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    Carbon-Coated Fluoride-Based Nanomaterials for Anode Applications
    3.
    发明申请
    Carbon-Coated Fluoride-Based Nanomaterials for Anode Applications 审中-公开
    基于碳涂层氟化物的纳米材料用于阳极应用

    公开(公告)号：US20100129713A1

    公开(公告)日：2010-05-27

    申请号：US12574530

    申请日：2009-10-06

    申请人： Rachid Yazami ,  Cedric M. Weiss

    发明人： Rachid Yazami ,  Cedric M. Weiss

    IPC分类号： H01M4/62

    CPC分类号： H01M4/62 ,  H01M4/136 ,  H01M4/366 ,  H01M4/582 ,  H01M10/05 ,  H01M10/052

    摘要： Electrodes for use in electrochemical cells are provided. The electrode may include a plurality of fluoride-based nanomaterials including calcium or magnesium, wherein a carbon-based film is deposited onto at least some of the nanomaterials. Electrochemical cells comprising the electrodes of the invention are also provided; the electrodes of the invention may act as the negative electrode of the cell.

    摘要翻译： 提供了用于电化学电池的电极。 电极可以包括多种基于氟化物的纳米材料，包括钙或镁，其中碳基膜沉积在至少一些纳米材料上。 还提供包含本发明电极的电化学电池; 本发明的电极可以充当电池的负电极。

    Fluoride ion electrochemical cell
    5.
    发明授权
    Fluoride ion electrochemical cell 有权
    氟离子电化学电池

    公开(公告)号：US08377586B2

    公开(公告)日：2013-02-19

    申请号：US11681493

    申请日：2007-03-02

    申请人： Rachid Yazami

    发明人： Rachid Yazami

    IPC分类号： H01M6/04 ,  H01M4/13

    CPC分类号： H01M10/0567 ,  H01M4/38 ,  H01M4/582 ,  H01M4/583 ,  H01M4/5835 ,  H01M4/60 ,  H01M4/604 ,  H01M4/606 ,  H01M4/608 ,  H01M6/04 ,  H01M6/045 ,  H01M6/166 ,  H01M10/04 ,  H01M10/0561 ,  H01M10/0568 ,  H01M10/08 ,  H01M10/22 ,  H01M10/26 ,  H01M10/36 ,  H01M2300/0002 ,  H01M2300/0017 ,  Y02E60/12

    摘要： The present invention provides electrochemical cells capable of good electronic performance, particularly high specific energies, useful discharge rate capabilities and good cycle life. Electrochemical cells of the present invention are versatile and include primary and secondary cells useful for a range of important applications including use in portable electronic devices. Electrochemical cells of the present invention also exhibit enhanced safety and stability relative to conventional state of the art primary lithium batteries and lithium ion secondary batteries. For example, electrochemical cells of the present invention include secondary electrochemical cells using anion charge carriers capable of accommodation by positive and negative electrodes comprising anion host materials, which entirely eliminate the need for metallic lithium or dissolved lithium ion in these systems.

    摘要翻译： 本发明提供能够具有良好的电子性能，特别高的比能，有用的放电速率能力和良好的循环寿命的电化学电池。 本发明的电化学电池是通用的，并且包括可用于一系列重要应用的一次和二次电池，包括用于便携式电子设备中。 本发明的电化学电池相对于现有技术的一次锂电池和锂离子二次电池也表现出增强的安全性和稳定性。 例如，本发明的电化学电池包括使用能够由包括阴离子主体材料的正极和负极调节的阴离子电荷载体的二次电化学电池，其完全不需要这些系统中的金属锂或溶解的锂离子。

    METHODS FOR PURIFYING CARBON MATERIALS
    6.
    发明申请
    METHODS FOR PURIFYING CARBON MATERIALS 审中-公开
    净化碳材料的方法

    公开(公告)号：US20100074832A1

    公开(公告)日：2010-03-25

    申请号：US12435877

    申请日：2009-05-05

    申请人： Anne Dailly ,  Channing Ahn ,  Rachid Yazami ,  Brent T. Fultz

    发明人： Anne Dailly ,  Channing Ahn ,  Rachid Yazami ,  Brent T. Fultz

    IPC分类号： D01F9/12

    CPC分类号： D01F11/127 ,  B82Y30/00 ,  C01B32/05 ,  C01B32/215 ,  D06M11/83 ,  D06M2101/40

    摘要： Methods of purifying samples are provided that are capable of removing carbonaceous and noncarbonaceous impurities from a sample containing a carbon material having a selected structure. Purification methods are provided for removing residual metal catalyst particles enclosed in multilayer carbonaceous impurities in samples generate by catalytic synthesis methods. Purification methods are provided wherein carbonaceous impurities in a sample are at least partially exfoliated, thereby facilitating subsequent removal of carbonaceous and noncarbonaceous impurities from the sample. Methods of purifying carbon nanotube-containing samples are provided wherein an intercalant is added to the sample and subsequently reacted with an exfoliation initiator to achieve exfoliation of carbonaceous impurities.

