanamine, and oligomers of benzoguanamine, glycoluril and oligomers of glycoluril. The vinyl terminated polyurethane compounds of the invention have a molecular weight of from about 3000 to about 80000, and contain at least two vinyl end groups.

公开(公告)号：US5359014A

公开(公告)日：1994-10-25

申请号：US943637

申请日：1992-09-11

申请人： Peter S. Forgione ,  Yuhshi Luh ,  Balwant Singh ,  William A. Henderson, Jr.

发明人： Peter S. Forgione ,  Yuhshi Luh ,  Balwant Singh ,  William A. Henderson, Jr.

IPC分类号： C07D251/70 ,  C07D521/00 ,  C08F290/00 ,  C08F290/14 ,  C08F299/00 ,  C09D4/06 ,  C09D157/12 ,  C09J4/06 ,  C09J157/12 ,  C08L75/16

CPC分类号： C09D4/06 ,  C07D251/70 ,  C08F290/14 ,  C09J4/06 ,  Y10S525/92

摘要： Disclosed are novel nitrogen containing heterocyclic compounds and novel vinyl terminated polyurethane/polyamide polymers together with the use of both of these compounds in a novel adhesive and coating composition. The nitrogen containing heterocyclic compounds of the invention contain two vinyl-terminated substituents and at least one carbamylmethyl substituent and have a nucleus selected from melamine, oligomers of melamine, benzoguanamine, and oligomers of benzoguanamine, glycoluril and oligomers of glycoluril. The vinyl terminated polyurethane compounds of the invention have a molecular weight of from about 3000 to about 80000, and contain at least two vinyl end groups.

摘要翻译： 公开了新颖的含氮杂环化合物和新颖的乙烯基封端的聚氨酯/聚酰胺聚合物，以及在新的粘合剂和涂料组合物中使用这两种化合物。 本发明的含氮杂环化合物含有两个乙烯基封端的取代基和至少一个氨甲酰甲基取代基，并且具有选自三聚氰胺，三聚氰胺的低聚物，苯并胍胺和苯并胍胺，甘脲和甘脲的低聚物的核。 本发明的乙烯基封端的聚氨酯化合物的分子量为约3000至约80000，并含有至少两个乙烯基端基。

公开(公告)号：US4873365A

公开(公告)日：1989-10-10

申请号：US848417

申请日：1986-04-04

申请人： Yuhshi Luh ,  Peter S. Forgione

发明人： Yuhshi Luh ,  Peter S. Forgione

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/14 ,  B01J23/72 ,  C07C67/00 ,  C07C241/00 ,  C07C263/04 ,  C07C265/04 ,  C07C265/10 ,  C07C265/14

CPC分类号： C07C263/04 ,  C07C2101/14

摘要： Isophorone diisocyanate, 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate (IPDI) is prepared by liquid phase thermolysis of the corresponding bis-carbamic acid ester into the corresponding isocyanate and alcohol, respectively, in the presence of a highly selective metal oxide catalyst (SnO.sub.2 and/or CuO). Typically, the cracking reaction is carried out at a temperature from 225.degree. to 350.degree. C., at a pressure of from 20 to 50 mm Hg. These catalysts give high IPDI yields with high conversions of the carbamic acid esters.

公开(公告)号：US4633010A

公开(公告)日：1986-12-30

申请号：US453681

申请日：1982-12-27

申请人： Balwant Singh ,  Peter S. Forgione

发明人： Balwant Singh ,  Peter S. Forgione

IPC分类号： C07C265/14 ,  C07C67/00 ,  C07C241/00 ,  C07C265/08 ,  C07C271/06 ,  C08G18/76 ,  C07C125/077 ,  C07C119/048

CPC分类号： C07C265/00 ,  C08G18/7628

摘要： 1,3,5-Tris(1-isocyanatomethylethyl)benzene is disclosed as a component in coating formulations and the like.

摘要翻译： 公开了1,3,5-三（1-异氰酸基甲基乙基）苯作为涂料配方等中的组分。

公开(公告)号：US4708984A

公开(公告)日：1987-11-24

申请号：US864626

申请日：1986-05-16

申请人： Peter S. Forgione ,  Balwant Singh

发明人： Peter S. Forgione ,  Balwant Singh

IPC分类号： B22C1/20 ,  C07D251/18 ,  C07D251/70 ,  C08G12/26 ,  C08G18/38 ,  C08K5/3492 ,  C08L61/20 ,  C08L61/26 ,  C08F8/30 ,  C08L75/00

CPC分类号： C08K5/3492 ,  B22C1/20 ,  C07D251/18 ,  C07D251/70 ,  C08G12/26 ,  C08G18/3851 ,  Y10T428/31942

摘要： Novel beta-hydroxyalkylcarbamylmethyl aminotriazines function in self-condensation and as crosslinkers for amino resins and also compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, and they can be used as binders for fillers such as insulating glass and foundry sand.

