公开(公告)号：US20050069650A1

公开(公告)日：2005-03-31

申请号：US10904325

申请日：2004-11-04

申请人： Ramgopal Darolia ,  Joseph Rigney ,  William Walston ,  Jeffrey Pfaendtner ,  Brett Boutwell ,  Irene Spitsberg ,  James Ruud

发明人： Ramgopal Darolia ,  Joseph Rigney ,  William Walston ,  Jeffrey Pfaendtner ,  Brett Boutwell ,  Irene Spitsberg ,  James Ruud

IPC分类号： C23C4/02 ,  C23C4/12 ,  C23C14/06 ,  C23C28/00 ,  H05H1/26

CPC分类号： C23C28/321 ,  C23C4/02 ,  C23C4/12 ,  C23C14/06 ,  C23C28/3215 ,  C23C28/324 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12576 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12736 ,  Y10T428/12771 ,  Y10T428/12806 ,  Y10T428/12944 ,  Y10T428/252

摘要： A beta-phase NiAl overlay coating containing a dispersion of ceramic particles and a process for depositing the overlay coating. If the coating is used to adhere a thermal barrier coating (TBC), the TBC exhibits improved spallation resistance as a result of the dispersion of ceramic particles having a dispersion-strengthening effect on the overlay coating. The overlay coating contains at least one reactive element and is deposited so that the some of the reactive element deposits as the ceramic particles dispersed in the overlay coating.

摘要翻译： 含有陶瓷颗粒分散体的β相NiAl覆盖涂层和沉积覆盖层的方法。 如果涂层用于粘附热障涂层（TBC），则由于在覆盖涂层上具有分散强化作用的陶瓷颗粒的分散，TBC显示出改进的抗剥落性。 覆盖层包含至少一个反应性元件并沉积成使得一部分反应性元素沉积为陶瓷颗粒分散在覆盖层中。

公开(公告)号：US20050136283A1

公开(公告)日：2005-06-23

申请号：US10707543

申请日：2003-12-19

申请人： Jeffrey Pfaendtner ,  Deborah Schorr ,  Ramgopal Darolia ,  Joseph Rigney ,  Irene Spitsberg ,  William Walston

发明人： Jeffrey Pfaendtner ,  Deborah Schorr ,  Ramgopal Darolia ,  Joseph Rigney ,  Irene Spitsberg ,  William Walston

IPC分类号： C22C19/03 ,  C23C4/00 ,  C23C28/00 ,  C23C30/00 ,  F01D5/00 ,  F01D5/28 ,  B32B15/01

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  F01D5/288 ,  F05D2220/3212 ,  F05D2300/13 ,  Y10T428/12611 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12875 ,  Y10T428/12944 ,  Y10T428/12986

摘要： An article and TBC coating system thereon that in combination exhibit significantly improved spallation resistance. The article comprises a substrate formed of a metal alloy containing ruthenium and one or more refractory elements (e.g., tantalum, tungsten, molybdenum, rhenium, hafnium, etc.). The substrate is protected by a coating system comprising an aluminum-containing bond coat on the surface of the substrate and a ceramic coating bonded to the substrate by the bond coat. The bond coat, preferably an aluminide, is deposited so as to be substantially free of ruthenium, though ruthenium is present in the bond coat as a result of diffusion from the substrate into the bond coat.

摘要翻译： 其上的一种制品和TBC涂层体系组合显示出显着改善的防剥落性。 该制品包括由含有钌和一种或多种难熔元素（例如钽，钨，钼，铼，铪等）的金属合金形成的基材。 基材由包括基材表面的含铝粘合涂层的涂层体系和通过粘合涂层粘合到基材上的陶瓷涂层保护。 沉积粘合涂层，优选铝化物，以便基本上不含钌，尽管由于从基材扩散到粘合涂层中，钌存在于粘合涂层中。

公开(公告)号：US20050019491A1

公开(公告)日：2005-01-27

申请号：US10711584

申请日：2004-09-27

申请人： Irene Spitsberg ,  Joseph Rigney ,  Ramgopal Darolia ,  Elissa Lee ,  Jeffrey Pfaendtner

发明人： Irene Spitsberg ,  Joseph Rigney ,  Ramgopal Darolia ,  Elissa Lee ,  Jeffrey Pfaendtner

IPC分类号： C21D7/06 ,  C23C4/18 ,  C23C8/02 ,  C23C26/00 ,  C23C28/00 ,  B05D3/12

CPC分类号： C23C28/321 ,  C21D7/06 ,  C23C4/18 ,  C23C8/02 ,  C23C26/00 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12611 ,  Y10T428/12736 ,  Y10T428/12937 ,  Y10T428/12944

