-
公开(公告)号：US20120193296A1
公开(公告)日：2012-08-02
申请号：US13017417
申请日：2011-01-31
IPC分类号： C02F1/52
CPC分类号： C02F1/5236 , C02F2101/12 , C02F2101/14 , C02F2101/20 , C02F2103/10 , C02F2209/06
摘要： A process for treating acid mine drainage containing heavy metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the acid mine drainage at a pre-select pH to form insoluble heavy metal complexes. In one embodiment, the metal cation is a trivalent metal ion, e.g., ferric iron such as in ferric sulfate. In another embodiment, a divalent metal ion such as in ferrous sulfate is used. After the removal of the heavy metal complexes, the effluent water is treated with at least a phosphate additive to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants.
摘要翻译： 提供了一种处理含有重金属和可溶性污染物的酸性矿井排水的方法。 在一个实施方案中，至少一种金属阳离子以预先选择的pH添加到酸性矿井排水中以形成不溶性重金属络合物。 在一个实施方案中，金属阳离子是三价金属离子，例如三价铁，例如硫酸铁。 在另一个实施方案中，使用二价金属离子如硫酸亚铁。 在去除重金属络合物之后，用至少一种磷酸盐添加剂处理流出水以除去剩余的可溶性污染物，从而产生具有降低的污染物水平的处理水流。
-
公开(公告)号：US08834725B2
公开(公告)日：2014-09-16
申请号：US13017417
申请日：2011-01-31
IPC分类号： B01D21/01 , B03D3/00 , C02F1/52 , B01D37/00 , B01D61/00 , C02F1/00 , B01D12/00 , B01D17/00 , B01D43/00 , C02F103/10 , C02F101/12 , C02F101/20 , C02F101/14
CPC分类号： C02F1/5236 , C02F2101/12 , C02F2101/14 , C02F2101/20 , C02F2103/10 , C02F2209/06
摘要： A process for treating acid mine drainage containing heavy metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the acid mine drainage at a pre-select pH to form insoluble heavy metal complexes. In one embodiment, the metal cation is a trivalent metal ion, e.g., ferric iron such as in ferric sulfate. In another embodiment, a divalent metal ion such as in ferrous sulfate is used. After the removal of the heavy metal complexes, the effluent water is treated with at least a phosphate additive to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants.
摘要翻译： 提供了一种处理含有重金属和可溶性污染物的酸性矿井排水的方法。 在一个实施方案中，至少一种金属阳离子以预先选择的pH添加到酸性矿井排水中以形成不溶性重金属络合物。 在一个实施方案中，金属阳离子是三价金属离子，例如三价铁，例如硫酸铁。 在另一个实施方案中，使用二价金属离子如硫酸亚铁。 在去除重金属络合物之后，用至少一种磷酸盐添加剂处理流出水以除去剩余的可溶性污染物，从而产生具有降低的污染物水平的处理水流。
-
公开(公告)号：US08815184B2
公开(公告)日：2014-08-26
申请号：US13156589
申请日：2011-06-09
IPC分类号： C01G37/14
CPC分类号： C22B34/345 , C22B7/009 , C22B23/026 , C22B23/0446 , C22B34/225 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals.
