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    Deposition of metals on electrically conductive, polymeric carriers
    2.
    发明授权
    Deposition of metals on electrically conductive, polymeric carriers 失效
    在导电的聚合物载体上沉积金属

    公开(公告)号：US4560593A

    公开(公告)日：1985-12-24

    申请号：US662546

    申请日：1984-10-19

    申请人： Herbert Naarmann ,  Volker Munch ,  Klaus Penzien

    发明人： Herbert Naarmann ,  Volker Munch ,  Klaus Penzien

    IPC分类号： C23C14/14 ,  C23C18/16 ,  C23C18/31 ,  C23C18/34 ,  C23C18/38 ,  C23C18/44 ,  C23C18/52 ,  C25D5/56 ,  H05K3/18 ,  C23C3/02

    CPC分类号： C23C18/52 ,  C25D5/56 ,  H05K3/181

    摘要： A process for depositing metals onto electrically conductive, polymeric carriers, wherein a finely divided metal M having a standard potential E.sub.o of >-2 V is deposited, from a solution of a metal cation compound of the formula (I) ##EQU1## where M', L.sup.1, L.sup.2, L.sup.3, L.sup.4, l, m, n, o, and p are as defined in the claims, in an aprotic polar or non-polar solvent, onto a polymeric, electrically conductive carrier of the formula (II) ##EQU2## where M" is Li, Na, K, Rb or Cs,P is P=--CH--, --C.sub.6 H.sub.4 --, --C.sub.4 H.sub.2 S--, --C.sub.6 H.sub.4 S--, --C.sub.4 H.sub.2 O--, --C.sub.4 H.sub.2 NH-- --C.sub.6 H.sub.4 O-- or --C.sub.5 H.sub.3 N--y is from 0.001 to 0.6 andx is from 5 to 1,000, or onto a polymeric, electrically conductive carrier of the formula (III)[(P)(X).sub.y ].sub.x (III)whereP is one of the groups listed for formula (II), X is ClO.sub.4.sup..crclbar., AsF.sub.6.sup..crclbar., PF.sub.6.sup..crclbar., SbF.sub.6.sup..crclbar., BF.sub.4.sup..crclbar., HSO.sub.4.sup..crclbar., CF.sub.3 SO.sub.3.sup..crclbar. or Br.sup..crclbar.,y is from 0.001 to 0.6 andx is from 5 to 1,000, by reduction, preferably at from -100.degree. to +100.degree. C. The electrically conductive, polymeric systems can be employed in the electrical industry for the production of solar cells, for converting and fixing radiation, and for the production of electric and magnetic switches and electrical storage devices, and can also be used as heterogeneous catalysts and to provide an antistatic finish on plastics.

    摘要翻译： 一种将金属沉积在导电聚合物载体上的方法，其中从式（I）的化学式（I）的化学式（I）的化学物质中沉积出具有> -2V的标准电位Eo的细碎金属M（I ）其中M'，L1，L2，L3，L4，l，m，n，o和p如权利要求中所定义，在非质子传递极性或非极性溶剂中， （II）其中M“是Li，Na，K，Rb或Cs，P是P = -CH-，-C6H4-，-C4H2S-，-C6H4S-， -C 4 H 2 O-，-C 4 H 2 NH-C 6 H 4 O-或-C 5 H 3 N-y为0.001至0.6，x为5至1,000，或通式（III）[（P）（X）y）的聚合导电载体上 ] x（III）其中P是式（II）中所列的基团之一，X是ClO 4（ - ），AsF 6（ - ），PF 6（ - ），SbF 6（ - ），BF 4（ - ），HSO 4 ，CF 3 SO 3（ - ）或Br（ - ），y为0.001至0.6，x为5至1,000，通过还原，优选为-100至+ 100℃。可使用导电聚合体系 在电气工业中用于生产太阳能电池，用于转换和固定辐射，以及用于生产电磁开关和蓄电装置，并且还可以用作非均相催化剂并在塑料上提供抗静电涂饰。

    Preparation of electrically conductive products
    3.
    发明授权
    Preparation of electrically conductive products 失效
    导电产品的制备

