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公开(公告)号：US5073655A
公开(公告)日：1991-12-17
申请号：US559242
申请日：1990-07-27
CPC分类号： B01J29/04 , C07C2/12 , C07C2529/70
摘要： Diarylalkanes are prepared by alkylating an aromatic hydrocarbon with an aromatic alkylation agent in the presence of a synthetic porous crystalline material catalyst composition. The aromatic hydrocarbon can be, for example, benzene, toluene, naphthalene, etc. The aromatic alkylating agent can be an aromatic compound with a hydroxy group, such as phenol, or benzyl alcohol, or an aromatic halide, aldehyde, ether, or an aromatic olefin such as styrene.
摘要翻译： 二芳基烷烃通过在合成的多孔结晶材料催化剂组合物的存在下用芳族烷基化剂烷基化芳族烃来制备。 芳族烃可以是例如苯，甲苯，萘等。芳族烷基化剂可以是具有羟基的芳香族化合物，例如苯酚或苄醇，或芳族卤化物，醛，醚或 芳族烯烃如苯乙烯。
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公开(公告)号：US5001295A
公开(公告)日：1991-03-19
申请号：US494203
申请日：1990-03-15
CPC分类号： C07C2/12 , B01J29/04 , C07C2529/70
摘要： A catalytic process is provided for the preparation of dialkylnaphthalenes by alkylating a 2-alkylnaphthalene with an alkylating agent having an aliphatic group of from one to five carbon atoms, such as methanol. The catalyst comprises a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 提供了通过用具有1至5个碳原子的脂族基团如甲醇的烷基化烷基化2-烷基萘来制备二烷基萘的催化方法。 该催化剂包括合成沸石，其特征在于X射线衍射图包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83±0.14,6.18±0.12,6.00±0.10， 4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US4982040A
公开(公告)日：1991-01-01
申请号：US454481
申请日：1989-12-21
CPC分类号： C07C6/123 , B01J29/04 , C07C2/12 , C07C2529/06 , C07C2529/70
摘要： A methylnaphthalene such as 2-methylnaphthalene undergoes catalytic disproportionation to naphthalene and a mixture of dimethylnaphthalene isomers, preferably containing substantial quantities of 2,6-dimethylnaphthalene, employing catalyst comprising zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 使用包含沸石的催化剂，其特征在于X射线衍射图包括12.36+的平面d间距，甲基萘如2-甲基萘经历催化歧化萘和二甲基萘异构体的混合物，优选含有大量的2,6-二甲基萘， /-0.4,11.03 +/- 0.2,8.83±0.14 6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US4992606A
公开(公告)日：1991-02-12
申请号：US469998
申请日：1990-01-25
CPC分类号： C07C2/12 , B01J29/04 , C07C2529/06 , C07C2529/70
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under alkylation reaction conditions in the presence of catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 通过在烷基化反应条件下，在催化剂存在下，在烷基化反应条件下，使烷基化芳族化合物与相对短链烷基化剂进行烷基化，制备相对短链烷基芳族化合物，所述催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括在 12.36 +/- 0.4,11.03 +/- 0.2,8.83±0.14 6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US4954663A
公开(公告)日：1990-09-04
申请号：US470015
申请日：1990-01-25
CPC分类号： C07C2/12 , B01J29/04 , C07C2529/06 , C07C2529/70
摘要： Long chain alkyl phenols are prepared by alkylating an alkylatable phenolic compound with a long chain alkylating agent under alkylation reaction conditions in the presence of catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07; 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 长链烷基酚通过在烷基化反应条件下在烷基化反应条件下在催化剂存在下烷基化制备，所述催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括在12.36±/ -0.4,11.03 +/- 0.2,8.83±0.14,6.18±0.12,6.00±0.10,4.06±0.07; 3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US5063038A
公开(公告)日：1991-11-05
申请号：US91612
申请日：1987-08-31
申请人： Garry W. Kirker , Donald J. Klocke , James C. Vartuli , Pochen Chu , David O. Marler , John P. McWilliams
发明人： Garry W. Kirker , Donald J. Klocke , James C. Vartuli , Pochen Chu , David O. Marler , John P. McWilliams
CPC分类号： C07C4/18 , B01J29/40 , B01J29/65 , B01J29/7046 , C01B39/48 , C07C2/66 , B01J2229/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/65 , C07C2529/70 , Y10S423/35 , Y10S423/36
摘要： There is provided a method for preparing a zeolite other than ZSM-5 from a reaction mixture comprising a mixed organic directing agent which is a combination of (a) an organic nitrogen containing compound such as an amine or a quaternary ammonium compound and (b) an alcohol and/or diol. Particular zeolites synthesized by this method include ZSM-22 and ZSM-23. The use of an alcohol or a diol may inhibit the coformation of ZSM-5. Especially when used to prepare ZSM-23, this method enables the preparation of more catalytically active ZSM-23 of reduced crystallite size and also enables the use of lower crystallization temperatures. Particular mixed organic directing agents for the preparation of ZSM-23 are combination of (a) pyrrolidine and (b) ethanol or ethylene glycol. Other factors which enhance the activity of ZSM-23 include the use of the following in the reaction mixtures for preparing ZSM-23: potassium ions; precipitated silica particles as sources of silica; and spray dried precipitated silica/alumina particles as sources of silica and alumina. The catalytic stability of alumina bound ZSM-23 catalysts is especially enhanced by steaming. Particular reactions which can be catalyzed by ZSM-23 made according to methods described herein include the dealkylation of ethylbenzene and the alkylation of benzene with ethylene.