摘要翻译： 提供了一种处理含有重金属的废催化剂的方法，例如VIB族金属和VIII族金属。 在脱油后的一个实施方案中，在足以将VIB族金属和VIII族金属溶解到浸出溶液中的条件下，用氨浸出溶液处理废催化剂，形成浸出浆料。 在固液分离回收浸出溶液后，进行化学沉淀和固体再浆化，得到含有硫酸铵（Amsul），氨基磺酸铵，VB族，VIB族和VIII族金属的流出物流。 硫化后，完全除去第Ⅷ族金属，并从Amsul流部分除去VB族和VI族金属。 在氧解溶解和铁沉淀的附加步骤中，加入预选择pH下的有效量的铁离子以与VB族和VIB族金属组合形成不溶性络合物，其在液固分离时产生流出的硫酸铵流，其含有 VB族和VIB族金属中的每一种都少于10ppm。
-
公开(公告)号：US20140251914A1
公开(公告)日：2014-09-11
申请号：US13787977
申请日：2013-03-07
IPC分类号： C02F9/00
CPC分类号： C02F9/00 , C02F1/442 , C02F1/5245 , C02F1/56 , C02F1/66 , C02F1/683 , C02F2001/007 , C02F2101/103 , C02F2101/20 , C02F2101/206 , C02F2103/10
摘要： A process for treating acid mine drainage containing heavy and base metals and soluble contaminants is provided. In one embodiment, at least a metal cation is added to the acid mine drainage at a pre-select pH to form insoluble heavy and base metal complexes. After the removal of the heavy and base metal complexes, the pH is raised to the alkaline range. Following removal of base metal hydroxides and gypsum, membrane filtration is employed to generate a treated membrane permeate having a reduced concentration of heavy and base metals and soluble contaminants, and a membrane reject stream containing a concentrated brine. The concentrated brine is further treated with additional lime and at least an aluminum salt to remove remaining soluble contaminants, thus producing a treated water stream with reduced levels of contaminants. Carbonation with CO2 is employed at the end of the process to neutralize flows and further precipitate residual aluminum and calcium salts.
摘要翻译： 提供了一种处理含有重金属和贱金属和可溶性污染物的酸性矿井排水的方法。 在一个实施方案中，至少一种金属阳离子以预先选择的pH添加到酸性矿井排水中以形成不溶性重和碱金属络合物。 去除重金属和碱金属络合物后，将pH提高至碱性范围。 在除去碱金属氢氧化物和石膏之后，使用膜过滤产生具有降低的重质和碱金属和可溶性污染物浓度的处理过的膜渗透物，以及含有浓缩盐水的膜排出流。 浓缩的盐水进一步用额外的石灰和至少一种铝盐处理以除去残留的可溶性污染物，从而产生具有降低的污染物水平的处理水流。 在过程结束时采用碳酸化方法中和流动，进一步沉淀出残留的铝和钙盐。
-
5.发明授权Recovery of vanadium from petroleum coke slurry containing solubilized base metals 有权从含有溶解的贱金属的石油焦浆中回收钒公开(公告)号：US08815185B1
公开(公告)日：2014-08-26
申请号：US13784325
申请日：2013-03-04
CPC分类号： C22B34/225 , Y02P10/23 , Y02P10/234
摘要： A method for recovering vanadium from a spent slurry catalyst for hydrocarbon oil hydroprocessing is disclosed. In one embodiment after de-oiling, the spent catalyst is treated with ammonia and air, forming a leach slurry. The leach slurry is subsequently treated with a flocculant. After solid-liquid separation to recover the solid residue containing coke and ammonium metavanadate, the solid residue is washed with an ammonium sulfate solution and leached with hot water. After solid-liquid separation to recover a solution containing ammonium metavanadate, the ammonium metavanadate is crystallized and purified from the leach solution.
摘要翻译： 公开了一种从用于烃油加氢处理的废浆催化剂中回收钒的方法。 在脱油后的一个实施方案中，用氨和空气处理废催化剂，形成浸出浆料。 随后用絮凝剂处理浸出浆料。 固液分离后，回收含有焦炭和偏钒酸铵的固体残渣，固体残渣用硫酸铵溶液洗涤，用热水浸出。 在固液分离以回收含偏钒酸铵的溶液之后，将偏钒酸铵从浸出溶液中结晶并纯化。
-
公开(公告)号：US20120172202A1
公开(公告)日：2012-07-05
申请号：US13331341
申请日：2011-12-20
申请人： Oleg Mironov , Alexander E. Kuperman , Rahul Shankar Bhaduri , Julie Chabot , Shuwu Yang , Joseph V. Nguyen , Ling Jiao , Bruce Edward Reynolds
发明人： Oleg Mironov , Alexander E. Kuperman , Rahul Shankar Bhaduri , Julie Chabot , Shuwu Yang , Joseph V. Nguyen , Ling Jiao , Bruce Edward Reynolds
IPC分类号： B01J31/02
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： A process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a pressure leach solution obtained from a metal recovery process as part of the metal precursor feed. In one embodiment, the process comprises: sulfiding a pressure leach solution having at least a Group VIB metal precursor compound in solution forming a catalyst precursor, and mixing the sulfided catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the pressure leach solution is mixed with a hydrocarbon diluent under high shear mixing conditions to form an emulsion, which emulsion can be sulfided in-situ upon contact with a heavy oil feedstock in the heavy oil upgrade process.
