摘要:
An article for use in hostile thermal environments, such as a component of a gas turbine engine. The article includes a nickel-base superalloy substrate that is prone to formation of a deleterious secondary reaction zone (SRZ), and an overlay coating having a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating, including a bond coat for a thermal barrier coating. The coating comprises a chromium-containing nickel aluminide intermetallic overlay coating of predominantly the gamma prime phase, in which aluminum is present in the coating in an amount approximately equal to the aluminum content of the superalloy substrate so as to inhibit diffusion of aluminum from the overlay coating into the superalloy substrate.
摘要翻译:用于敌对热环境中的物品,例如燃气轮机的部件。 该制品包括易于形成有害的次级反应区(SRZ)的镍基超级合金基材和具有主要为γ原相镍铝化合物(Ni 3 Al 3 Al)组成的覆盖涂层 适合用作环境涂层,包括用于热障涂层的粘合涂层。 该涂层包括主要为γ'相的含铬镍铝金属间覆盖涂层,其中铝在涂层中的含量约等于超级合金基材的铝含量,从而抑制铝从覆盖层的扩散 涂覆到超合金基材中。
摘要:
An overlay coating for articles used in hostile thermal environments. The coating has a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating and as a bond coat for a thermal barrier coating. The coating has a composition of, by weight, at least 6% to about 15% aluminum, about 2% to about 5% chromium, optionally one or more reactive elements in individual or combined amounts of up to 4%, optionally up to 2% silicon, optionally up to 60% of at least one platinum group metal, and the balance essentially nickel. A thermal-insulating ceramic layer may be deposited on the coating.
摘要翻译:用于敌对热环境中的物品的覆盖涂层。 该涂层主要具有适合用作环境涂层和用作热障涂层的粘合涂层的γ初始相铝酸镍(Ni 3 Al 3 Al)组合物。 该涂层具有按重量计至少6%至约15%的铝,约2%至约5%的铬,任选的一种或多种反应性元素的组合物,其个体或组合量可达4%,任选至多2 %硅,任选至多60%的至少一种铂族金属,余量基本上为镍。 绝热陶瓷层可以沉积在涂层上。
摘要:
A nickel-base alloy that exhibits a desirable balance of mechanical properties, environmental properties, and microstructural stability suitable for gas turbine engine applications. The nickel-base alloy is in the form of a single-crystal casting consisting of, by weight, 5.75% to 6.5% aluminum, 4% to 5% tantalum, 2% to 6% chromium, 5.5% to 7% tungsten, 1.5% to 3% molybdenum, 4% to 5% rhenium, up to 1.0% niobium, 10% to 16% cobalt, up to 1% titanium, 0.01% to 0.05% carbon, up to 0.005% boron, up to 0.01% yttrium, 0.5% to 1.0% hafnium, the balance nickel and incidental impurities. The alloy has a density of not more than 0.320 lbs/in3 (about 8.87 g/cm3), and contains a combined amount of aluminum, tungsten, molybdenum, niobium, titanium, and hafnium specified relative to the combined amount of tantalum and rhenium.
摘要:
An article includes a substantially single crystal piece having a composition consisting essentially of, in weight percent, from 0.4 to 6.5 percent ruthenium, from 3 to 8 percent rhenium, from 5.8 to 10.7 percent tantalum, from 4.25 to 17.0 percent cobalt, from 0.1 to 2.0 percent hafnium, from 0.02 to 0.4 percent carbon, from 0.001 to 0.005 percent boron, from 0 to 0.02 percent yttrium, from 1 to 4 percent molybdenum, from 1.25 to 10 percent chromium, from 0.5 to 2.0 percent niobium, from 0.05 to 0.5 percent zirconium, from 5.0 to 6.6 percent aluminum, from 0 to 2.0 percent titanium, from 3.0 to 7.5 percent tungsten, and from 0.1 to 6 percent of platinum, iridium, rhodium, and palladium, and combinations thereof, balance nickel and incidental impurities.
摘要翻译:一种制品包括基本上单晶片,其组成基本上由重量百分比组成,钌含量为henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium henium r r r r r r r r r r r r r r r 2.0%的铪,0.02〜0.4%的碳,0.001〜0.005%的硼,0〜0.02%的钇,1〜4%的钼,1.25〜10%的铬,0.5〜2.0%的铌,0.05〜0.5 的锆,5.0至6.6%的铝,0至2.0%的钛,3.0至7.5%的钨和0.1至6%的铂,铱,铑和钯及其组合,才能平衡镍和杂质。
摘要:
An article and TBC coating system thereon that in combination exhibit significantly improved spallation resistance. The article comprises a substrate formed of a metal alloy containing ruthenium and one or more refractory elements (e.g., tantalum, tungsten, molybdenum, rhenium, hafnium, etc.). The substrate is protected by a coating system comprising an aluminum-containing bond coat on the surface of the substrate and a ceramic coating bonded to the substrate by the bond coat. The bond coat, preferably an aluminide, is deposited so as to be substantially free of ruthenium, though ruthenium is present in the bond coat as a result of diffusion from the substrate into the bond coat.
摘要:
A beta-phase NiAl overlay coating containing a dispersion of ceramic particles and a process for depositing the overlay coating. If the coating is used to adhere a thermal barrier coating (TBC), the TBC exhibits improved spallation resistance as a result of the dispersion of ceramic particles having a dispersion-strengthening effect on the overlay coating. The overlay coating contains at least one reactive element and is deposited so that the some of the reactive element deposits as the ceramic particles dispersed in the overlay coating.
摘要:
A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.
摘要:
A gas turbine engine component and coating system including a superalloy substrate having a coating system disposed thereon. A bond coating may be applied to the substrate. An adherent layer of ceramic material forming a thermal barrier coating is present on the bond coat layer. A topcoat layer overlies the thermal barrier coating. The topcoat layer includes greater than about 20 wt % yttria.
摘要:
A protected article is prepared by providing the article, depositing a bond coat onto an exposed surface of the article, and producing a thermal barrier coating on an exposed surface of the bond coat. The step of producing the thermal barrier coating includes the steps of depositing a primary ceramic coating onto an exposed surface of the bond coat, and depositing a stabilization composition onto an exposed surface of the primary ceramic coating. The stabilization composition includes a first element selected from Group 2 or Group 3 of the periodic table, and a second element selected from Group 5 of the periodic table. The atomic ratio of the amount of the first element to the amount of the second element is at least 1.3, more preferably at least 1:1.
摘要:
A coating process for an article having a substrate formed of a metal alloy that is prone to the formation of a secondary reaction zone (SRZ). The coating process forms a coating system that includes an aluminum-containing overlay coating and a stabilizing layer between the overlay coating and the substrate. The overlay coating contains aluminum in an amount greater by atomic percent than the metal alloy of the substrate, such that there is a tendency for aluminum to diffuse from the overlay coating into the substrate. The stabilizing layer is predominantly or entirely formed of at least one platinum group metal (PGM), namely, platinum, rhodium, iridium, and/or palladium. The stabilizing layer is sufficient to inhibit diffusion of aluminum from the overlay coating into the substrate so that the substrate remains essentially free of an SRZ that would be deleterious to the mechanical properties of the alloy.