公开(公告)号：US4046687A

公开(公告)日：1977-09-06

申请号：US672334

申请日：1976-03-31

Applicant: Reinhold Schulze

Inventor： Reinhold Schulze

IPC: B01D15/08 ,  C02F1/28 ,  C25B15/08 ,  C25C1/12 ,  B01D15/06

CPC classification number: B01D15/08 ,  C02F1/281 ,  C02F1/288 ,  C22B3/24 ,  C25C1/12 ,  Y02P10/234

Abstract: A process for the adsorptive removal of one or more impurity elements, selected from the group which consists of: arsenic, antimony and bismuth, from an aqueous solution containing same in which the solution is contacted with a water-insoluble or low-solubility salt of phosphoric acid or a phosphoric acid ester (phosphate ester) on a porous substrate.

Abstract translation: 一种从含有砷，锑和铋的水溶液中吸附去除一种或多种杂质元素的方法，其中所述杂质元素含有砷，锑和铋，其中溶液与水不溶性或低溶解度盐 磷酸或磷酸酯（磷酸酯）。

公开(公告)号：US4561947A

公开(公告)日：1985-12-31

申请号：US578698

申请日：1984-02-09

Applicant: Reinhold Schulze

Inventor： Reinhold Schulze

IPC: B01D15/00 ,  C22B20060101 ,  C22B3/00 ,  C22B11/00 ,  C25C1/20 ,  C22B11/04

CPC classification number: C22B11/04 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234 ,  Y10S210/903

Abstract: The present invention provides a process for the hydrometallurgical recovery of noble metals from materials containing them by treatment with thiourea in an aqueous, acidic medium in the presence of an oxidation agent, wherein the aqueous medium simultaneously contains an oxidation agent and a reduction agent.

Abstract translation: 本发明提供了一种通过在氧化剂存在下在含水酸性介质中用硫脲处理的含有它们的材料进行湿法冶金回收贵金属的方法，其中水性介质同时含有氧化剂和还原剂。

公开(公告)号：US3988225A

公开(公告)日：1976-10-26

申请号：US576256

申请日：1975-05-12

Applicant: Reinhold Schulze

Inventor： Reinhold Schulze

IPC: B01D15/08 ,  C25C1/12 ,  C25C7/06 ,  C25C1/22

CPC classification number: C25C1/12 ,  B01D15/08 ,  B01D15/203 ,  C25C7/06

Abstract: A process for the prevention of supersaturation of electrolytes from nonferrous metal refining (preferably copper refining) with arsenic, antimony and bismuth in which the electrolyte solution is brought into contact with a chemisorption agent on a flat substrate. The substrate with the chemisorption agent is brought into a compact form with neighboring substrates and is enclosed in a protective housing before being contacted with the electrolyte.

Abstract translation: 一种防止电解质过度使用砷，锑和铋的有色金属精炼（优选铜精炼）过电压的方法，其中电解质溶液与平坦基板上的化学吸附剂接触。 具有化学吸附剂的基材与相邻的基材一起形成紧凑形状，并且在与电解质接触之前被包封在保护壳体中。

公开(公告)号：US4925485A

公开(公告)日：1990-05-15

申请号：US686421

申请日：1984-12-26

Applicant: Reinhold Schulze

Inventor： Reinhold Schulze

IPC: C22B11/00 ,  C01G5/00 ,  C01G7/00 ,  C01G55/00 ,  C22B3/16

CPC classification number: C01G5/003 ,  C01G55/001 ,  C01G7/003 ,  C22B3/1616 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234

Abstract: The present invention involves the isolation or leaching of noble metals from materials containing noble metals, e.g. ores, by treating the noble metal- containing materials with a cyclic thiourea derivative under acid pH conditions. Removal is effected by adsorption onto charcoal or by an ion exchanger, for example. Preferred cyclic thioureas are N,N'-ethylenethiourea and N,N'-propylenethiourea and the acid pH conditions may be achieved by sulfuric acid or hydrochloric acid solutions containing 0.01 to 2.0% by weight of the cyclic thiourea.

Abstract translation: 本发明涉及从含贵金属的材料中分离或浸出贵金属，例如， 通过在酸性pH条件下用环状硫脲衍生物处理含贵金属的物质。 例如，通过吸附到木炭上或通过离子交换器进行去除。 优选的环状硫脲是N，N'-亚乙基硫脲和N，N'-丙基硫脲，酸性pH条件可以通过含有0.01至2.0重量％的环硫脲的硫酸或盐酸溶液来实现。

公开(公告)号：US3947612A

公开(公告)日：1976-03-30

申请号：US352082

申请日：1973-04-17

Applicant: Reinhold Schulze

Inventor： Reinhold Schulze

IPC: B01J20/285 ,  B01D53/18 ,  B01J19/00 ,  B01J19/30 ,  B01J20/30 ,  B01J20/32 ,  B01J37/02 ,  B01J47/00 ,  B05D3/10 ,  B05D5/00 ,  G01N30/88 ,  B23B7/04

CPC classification number: B05D3/10 ,  B01J20/261 ,  B01J20/2803 ,  B01J20/28045 ,  B01J20/3014 ,  B01J20/3021 ,  B01J20/3042 ,  B01J20/3064 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/321 ,  B01J20/3236 ,  B01J20/3293 ,  B01J47/006

Abstract: A method of forming an active surface on a solid, e.g. for use of the solid as an adsorbent, catalyst carrier or contact or reactant catalyst, comprising adding a mixture of binders to a solution or suspension of an activatable substance (reactant), the binder mixture containing water-insoluble synthetic-resin substances which can be swelled by water only to a limited extent.

Abstract translation: 在固体上形成活性表面的方法，例如 用于固体作为吸附剂，催化剂载体或接触或反应物催化剂，包括将粘合剂混合物加入到可活化物质（反应物）的溶液或悬浮液中，所述粘合剂混合物含有水不溶性合成树脂物质，其可以是 仅在有限的程度上被水膨胀。