摘要翻译： 提供了一种制备用于升级重油原料的浆料催化剂的方法。 该方法采用从金属回收工艺获得的压力浸出溶液作为金属前体进料的一部分。 在一个实施方案中，该方法包括：在形成催化剂前体的溶液中硫化具有至少VIB族金属前体化合物的压力浸出溶液，并将硫化催化剂前体与烃稀释剂混合以形成浆料催化剂。 在另一个实施方案中，将压力浸出溶液与烃稀释剂在高剪切混合条件下混合以形成乳液，该乳液可在重油升级过程中与重油原料接触时原位硫化。
-
7.发明申请METALLURGICAL EXTRACTION TECHNIQUE TO RECOVER PLATINUM GROUP METALS FROM A FILTER CAKE 有权从过滤器中回收铂族金属的冶金提取技术公开(公告)号：US20160115567A1
公开(公告)日：2016-04-28
申请号：US14521211
申请日：2014-10-22
CPC分类号： C22B11/08 , C22B3/46 , C22B7/009 , C22B11/048 , Y02P10/214 , Y02P10/234
摘要： This application provides a metallurgical extraction technique, comprising: a) re-pulping a feed filter cake to make a filter cake slurry; b) grinding the filter cake slurry; c) leaching the ground filter cake slurry in a hot alkaline cyanide solution to provide dissolved platinum group metals; d) liquid-solid separating of the dissolved platinum group metals; and e) recovering the dissolved platinum group metals by cementing the dissolved platinum group metals with a precipitating metal comprising an aluminum or a zinc; wherein the feed filter cake has the platinum group metals at a total amount from 0.1 to 1.5 wt % and a halide anion content from zero to less than 4 wt %. This application provides a process for platinum group metal recovery, comprising: converting a catalyst which was in contact with a water reactive ionic liquid catalyst into a non-water reactive filter cake and extracting the platinum group metals.
摘要翻译： 本申请提供冶金提取技术，其包括：a）重新制浆进料滤饼以制备滤饼浆料; b）研磨滤饼浆料; c）将研磨的滤饼浆液浸入热碱性氰化物溶液中以提供溶解的铂族金属; d）溶解的铂族金属的液固分离; 和e）通过用包含铝或锌的沉淀金属固溶溶解的铂族金属来回收溶解的铂族金属; 其中所述进料滤饼具有总量为0.1至1.5重量％的铂族金属和从零至小于4重量％的卤化物阴离子含量。 本申请提供了铂族金属回收方法，包括：将与水反应性离子液体催化剂接触的催化剂转化成非水反应性滤饼并萃取铂族金属。
-
8.发明申请RECOVERY OF VANADIUM FROM PETROLEUM COKE SLURRY CONTAINING SOLUBILIZED BASE METALS 有权从含有溶解碱性金属的石油焦浆料中回收钒公开(公告)号：US20140248199A1
公开(公告)日：2014-09-04
申请号：US13784325
申请日：2013-03-04
IPC分类号： C22B34/22
CPC分类号： C22B34/225 , Y02P10/23 , Y02P10/234
摘要： A method for recovering vanadium from a spent slurry catalyst for hydrocarbon oil hydroprocessing is disclosed. In one embodiment after de-oiling, the spent catalyst is treated with ammonia and air, forming a leach slurry. The leach slurry is subsequently treated with a flocculant. After solid-liquid separation to recover the solid residue containing coke and ammonium metavanadate, the solid residue is washed with an ammonium sulfate solution and leached with hot water. After solid-liquid separation to recover a solution containing ammonium metavanadate, the ammonium metavanadate is crystallized and purified from the leach solution.