摘要： A beta-phase nickel aluminide (NiAl) overlay coating (24) and method for modifying the grain structure of the coating (24) to improve its oxidation resistance. The coating (24) is deposited by a method that produces a grain structure characterized by grain boundaries (44) exposed at the outer coating surface (36). The grain boundaries (44) may also contain precipitates (40) as a result of the alloyed chemistry of the coating (24). During or after deposition, the overlay coating (24) is caused to form new grain boundaries (34) that, though open to the outer surface (36) of the coating (24), are free of precipitates or contain fewer precipitates (40) than the as-deposited grain boundaries (44). New grain boundaries (34) are preferably produced by causing the overlay coating (24) to recrystallize during coating deposition or after deposition as a result of a surface treatment followed by heat treatment.

摘要翻译： β相镍铝化合物（NiAl）覆盖层（24）以及用于改变涂层（24）的晶粒结构以提高其抗氧化性的方法。 通过产生以在外涂层表面（36）处暴露的晶界（44）为特征的晶粒结构的方法沉积涂层（24）。 作为涂层（24）的合金化学的结果，晶界（44）也可以含有沉淀物（40）。 在沉积期间或之后，使覆盖涂层（24）形成新的晶粒边界（34），其尽管向涂层（24）的外表面（36）开口，但没有沉淀物或含有较少的沉淀物（40） 比沉积的晶界（44）。 优选通过在涂布沉积期间或沉积后的覆盖涂层（24）进行再结晶，然后进行热处理后的表面处理，来制造新的晶界（34）。

公开(公告)号：US20060182892A9

公开(公告)日：2006-08-17

申请号：US10248056

申请日：2002-12-13

申请人： Irene Spitsberg ,  Joseph Rigney ,  Ramgopal Darolia ,  Elissa Lee ,  Jeffrey Pfaendtner

发明人： Irene Spitsberg ,  Joseph Rigney ,  Ramgopal Darolia ,  Elissa Lee ,  Jeffrey Pfaendtner

IPC分类号： B32B15/00 ,  B32B15/10 ,  B05D3/02 ,  B05D1/36

CPC分类号： C23C28/321 ,  C21D7/06 ,  C23C4/18 ,  C23C8/02 ,  C23C26/00 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12611 ,  Y10T428/12736 ,  Y10T428/12937 ,  Y10T428/12944

摘要： A beta-phase nickel aluminide (NiAl) overlay coating (24) and method for modifying the grain structure of the coating (24) to improve its oxidation resistance. The coating (24) is deposited by a method that produces a grain structure characterized by grain boundaries (44) exposed at the outer coating surface (36). The grain boundaries (44) may also contain precipitates (40) as a result of the alloyed chemistry of the coating (24). During or after deposition, the overlay coating (24) is caused to form new grain boundaries (34) that, though open to the outer surface (36) of the coating (24), are free of precipitates or contain fewer precipitates (40) than the as-deposited grain boundaries (44). New grain boundaries (34) are preferably produced by causing the overlay coating (24) to recrystallize during coating deposition or after deposition as a result of a surface treatment followed by heat treatment.

摘要翻译： β相镍铝化合物（NiAl）覆盖层（24）以及用于改变涂层（24）的晶粒结构以提高其抗氧化性的方法。 通过产生以在外涂层表面（36）处暴露的晶界（44）为特征的晶粒结构的方法沉积涂层（24）。 由于涂层（24）的合金化学，晶界（44）也可含有沉淀物（40）。 在沉积期间或之后，使覆盖涂层（24）形成新的晶粒边界（34），其尽管向涂层（24）的外表面（36）开口，但没有沉淀物或含有较少的沉淀物（40） 比沉积的晶界（44）。 优选通过在涂布沉积期间或沉积后的覆盖涂层（24）进行再结晶，然后进行热处理后的表面处理，来制造新的晶界（34）。

公开(公告)号：US20060057406A1

公开(公告)日：2006-03-16

申请号：US10711364

申请日：2004-09-14

申请人： Ramgopal Darolia ,  Brett Boutwell ,  Brian Hazel ,  Bangalore Nagaraj ,  Joseph Rigney ,  Roger Wustman

发明人： Ramgopal Darolia ,  Brett Boutwell ,  Brian Hazel ,  Bangalore Nagaraj ,  Joseph Rigney ,  Roger Wustman

IPC分类号： B32B15/04 ,  B32B9/00 ,  C23C16/00

CPC分类号： C23C14/226 ,  C23C14/22 ,  C23C14/505 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/345 ,  C23C28/3455 ,  C23C28/42 ,  F01D5/288 ,  F05D2230/90 ,  F05D2300/611 ,  Y10T428/24355 ,  Y10T428/24413

摘要： Thermal barrier coating (TBC) and a method of depositing a TBC having a modulated columnar microstructure that exhibits increased impact resistance. The TBC is deposited to have a columnar microstructure in which columns extend from a substrate surface. The columns having inner regions contacting the surface, outer regions near an outermost surface of the TBC, and interior regions therebetween. The inner regions of the columns are substantially normal to the substrate surface and at least one of the interior and outer regions of the columns are nonaligned with its respective inner regions, so that the columns of the columnar microstructure are continuous but modulated between the inner and outer regions to reduce tensile stresses within the columns resulting from particle impact.