    公开(公告)号：US4440693A

    公开(公告)日：1984-04-03

    申请号：US327726

    申请日：1981-12-04

    申请人： Herbert Naarmann ,  Klaus Penzien ,  Volker Muench ,  Klaus-Dieter Franz

    发明人： Herbert Naarmann ,  Klaus Penzien ,  Volker Muench ,  Klaus-Dieter Franz

    IPC分类号： C08G79/00 ,  C08G79/14 ,  C08K5/00 ,  H01B1/12 ,  H01L51/30 ,  C07F1/08 ,  C07F15/02

    CPC分类号： H01L51/0077 ,  C08G79/00 ,  C08G79/14 ,  C08K5/0091 ,  H01B1/12 ,  H01L51/0051 ,  H01L51/0052 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive products which are stable to air and have conductivities greater than 1 .times.10.sup.-3 S/cm, by reacting a cation of a metal of group VII or VIII or of sub-group I of the periodic table with an organic chelating compound to give a metal chelate and oxidizing the latter to form a oxidized product, wherein the organic chelating compound is a 1,9-substituted phenalene of the formula I ##STR1## where X is O, NH, S, Se or Te and Y is OH, NH.sub.2 or SH. The electrically conductive products are useful for the production of solar cells, the conversion and fixing of radiation, the production of electrical and magnetic switches and the antistatic treatment of plastics.

    摘要翻译： 通过将元素周期表第VII族或第Ⅷ族金属或第1族元素的阳离子与阳离子的反应，通过使周期表第Ⅶ族或Ⅷ族金属的阳离子与 一种有机螯合化合物，得到金属螯合物并将其氧化以形成氧化产物，其中有机螯合化合物是式I的1,9-取代的非那烯，其中X是O，NH，S，Se或 Te和Y是OH，NH2或SH。 导电产品可用于生产太阳能电池，辐射的转换和固定，电气和磁性开关的生产以及塑料的抗静电处理。

    Preparation of electrically conductive soluble heteropolyphenylenes
    4.
    发明授权
    Preparation of electrically conductive soluble heteropolyphenylenes 失效
    导电性可溶性多聚苯乙烯的制备

    公开(公告)号：US4395497A

    公开(公告)日：1983-07-26

    申请号：US273688

    申请日：1981-06-15

    申请人： Herbert Naarmann ,  Dieter Naegele ,  Klaus Penzien ,  Johannes Schlag

    发明人： Herbert Naarmann ,  Dieter Naegele ,  Klaus Penzien ,  Johannes Schlag

    IPC分类号： C08G61/12 ,  C08L65/00 ,  H01B1/12 ,  H01L51/30 ,  C08L77/02

    CPC分类号： H01B1/128 ,  C08G61/123 ,  C08L65/00 ,  H01B1/127 ,  H01L51/0035 ,  C08G2261/312 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive heteropolyphenylenes, wherein from 0.5 to 5 per cent by weight of an activating additive is introduced, in the absence of moisture and of oxygen, into a heteropolyphenylene of the general formula ##STR1## where X is O, S, Se, SO or SO.sub.2 and Y has one of the meanings given for X or is NH, CH.sub.2, CO or C.sub.6 H.sub.4, and n is from 2 to 250. The activating additive is preferably one of the compounds AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, SbCl.sub.5, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid and 2,4,6-trinitrophenylcarboxylic acid, or is sodium, potassium, rubidium, cesium, calcium or barium or one of their amides, the latter being added, if appropriate, in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene. The conductive heteropolyphenylenes may be used in the electrical industry for the production of solar cells, for conversion and fixing of radiation and for the production of electrical and magnetic switches, or may be used for the antistatic treatment of plastics.

    摘要翻译： 一种用于制备导电杂多苯基苯的方法，其中将0.5-5重量％的活化添加剂在没有水分和氧气的情况下引入通式为“IMAGE”的杂多亚苯基，其中X为O， S，Se，SO或SO 2，Y具有对X给出的含义之一或为NH，CH 2，CO或C 6 H 4，n为2至250.活化添加剂优选为化合物AsF5，SbF5，UF6， HClO4，NO + SbF6-，NO2 + SbF6-，NO + PF6-，SbCl5，NO2 + PF6-，NO + BF4-，NO + ClO4-，（CF3）2SO4,2,4,6-三硝基苯酚 ，6-三硝基苯磺酸和2,4,6-三硝基苯基羧酸，或者是钠，钾，铷，铯，钙或钡或它们的酰胺之一，如果合适，将其加入四氢呋喃，二甲氧基乙二醇，蒽，萘 或2-甲基苯乙烯。 导电杂多亚苯基可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及用于电气和磁性开关的生产，或可用于塑料的抗静电处理。

