Method for the preparation of an improved photographic tabular emulsion
rich in chloride
    2.
    发明授权
    Method for the preparation of an improved photographic tabular emulsion rich in chloride 失效
    用于制备富含氯化物的改进的照相片状乳液的方法

    公开(公告)号:US5885763A

    公开(公告)日:1999-03-23

    申请号:US956362

    申请日:1997-10-23

    摘要: A method is disclosed of preparing of a photographic silver halide emulsion comprising precipitating in one or more precipitation steps in a reaction vessel, followed by desalting by means of flocculation and washing or by means of ultrafiltration, said emulsion comprising gelatin as a binder and {100} tabular silver halide grains containing at least 50 mole % of chloride, wherein at least 40% by number of all grains is provided by said tabular grains, and wherein said tabular grains exhibit an average aspect ratio of at least 2, an average thickness of at most 0.5 .mu.m, and an average equivalent circular crystal diameter of 0.3 .mu.m or more, characterized in that during said precipitation step(s) said gelatin binder present in said reaction vessel is substantially free of calcium ions and is oxidized to a degree in order to have a methionine content of at most 4000 ppm.

    摘要翻译: 公开了一种制备照相卤化银乳剂的方法,其包括在反应容器中的一个或多个沉淀步骤中沉淀,然后通过絮凝和洗涤或通过超滤脱盐,所述乳液包含明胶作为粘合剂和{100 }含有至少50摩尔%氯化物的片状卤化银颗粒,其中由所述片状颗粒提供至少40%的全部颗粒,并且其中所述片状颗粒的平均纵横比至少为2,平均厚度为 至多0.5μm,平均当量圆形结晶直径为0.3μm以上,其特征在于,在所述沉淀步骤中,存在于所述反应容器中的所述明胶粘合剂基本上不含钙离子并被氧化至一定程度 以使甲硫氨酸含量在4000ppm以下。

    NEGATIVE WORKING, HEAT SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR
    5.
    发明申请
    NEGATIVE WORKING, HEAT SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR 有权
    负极工作,感光感光印刷机

    公开(公告)号:US20090258314A1

    公开(公告)日:2009-10-15

    申请号:US12300805

    申请日:2007-05-22

    IPC分类号: G03F7/004 G03F7/20 B41F1/18

    摘要: A heat-sensitive negative-working lithographic printing plate precursor include a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye; wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm; the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.80 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fraction; and—the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60-%.

    摘要翻译: 热敏负性平版印刷版原版包括具有亲水性表面的或具有亲水层的涂层和设置在其上的涂层的涂层,该涂层包括图像记录层,该图像记录层包括疏水性热塑性聚合物颗粒,粘合剂, 和红外吸收染料; 其中所述疏水热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40nm; 通过流体力学分数测量,不考虑任选的抗衡离子的IR染料的量大于0.80mg / m 2热塑性聚合物颗粒的总表面; 和 - 相对于成像层的成分的总重量,疏水性热塑性聚合物颗粒的量为至少60%。

    METHOD FOR MAKING A LITHOGRAPHIC PRINTING PLATE
    6.
    发明申请
    METHOD FOR MAKING A LITHOGRAPHIC PRINTING PLATE 有权
    制作平版印刷版的方法

    公开(公告)号:US20090155722A1

    公开(公告)日:2009-06-18

    申请号:US12300801

    申请日:2007-05-22

    IPC分类号: G03F7/20 B41M5/00

    摘要: A method for making a lithographic printing plate includes the steps of (i) providing a negative-working, heat-sensitive lithographic printing plate precursor including a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye, wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm, and the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.70 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fractionation, and the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60%; (ii) exposing the precursor to infrared light; and (iii) developing the exposed precursor in an alkaline aqueous solution.

    摘要翻译: 制备平版印刷版的方法包括以下步骤:(i)提供负型热敏平版印刷版原版,其包含具有亲水性表面的载体,或提供有亲水层和设置在其上的涂层, 包括包含疏水性热塑性聚合物颗粒,粘合剂和红外吸收染料的图像记录层的涂层,其中所述疏水性热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40 nm,并且不考虑任选的抗衡离子的IR染料的量通过流体动力学分级测定的每摩尔热塑性聚合物颗粒的总表面的每摩尔浓度大于0.70mg,并且疏水性热塑性聚合物颗粒的量 相对于成像层的成分的总重量为至少60%; (ii)将前体暴露于红外光; 和(iii)在碱性水溶液中显影暴露的前体。

    Layer configuration with improved stability to sunlight exposure
    8.
    发明授权
    Layer configuration with improved stability to sunlight exposure 有权
    层状结构具有改善的阳光照射的稳定性

    公开(公告)号:US07147936B2

    公开(公告)日:2006-12-12

    申请号:US10642933

    申请日:2003-08-18

    IPC分类号: C07D211/021 H01L51/50

    摘要: A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH  (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH  (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.

    摘要翻译: 在支撑体上的层构型,该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层,其中两个烷氧基可以相同或不同,或一起代表任选取代的氧基 - 桥,以及选自多磷酸,多磷酸盐,硫杂烷二羧酸,环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物:四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物,根据式(I)的化合物:<?in-line-formula description =“In-line formula”end =“lead”?> HO-CH 2 -CH(OH) - (CH 2 CH 2)m -S- CH 2 -C(R 1) (R 2) - CH 2 -S-(CH 2)n - (CH 2)n - (CH 2) -CH 2 -O-OH(I)<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2, SUP> 2独立地是H,-OH或烷基,n和m独立地是1,2或3; 根据式(II)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?> HO-(CH 2) > -S-CH 2 -S-(CH 2)2 -O-OH(II)<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式(I)的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

    Preparation of ZNS particles doped with copper
    10.
    发明授权
    Preparation of ZNS particles doped with copper 失效
    掺杂铜的ZNS颗粒的制备

    公开(公告)号:US06787064B2

    公开(公告)日:2004-09-07

    申请号:US10050317

    申请日:2002-01-16

    IPC分类号: C09K1156

    CPC分类号: C09K11/584

    摘要: An improved method for the preparation of a dispersion of ZnS particles doped with copper is disclosed. The method comprises the step of performing a precipitation by mixing together a zinc salt, a sulfide, and a citrate or EDTA complex of copper ions, dissolved in several aqueous solutions. Enhanced luminescence is obtained.

    摘要翻译: 公开了一种用于制备掺杂有铜的ZnS颗粒的分散体的改进方法。 该方法包括通过将溶解在几种水溶液中的锌盐,硫化物和铜离子的柠檬酸盐或EDTA络合物混合在一起来进行沉淀的步骤。 获得增强的发光。