摘要翻译： 热屏蔽涂层（TBC）和沉积具有显示出增加的耐冲击性的调制柱状微结构的TBC的方法。 沉积TBC以具有柱状微结构，其中柱从衬底表面延伸。 具有接触表面的内部区域，靠近TBC的最外表面的外部区域以及它们之间的内部区域的列。 柱的内部区域基本上垂直于基底表面，并且柱的内部和外部区域中的至少一个与其相应的内部区域不对齐，使得柱状微结构的列是连续的但是在内部和/ 外部区域以减少由于颗粒撞击引起的柱内的拉伸应力。

公开(公告)号：US20060093850A1

公开(公告)日：2006-05-04

申请号：US10904220

申请日：2004-10-29

申请人： Ramgopal Darolia ,  Joseph Rigney ,  William Walston

发明人： Ramgopal Darolia ,  Joseph Rigney ,  William Walston

IPC分类号： B32B15/01 ,  B32B15/04

CPC分类号： F01D5/288 ,  F05C2201/0466 ,  F05D2230/90 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12875 ,  Y10T428/12931 ,  Y10T428/12937 ,  Y10T428/12944

摘要： An overlay coating for articles used in hostile thermal environments. The coating has a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating and as a bond coat for a thermal barrier coating. The coating has a composition of, by weight, at least 6% to about 15% aluminum, about 2% to about 5% chromium, optionally one or more reactive elements in individual or combined amounts of up to 4%, optionally up to 2% silicon, optionally up to 60% of at least one platinum group metal, and the balance essentially nickel. A thermal-insulating ceramic layer may be deposited on the coating.

摘要翻译： 用于敌对热环境中的物品的覆盖涂层。 该涂层主要具有适合用作环境涂层和用作热障涂层的粘合涂层的γ初始相铝酸镍（Ni 3 Al 3 Al）组合物。 该涂层具有按重量计至少6％至约15％的铝，约2％至约5％的铬，任选的一种或多种反应性元素的组合物，其个体或组合量可达4％，任选至多2 ％硅，任选至多60％的至少一种铂族金属，余量基本上为镍。 绝热陶瓷层可以沉积在涂层上。

公开(公告)号：US20060093801A1

公开(公告)日：2006-05-04

申请号：US10904844

申请日：2004-12-01

申请人： Ramgopal Darolia ,  Joseph Rigney ,  Gillion Marijnissen ,  Eric Vergeldt ,  Annejan Kloosterman

发明人： Ramgopal Darolia ,  Joseph Rigney ,  Gillion Marijnissen ,  Eric Vergeldt ,  Annejan Kloosterman

IPC分类号： B32B15/01 ,  B63H1/26 ,  B32B15/00

CPC分类号： F01D5/288 ,  C23C4/18 ,  C23C10/02 ,  C23C10/48 ,  C23C10/50 ,  C23C10/52 ,  C23C28/021 ,  C23C28/321 ,  C23C28/3455 ,  C23C30/00 ,  F05D2230/90 ,  F05D2300/611 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12736 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12951 ,  Y10T428/24967 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/31678

摘要： A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.

摘要翻译： 用于将涂层沉积在基材上的涂层和方法。 涂层是主要是β（NiAl）和γ-prime（Ni 3 Al 3 Al）金属间相的镍铝化物覆盖涂层，并且适合用作环境涂层和作为粘合涂层 隔热涂层（TBC）。 可以通过以适当的量沉积镍和铝来形成所述涂层，以产生所需的β+γ初相相含量。 或者，可以沉积镍和铝，使得涂层的铝含量超过适当的量以产生所需的β+γ初相相含量，之后热处理涂层以将过量的铝从涂层扩散到基底中 产生期望的β+γ'相相含量。