摘要翻译： 公开了一种从用于烃油加氢处理的废浆催化剂中回收钒的方法。 在脱油后的一个实施方案中，用氨和空气处理废催化剂，形成浸出浆料。 随后用絮凝剂处理浸出浆料。 固液分离后，回收含有焦炭和偏钒酸铵的固体残渣，固体残渣用硫酸铵溶液洗涤，用热水浸出。 在固液分离以回收含偏钒酸铵的溶液之后，将偏钒酸铵从浸出溶液中结晶并纯化。
-
公开(公告)号：US08778828B2
公开(公告)日：2014-07-15
申请号：US13331341
申请日：2011-12-20
申请人： Oleg Mironov , Alexander E. Kuperman , Rahul Shankar Bhaduri , Julie Chabot , Shuwu Yang , Ling Jiao , Joseph V. Nguyen , Bruce Edward Reynolds
发明人： Oleg Mironov , Alexander E. Kuperman , Rahul Shankar Bhaduri , Julie Chabot , Shuwu Yang , Ling Jiao , Joseph V. Nguyen , Bruce Edward Reynolds
IPC分类号： B01J31/00 , B01J27/24 , B01J27/02 , B01J27/043 , B01J27/045 , B01J23/00 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/58 , B01J23/70 , B01J23/74 , B01J27/051 , B01J23/85 , B01J35/00 , B01J23/883 , B01J23/24 , B01J23/887 , B01J37/20 , C10G49/04 , B01J35/10
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： A process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a pressure leach solution obtained from a metal recovery process as part of the metal precursor feed. In one embodiment, the process comprises: sulfiding a pressure leach solution having at least a Group VIB metal precursor compound in solution forming a catalyst precursor, and mixing the sulfided catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the pressure leach solution is mixed with a hydrocarbon diluent under high shear mixing conditions to form an emulsion, which emulsion can be sulfided in-situ upon contact with a heavy oil feedstock in the heavy oil upgrade process.
摘要翻译： 提供了一种制备用于升级重油原料的浆料催化剂的方法。 该方法采用从金属回收工艺获得的压力浸出溶液作为金属前体进料的一部分。 在一个实施方案中，该方法包括：在形成催化剂前体的溶液中硫化具有至少VIB族金属前体化合物的压力浸出溶液，并将硫化催化剂前体与烃稀释剂混合以形成浆料催化剂。 在另一个实施方案中，将压力浸出溶液与烃稀释剂在高剪切混合条件下混合以形成乳液，该乳液可在重油升级过程中与重油原料接触时原位硫化。
-
公开(公告)号：US20120039777A1
公开(公告)日：2012-02-16
申请号：US13156589
申请日：2011-06-09
IPC分类号： C22B34/30
CPC分类号： C22B34/345 , C22B7/009 , C22B23/026 , C22B23/0446 , C22B34/225 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals.
摘要翻译： 提供了一种处理含有重金属的废催化剂的方法，例如VIB族金属和VIII族金属。 在脱油后的一个实施方案中，在足以将VIB族金属和VIII族金属溶解到浸出溶液中的条件下，用氨浸出溶液处理废催化剂，形成浸出浆料。 在固液分离回收浸出溶液后，进行化学沉淀和固体再浆化，得到含有硫酸铵（Amsul），氨基磺酸铵，VB族，VIB族和VIII族金属的流出物流。 硫化后，完全除去第Ⅷ族金属，并从Amsul流部分除去VB族和VI族金属。 在氧解溶解和铁沉淀的附加步骤中，加入预选择pH下的有效量的铁离子以与VB族和VIB族金属组合形成不溶性络合物，其在液固分离时产生流出的硫酸铵流，其含有 VB族和VIB族金属中的每一种都少于10ppm。
-
-
-
-
-
-
-
-
-
搜索结果
13 条记录 (耗时 0.022 秒)