摘要翻译： 提供了一种从含有（a）有机氮化合物如胺或季铵化合物的组合的混合有机导向剂的反应混合物制备ZSM-5以外的沸石的方法，（b） 醇和/或二醇。 通过该方法合成的特定沸石包括ZSM-22和ZSM-23。 使用醇或二醇可能会抑制ZSM-5的共形。 特别是当用于制备ZSM-23时，该方法能够制备更小的微晶尺寸的更具催化活性的ZSM-23，并且还能够使用较低的结晶温度。 用于制备ZSM-23的特殊混合有机导向剂是（a）吡咯烷和（b）乙醇或乙二醇的组合。 提高ZSM-23活性的其他因素包括在制备ZSM-23：钾离子的反应混合物中使用以下物质： 沉淀二氧化硅颗粒作为二氧化硅来源; 和喷雾干燥的沉淀二氧化硅/氧化铝颗粒作为二氧化硅和氧化铝的来源。 氧化铝结合的ZSM-23催化剂的催化稳定性通过蒸汽特别提高。 根据本文所述方法制备的可以由ZSM-23催化的特定反应包括乙苯的脱烷基化和苯与乙烯的烷基化。
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公开(公告)号：US4885426A
公开(公告)日：1989-12-05
申请号：US327378
申请日：1989-03-23
申请人： Yung F. Chu , David O. Marler , John P. McWilliams
发明人： Yung F. Chu , David O. Marler , John P. McWilliams
IPC分类号： C07C6/12
CPC分类号： C07C6/126 , C07C2529/40
摘要： A process is provided for transalkylation of polyalkylaromatics over a catalyst comprising a molecular sieve having a high lattice aluminum content whereby its silica/alumina mole ratio is less than 40 and an alpha value of at least about 140.
摘要翻译： 提供了一种方法，用于在包含具有高格子铝含量的分子筛的催化剂上进行多烷基芳族化合物的烷基转移，由此其二氧化硅/氧化铝摩尔比小于40，α值至少为约140。
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公开(公告)号：US5157185A
公开(公告)日：1992-10-20
申请号：US402018
申请日：1989-09-01
申请人： Yung F. Chu , David O. Marler , John P. McWilliams
发明人： Yung F. Chu , David O. Marler , John P. McWilliams
CPC分类号： C07C2/66 , B01J29/40 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/40
摘要： Alkylation of aromatics, e.g. ethylbenzene preparation, with minimized o-xylene make by contacting with olefin alkylating agent in the presence of ZSM-5 crystals having a diffusion rate constant of at least about 100 sec.sup.-1 .times.10.sup.-6 and an alpha value of less than about 100 prepared from a non-organic forming mixture comprising a silica source of precipitated silica having a particle size of 1 to 500 microns.
摘要翻译： 芳族化合物的烷基化，例如 乙基苯制备，通过在烯烃烷基化剂与ZSM-5晶体的存在下使烷基化反应最小化，所述ZSM-5晶体的扩散速率常数为至少约100秒-1×10-6，α值小于约100，由 非有机形成混合物，其包含粒度为1至500微米的沉淀二氧化硅的二氧化硅源。
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公开(公告)号：US5072054A
公开(公告)日：1991-12-10
申请号：US560401
申请日：1990-07-31
IPC分类号： B01J29/04 , C07C2/12 , C07C2/66 , C07C37/14 , C07C51/347
CPC分类号： C07C51/347 , B01J29/04 , C07C2/12 , C07C2/66 , C07C37/14 , C07C2529/06 , C07C2529/70
摘要： Short-chain alkyl phenols are prepared by reacting an alkylatable phenolic compound with an alkylating agent having one or more available alkylating aliphatic groups of from one to five carbon atoms. The reaction is carried out under alkylation conditions with a zeolite catalyst characterized by x-ray diffraction values as set forth in Tables A to D, infra.
摘要翻译： 通过使可烷基化的酚化合物与具有一个或多个可用的1-5个碳原子的烷基化脂肪族基团的烷基化剂反应来制备短链烷基酚。 反应在烷基化条件下进行，沸石催化剂的特征在于如下表A至D所示的X射线衍射值。
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10.发明授权
公开(公告)号：US5254322A
公开(公告)日：1993-10-19
申请号：US927108
申请日：1992-08-10
IPC分类号： F01N3/24 , B01D53/56 , B01D53/86 , B01D53/94 , B01J29/40 , B01J29/44 , B01J29/46 , B01J29/48 , B01J8/00 , B01D47/00 , C01B21/00
CPC分类号： B01J29/46 , B01D53/9418 , B01J29/40 , B01D2251/208 , B01D2255/204 , B01D2255/20761 , B01D2255/504 , Y02T10/24
摘要： A method is provided for reducing NO.sub.x for high flow applications such as NO.sub.x abatement in an exhaust gas from an internal combustion engine operating under lean burn conditions wherein NO.sub.x is reduced by hydrocarbon reductants. The method employs a hydrothermally stable catalyst comprising transition metal-containing ZSM-5 which is prepared by in-situ crystallization of an aggregate comprising ZSM-5 seeds, silica, and a crystalline silicate.
摘要翻译： 提供了一种用于减少用于高流量应用的NOx的方法，例如来自在贫燃条件下运行的内燃机的废气中的NOx的减少，其中NOx由烃还原剂还原。 该方法采用包含含过渡金属的ZSM-5的水热稳定催化剂，其通过包含ZSM-5种子，二氧化硅和结晶硅酸盐的骨料的原位结晶而制备。
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