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    Process for the production of hydrogenated ring-opened metathesis polymers
    3.
    发明授权
    Process for the production of hydrogenated ring-opened metathesis polymers 失效
    氢化开环复分解聚合物的制备方法

    公开(公告)号：US5932664A

    公开(公告)日：1999-08-03

    申请号：US991721

    申请日：1997-12-16

    申请人： Yun Chen ,  Ralf Dujardin ,  Harald Pielartzik ,  Uli Werner Franz

    发明人： Yun Chen ,  Ralf Dujardin ,  Harald Pielartzik ,  Uli Werner Franz

    IPC分类号： C08F4/60 ,  C08F4/80 ,  C08G61/08 ,  C08F8/04

    CPC分类号： C08G61/08

    摘要： Process for the production of hydrogenated, ring-opened metathesis (co)polymers from cyclic olefins using the ruthenium-carbene complexes of the general formula (I) ##STR1## in which R.sub.1 and R.sub.2 mutually independently mean hydrogen, C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.1 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbon-yl,C.sub.1 -C.sub.20 alkylthio, which may optionally be substituted by C.sub.1 -C.sub.5 alkyl, halogen, C.sub.1 -C.sub.5 alkoxy or by phenyl optionally substituted by C.sub.1 -C.sub.5 alkyl, halogen, C.sub.1 -C.sub.5 alkoxy;X.sub.1 and X.sub.2 mutually independently mean any desired anionic ligand;L.sub.1 and L.sub.2 mutually independently mean any desired neutral electron donorand two or three of X.sub.1, X.sub.2, L.sub.1 and L.sub.2 may furthermore together form a multi-dentate chelating ligand,as catalysts for the polymerisation stage, wherein the catalyst is optionally modified after polymerisation by adding a modifier and the polymerisation product is hydrogenated as a solution (optionally diluted with the same inert solvent as during polymerisation or with another inert solvent) without addition of an extra hydrogenation catalyst at temperatures of 0.degree. C. to 200.degree. C. preferably of 35.degree. C. to 150.degree. C. under a hydrogen pressure of 2 to 200 bar, preferably of 10 to 50 bar, wherein at least 60%, preferably at least 95% of the olefinic double bonds are saturated.

    摘要翻译： 使用其中R 1和R 2相互独立地表示氢，C 2 -C 20烯基，C 1 -C 20烷基的通式（I）的钌 - 卡宾复合物从环烯烃生产氢化的开环复分解体（共）聚合物的方法 ，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基，C 2 -C 20链烯氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，其可以任选地被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或 任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基取代的苯基; X1和X2相互独立地表示任何所需的阴离子配体; L1和L2相互独立地表示任何所需的中性电子给体，并且X1，X2，L1和L2中的两个或三个还可以一起形成多齿螯合配体，作为聚合阶段的催化剂，其中催化剂在聚合后任选地被改性 加入改性剂，并且将聚合产物作为溶液氢化（任选地用与聚合期间相同的惰性溶剂稀释或与另一种惰性溶剂一起稀释），而在0℃至200℃的温度下不加入额外的氢化催化剂，优选为 35℃至150℃，氢压为2至200巴，优选10至50巴，其中至少60％，优选至少95％的烯属双键是饱和的。

    Decomposable packing material
    4.
    发明授权
    Decomposable packing material 失效
    分解包装材料

    公开(公告)号：US5512339A

    公开(公告)日：1996-04-30

    申请号：US139869

    申请日：1993-10-22

    申请人： Ralf Dujardin ,  Rolf Dhein ,  Martin Wandel

    发明人： Ralf Dujardin ,  Rolf Dhein ,  Martin Wandel

    IPC分类号： B65D65/46 ,  C08L77/00 ,  B29D22/00 ,  B32B1/08

    CPC分类号： C08L77/00 ,  Y10S525/938 ,  Y10T428/1345 ,  Y10T428/1352

    摘要： This invention relates to decomposable polyamide masses for packaging materials containing 5 to 25% by weight of an addition of linear, oligomeric aliphatic polyesters or polycarbonates with molecular weights from 800 to 4000. These additives preferably consist of polyesters of aliphatic diols and dicarboxylic acids having up to 10 carbon atoms or aliphatic carbonates having up to 10 carbon atoms.The use of such mixtures for easily degradable, decomposable polyamide packages is also claimed, in particular in the form of films or thin walled injection moulded parts for (food) packaging.

    摘要翻译： 本发明涉及用于包装材料的可分解聚酰胺质料，其含有5至25重量％的直链，低聚脂族聚酯或分子量为800至4000的聚碳酸酯。这些添加剂优选由脂肪族二醇和二羧酸的聚酯组成， 至10个碳原子或具有至多10个碳原子的脂族碳酸酯。 还要求使用这种混合物用于易降解的可分解的聚酰胺封装，特别是以（食品）包装的薄膜或薄壁注模部件的形式。