    Preparation of electrically conductive polymers
    8.
    发明授权
    Preparation of electrically conductive polymers 失效
    导电聚合物的制备

    公开(公告)号：US4418187A

    公开(公告)日：1983-11-29

    申请号：US254258

    申请日：1981-04-15

    申请人： Volker Muench ,  Herbert Naarmann ,  Klaus Penzien

    发明人： Volker Muench ,  Herbert Naarmann ,  Klaus Penzien

    IPC分类号： C08F4/06 ,  C08F38/00 ,  H01L51/30 ,  C08F112/32 ,  C08F126/00 ,  C08F126/06 ,  C08F126/12

    CPC分类号： H01L51/004 ,  C08F38/00 ,  H01L51/0042 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive polymers by polymerizing acenaphthylene, N-vinyl-heterocyclics, eg. N-vinylcarbazole or N-vinylpyridine, or N,N-divinylaniline at from -80.degree. to +100.degree. C. in the presence of a cationtic catalyst, wherein from 1 to 50 percent by weight of an oxidizing Lewis acid, preferably FeCl.sub.3, FeBr.sub.3, SbCl.sub.5, SbF.sub.5, AsF.sub.5 or CF.sub.3 -SO.sub.3 H, or a combination of AlCl.sub.3 or TiCl.sub.4 with the said compounds or with CrO.sub.3 or OsO.sub.4 is used as the catalyst. In a preferred embodiment of the process, thin films of the monomers to be polymerized, applied to glass or to a polymeric base, preferably to a plastic film, are treated with gaseous SbCl.sub.5, SbF.sub.5 or AsF.sub.5. The conductive polymers obtained can be used in the electrical industry for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches, as well as for the antistatic treatment of plastics.

    摘要翻译： 通过聚合苊烯，N-乙烯基 - 杂环化合物制备导电聚合物的方法， N-乙烯基咔唑或N-乙烯基吡啶或N，N-二乙烯基苯胺，在-80℃至+ 100℃下，在阳离子催化剂存在下，其中1至50重量％的氧化路易斯酸，优选FeCl 3， FeBr 3，SbCl 5，SbF 5，AsF 5或CF 3 SO 3 H，或AlCl 3或TiCl 4与所述化合物或与CrO 3或OsO 4的组合用作催化剂。 在该方法的优选实施方案中，将待聚合的单体的薄膜施加到玻璃上或聚合物基体上，优选用塑料膜，用气态SbCl 5，SbF 5或AsF 5处理。 所得到的导电聚合物可用于电气工业中用于生产太阳能电池，用于辐射的转换和固定以及电气和磁性开关的生产以及用于塑料的抗静电处理。

    Preparation of electrically conductive hetero-poly-phenylenes
    10.
    发明授权
    Preparation of electrically conductive hetero-poly-phenylenes 失效
    导电异聚亚苯基的制备

    公开(公告)号：US4344869A

    公开(公告)日：1982-08-17

    申请号：US237635

    申请日：1981-02-24

    申请人： Gerd Blinne ,  Herbert Naarmann ,  Klaus Penzien

    发明人： Gerd Blinne ,  Herbert Naarmann ,  Klaus Penzien

    IPC分类号： C08L71/00 ,  C08L81/00 ,  C08L85/00 ,  C09K3/16 ,  H01B1/12 ,  H01L51/30 ,  H01B1/00

    CPC分类号： H01L51/0036 ,  C08L71/00 ,  C08L81/00 ,  C08L85/00 ,  C09K3/16 ,  H01B1/128 ,  H01L51/0035 ,  Y02E10/549

    摘要： A process for the preparation of electrically conductive hetero-polyphenylenes, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyphenylene in the absence of moisture and of oxygen.

    摘要翻译： 具有导电性大于10-2S / cm的导电异聚亚苯基的制备方法，其中0.5至35重量％的pka为-10至+4的强路易斯酸，优选AsF5，SbF5 ，UF6，HClO4，NO + SbF6-，NO2 + SbF6-，NO + AsF6-，NO + PF6-，NO2 + PF6-，NO + BF4-，NO2 + BF4-，NO + ClO4-，（CF3） 将2,4,6-三硝基苯酚，2,4,6-三硝基苯磺酸或2,4,6-三硝基苯甲酸加入到不存在水分和氧气的异亚苯基中。