公开(公告)号：US20050266266A1

公开(公告)日：2005-12-01

申请号：US10855687

申请日：2004-05-27

申请人： Joseph Rigney ,  David Clarke ,  Ramgopal Darolia

发明人： Joseph Rigney ,  David Clarke ,  Ramgopal Darolia

IPC分类号： F01D5/28 ,  C04B35/486 ,  C22C19/03 ,  C23C4/04 ,  C23C4/08 ,  C23C4/18 ,  C23C8/02 ,  C23C28/00 ,  F02C7/00 ,  B32B15/04

CPC分类号： C04B35/486 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C23C4/18 ,  C23C8/02 ,  C23C28/321 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12493 ,  Y10T428/12535 ,  Y10T428/12618 ,  Y10T428/12736 ,  Y10T428/12944

摘要： In one embodiment of the invention, a NiAl overlay bond coating composition comprises a NiAl alloy. The alloy comprises Zr and at least one modifying element in an amount effective to form a stabilized oxide structure comprising stabilized zirconia including a substantially tetragonal structure upon oxidation of the alloy. The tetragonal structure is stabilized such that it does not change phases and revert to a monoclinic or monoclinic and tetragonal structure, which is not substantially tetragonal, upon thermal cycling.

摘要翻译： 在本发明的一个实施方案中，NiAl覆盖层涂层组合物包含NiAl合金。 合金包含Zr和至少一种修饰元素，其量有效地形成稳定的氧化物结构，其包含在合金氧化时包括基本上四方晶结构的稳定的氧化锆。 四方结构被稳定，使得其在热循环时不改变相并恢复为单斜晶体或单斜晶体和四方晶体结构，其基本上不是四边形。

公开(公告)号：US20060040129A1

公开(公告)日：2006-02-23

申请号：US10922527

申请日：2004-08-20

申请人： Ramgopal Darolia ,  Mark Gorman ,  Joseph Rigney

发明人： Ramgopal Darolia ,  Mark Gorman ,  Joseph Rigney

IPC分类号： B32B15/01

CPC分类号： C23C30/00 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/322 ,  C23C28/345 ,  C23C28/3455 ,  Y02T50/67 ,  Y02T50/6765 ,  Y10T428/12736 ,  Y10T428/12875

摘要： A protected article includes a substrate having a surface and a substrate aluminum content. A first protective layer overlies a first region of the surface of the substrate, wherein the first protective layer has a composition having a first-protective-layer aluminum content at least 3 atomic percent greater than the substrate aluminum content. A second protective layer overlies a second region of the surface of the substrate different from the first region, wherein the second protective layer has a composition with at least about 60 percent by weight of platinum, rhodium, or palladium, and combinations thereof.

摘要翻译： 受保护的制品包括具有表面和基底铝含量的基底。 第一保护层覆盖在基板的表面的第一区域上，其中第一保护层具有比基板铝含量大至少3原子％的第一保护层铝含量的组合物。 第二保护层覆盖不同于第一区域的衬底表面的第二区域，其中第二保护层具有至少约60重量％的铂，铑或钯及其组合的组成。

公开(公告)号：US20070292710A1

公开(公告)日：2007-12-20

申请号：US11605082

申请日：2006-11-28

申请人： Joseph Rigney ,  Ramgopal Darolia

发明人： Joseph Rigney ,  Ramgopal Darolia

IPC分类号： C25D11/02 ,  B32B15/00

CPC分类号： C23C10/02 ,  C23C18/54 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  C25D7/04 ,  Y10T428/1259 ,  Y10T428/12736 ,  Y10T428/12771 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/265

摘要： According to an embodiment of the invention, a repaired component is disclosed. The repaired component comprises an engine run component having a base metal substrate, a portion of the base metal substrate between about 1-3 mils in thickness and an overlying bond coat having been removed to create a remaining base metal substrate of reduced thickness. The repaired component further comprises a lower growth environmental bond coating comprising an alloy having an aluminum content of about 10-60 atomic percent applied to the remaining base metal substrate so that upon subsequent repair of the component, less than about 1-3 mils in thickness of the remaining base metal substrate is removed because of less environmental coating growth into the substrate than the prior bond coat. Advantageously, the repaired component has extended component life and increased repairability.

摘要翻译： 根据本发明的实施例，公开了修理的部件。 被修复的部件包括具有贱金属基底的发动机运行部件，贱金属基底的厚度在约1-3密耳之间的部分和已经去除的上覆接合涂层，以产生厚度减小的剩余基底金属基底。 修复的部件还包括较低生长环境粘合涂层，其包含施加到剩余的贱金属基底上的约10-60原子百分比的铝含量的合金，使得在随后修复部件时，厚度小于约1-3密耳 剩余的贱金属基底被去除，因为比现有的粘合涂层更少的环境涂层生长到基底中。 有利地，修复的部件具有延长的部件寿命和增加的可修复性。