    摘要翻译： 提供了能够从含有选定结构的碳材料的样品中除去含碳杂质和非碳质杂质的样品的提纯方法。 提供了净化方法，用于除去通过催化合成方法产生的样品中包围在多层含碳杂质中的残余金属催化剂颗粒。 提供了纯化方法，其中样品中的碳质杂质至少部分地被剥离，从而有助于随后从样品中除去碳质和非碳质杂质。 提供了含有碳纳米管的样品的纯化方法，其中将插入剂加入到样品中，随后与剥离引发剂反应以实现含碳杂质的剥离。

    DISSOCIATING AGENTS, FORMULATIONS AND METHODS PROVIDING ENHANCED SOLUBILITY OF FLUORIDES
    7.
    发明申请
    DISSOCIATING AGENTS, FORMULATIONS AND METHODS PROVIDING ENHANCED SOLUBILITY OF FLUORIDES 有权
    提供增强氟化物溶解性的分散剂，配方和方法

    公开(公告)号：US20080171268A1

    公开(公告)日：2008-07-17

    申请号：US11837004

    申请日：2007-08-10

    申请人： Rachid Yazami

    发明人： Rachid Yazami

    IPC分类号： H01M6/04

    CPC分类号： H01M10/0567 ,  H01M4/583 ,  H01M4/5835 ,  H01M6/168 ,  H01M10/052

    摘要： The present invention provides compositions, formulations and methods providing for the effective dissolution of inorganic fluorides in solvents via incorporation of a dissociating agent component. Dissociating agents of the present invention participate in chemical reactions in solution, such as complex formation, acid-base reactions, and adduct formation reactions, that result in enhancement in the dissolution of inorganic fluorides in a range of solvent environments. Dissociating agents comprising Lewis acids, Lewis bases, anion receptors, cation receptors or combinations thereof are provided that significantly increase the extent of dissolution of a range of inorganic fluorides, particularly inorganic fluorides, such as LiF, that are highly insoluble in many solvents in the absence of the dissociating agents of the present invention.

    摘要翻译： 本发明提供组合物，制剂和方法，其通过并入解离剂组分提供无机氟化物在溶剂中的有效溶解。 本发明的离解剂参与溶液中的化学反应，例如复合物形成，酸碱反应和加合物形成反应，其导致无机氟化物在一系列溶剂环境中的溶解的增强。 提供了包含路易斯酸，路易斯碱，阴离子受体，阳离子受体或其组合的解离剂，其显着增加一系列无机氟化物，特别是无机氟化物如LiF的溶解程度，其在 不存在本发明的离解剂。

    Methods for thermodynamic evaluation of battery state of health
    9.
    发明授权
    Methods for thermodynamic evaluation of battery state of health 有权
    电池状态的热力学评估方法

    公开(公告)号：US08446127B2

    公开(公告)日：2013-05-21

    申请号：US12537712

    申请日：2009-08-07

    申请人： Rachid Yazami ,  Joseph McMenamin ,  Yvan Reynier ,  Brent T. Fultz

    发明人： Rachid Yazami ,  Joseph McMenamin ,  Yvan Reynier ,  Brent T. Fultz

    IPC分类号： H02J7/04

    CPC分类号： H02J7/007 ,  G01R31/3606 ,  G01R31/3679 ,  H01M10/052 ,  H01M10/443 ,  H01M10/48 ,  H01M10/486 ,  H01M10/657 ,  H01M10/6571 ,  H01M10/6572 ,  Y02E60/12

    摘要： Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

    摘要翻译： 描述了用于精确表征电极和电池系统的热力学和材料性质以及用于表征电极和电池系统的健康状态的系统和方法。 对与热力学稳定的电极条件相对应的电极和电池的物理属性的测量允许确定热力学参数，包括诸如吉布斯自由能，电极/电化学电池反应的焓和熵等状态函数，能够预测电极材料的重要性能属性 和电池系统，如能量，功率密度，当前速率，循环寿命和健康状况。 还提供了根据其健康状况对电池充电的系统和方法。