摘要翻译： 新型β-羟基烷基氨基甲酰基甲基氨基三嗪在自缩合中起作用，作为氨基树脂的交联剂以及含有活性氢基团的化合物起作用。 组合物固化成具有优异性能的涂料，并且它们可以用作填料的粘合剂，例如中空玻璃和铸造砂。

公开(公告)号：US4547265A

公开(公告)日：1985-10-15

申请号：US499942

申请日：1983-06-01

申请人： Peter S. Forgione ,  Balwant Singh ,  John A. Sedlak

发明人： Peter S. Forgione ,  Balwant Singh ,  John A. Sedlak

IPC分类号： C08F12/28 ,  D21H17/45 ,  D21H3/48

CPC分类号： C08F12/28 ,  D21H17/45

摘要： A method of sizing paper, comprising applying thereto a sizingly effective amount of a polymer selected from the group consisting of:(a) homopolymers of .alpha.,.alpha.-dimethyl-m-isopropenyl benzyl amine or .alpha.,.alpha.-dimethyl-p-isopropenyl benzyl amine;(b) copolymers of (i) .alpha.,.alpha.-dimethyl-m-isopropenyl benzyl amine or .alpha.,.alpha.-dimethyl-p-isopropenyl benzylamine, and (ii) at least one other ethylenically unsaturated monomer copolymerizable therewith; and(c) acid salts of said homopolymers (a) and copolymers (b).Such homopolymers or copolymers suitably may be prepared as the hydrolysis reaction products of the corresponding homopolymeric or copolymeric isocyanates.

摘要翻译： 一种调整纸张尺寸的方法，其包括施加大小有效量的选自以下的聚合物：（a）α，α-二甲基 - 间 - 异丙烯基苄胺或α，α-二甲基 - 对 - 异丙烯基苄基 胺; （b）（i）α，α-二甲基 - 间 - 异丙烯基苄胺或α，α-二甲基 - 对异丙烯基苄胺的共聚物，和（ii）至少一种可与其共聚的其它烯属不饱和单体; 和（c）所述均聚物（a）和共聚物（b）的酸式盐。 这种均聚物或共聚物可以适当地制备为相应的均聚或共聚异氰酸酯的水解反应产物。

公开(公告)号：US5006653A

公开(公告)日：1991-04-09

申请号：US120285

申请日：1987-11-12

申请人： Peter S. Forgione ,  Balwant Singh

发明人： Peter S. Forgione ,  Balwant Singh

IPC分类号： C07D251/18 ,  C07D251/70 ,  C08K5/3492

CPC分类号： C08K5/3492 ,  C07D251/18 ,  C07D251/70

摘要： Novel alkylcarbamylmethyl aminotriazines self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated polymers, coatings are provided with exceptional resistance to detergent and salt-spray exposure and improved abrasion resistance. The novel aminotriazines also can be combined with fillers as binders which when cured provide shaped articles of manufacture, such as insulation and foundry core molds.

摘要翻译： 新型烷基氨基甲酰基甲基氨基三嗪自固化，也用作含有活性氢基团的化合物的交联剂。 当活性含氢化合物是羟基化聚合物时，涂层具有优异的抗洗涤剂和盐雾暴露性能，并提高耐磨性。 新型氨基三嗪还可以与作为粘合剂的填料结合，当固化时提供成型制品，例如绝缘和铸造芯模。

公开(公告)号：US4439616A

公开(公告)日：1984-03-27

申请号：US400799

申请日：1982-07-22

申请人： Balwant Singh ,  Laurence W. Chang ,  Peter S. Forgione

发明人： Balwant Singh ,  Laurence W. Chang ,  Peter S. Forgione

IPC分类号： C07C263/04 ,  B05D7/26 ,  C07C67/00 ,  C07C239/00 ,  C07C241/00 ,  C07C265/00 ,  C07C265/08 ,  C07C265/14 ,  C07C269/02 ,  C07C269/06 ,  C07C271/06 ,  C07C271/10 ,  C08G18/76 ,  C07C125/073 ,  C07C125/065

CPC分类号： C08G18/765 ,  C07C263/04

摘要： Production of tertiary aralkyl isocyanates, such as tetramethyl xylylene diisocyanates, by thermal cracking of corresponding urethanes formed by addition of corresponding olefins and carbamic acid esters at moderate temperatures and in the presence of acid catalyst.

摘要翻译： 通过在中等温度和酸催化剂的存在下通过加入相应的烯烃和氨基甲酸酯形成的相应的聚氨酯的热裂解，生产叔芳烷基异氰酸酯，如四甲基亚二甲苯基二异氰酸酯。

公开(公告)号：US5089617A

公开(公告)日：1992-02-18

申请号：US120570

申请日：1987-11-13

申请人： Peter S. Forgione ,  Balwant Singh

发明人： Peter S. Forgione ,  Balwant Singh

IPC分类号： B22C1/20 ,  C07D251/18 ,  C07D251/70 ,  C08G12/26 ,  C08G18/38 ,  C08K5/3492

CPC分类号： C07D251/18 ,  B22C1/20 ,  C07D251/70 ,  C08G12/26 ,  C08G18/3851 ,  C08K5/3492

摘要： Novel beta-hydroxyalkylcarbamylmethyl aminotriazines function in self-condensation and as cross-linkers for amino resins and also compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, and they can be used as binders for fillers such as insulating glass and foundry sand.

摘要翻译： 新型β-羟基烷基氨基甲酰基甲基氨基三嗪在自缩合中起作用，作为氨基树脂的交联剂和含有活性氢基团的化合物起作用。 组合物固化成具有优异性能的涂料，并且它们可以用作填料的粘合剂，例如中空玻璃和铸造砂。