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18 条记录 (耗时 0.035 秒)

    Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds
    2.
    发明授权
    Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
    含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂

    公开(公告)号：US4897220A

    公开(公告)日：1990-01-30

    申请号：US191979

    申请日：1988-05-10

    申请人： Wolfgang Trieselt ,  Richard Baur ,  Ekhard Winkler ,  Paul Diessel ,  Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann

    发明人： Wolfgang Trieselt ,  Richard Baur ,  Ekhard Winkler ,  Paul Diessel ,  Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann

    IPC分类号： C08L33/02 ,  C08F20/10 ,  C08F220/04 ,  C08F220/06 ,  C08F222/16 ,  C11D3/37

    CPC分类号： C11D3/3761

    摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated nonconjugated double bonds and have one or more --CO--OX groups where X is hydrogen, an alkali metal, one equivalent of an alkaline earth metal or ammonium,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethylenically unsaturated C.sub.3 - to C.sub.6 -carboxylic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Finkentscher K value of from 8 to 120.

    摘要翻译： 基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％的一种或多种共聚单体， 含有两个或多个烯键式不饱和非共轭双键，并且具有一个或多个-CO-OX基团，其中X为氢，碱金属，1当量碱土金属或铵，（c）0至84.5摩尔％ 更多的单烯属不饱和C 4 -C 6 - 二羧酸，（d）0至20摩尔％的一种或多种单烯属不饱和C 3 -C 6羧酸的羟烷基酯和（e）0至30摩尔％ 可与（a）至（d）共聚的可溶性单烯属不饱和单体作为共聚单元，条件是mol％年龄（a）至（e）的总和始终为100，Finkentscher K值为8至120 。

    Iodine-containing block copolymers of 1,4-butylene oxide and ethylene oxide
    4.
    发明授权
    Iodine-containing block copolymers of 1,4-butylene oxide and ethylene oxide 失效
    含碘的1,4-环氧丁烷和环氧乙烷的嵌段共聚物

    公开(公告)号：US4200733A

    公开(公告)日：1980-04-29

    申请号：US25174

    申请日：1979-03-29

    申请人： Johannes Perner ,  Norbert Greif ,  Rolf Fikentscher ,  Paul Diessel

    发明人： Johannes Perner ,  Norbert Greif ,  Rolf Fikentscher ,  Paul Diessel

    IPC分类号： A01N59/12 ,  C08G65/26 ,  C11D3/48 ,  C08L71/02 ,  C08G65/32

    CPC分类号： C11D3/485 ,  A01N59/12 ,  C08G65/2609

    摘要： Iodine-containing block copolymers which contain from 5 to 25% by weight of bonded iodine, and which are based on iodine-free compounds of the formula IR(AB).sub.z Iwhereif z=1, R is hydrogen or a C.sub.1 -C.sub.18 -aliphatic hydrocarbon radical,if z.noteq.1, R is a z-valent aliphatic hydrocarbon radical of 2 to 8 carbon atoms, which may or may not carry up to z ethylene oxide units,z is from 1 to 6,A is a polymer or copolymer block of from 4 to 100 1,4-butylene oxide units and from 0 to 25 ethylene oxide units andB is a polymer or copolymer block of from 0 to 50 1,4-butylene oxide units and from 1 to 100 ethylene oxide units, the proportion of 1,4-butylene oxide being >50 mole % in A and

    摘要翻译： 含有5〜25重量％的结合碘的含碘嵌段共聚物，其基于式IR（AB）zI的无碘化合物，其中如果z = 1，R为氢或C1-C18- 脂族烃基，如果z NOTEQUAL 1，R是2至8个碳原子的z价脂族烃基，其可以或可以不携带至z环氧乙烷单元，z为1-6，A为聚合物或 共聚物嵌段为4至100个1,4-环氧丁烷单元和0至25个环氧乙烷单元，B为0至50个1,4-环氧丁烷单元和1至100个环氧乙烷单元的聚合物或共聚物嵌段 ，A环中1,4-环氧丁烷的比例> 50摩尔％，B中的<50摩尔％

    Liquid detergent with copolymer additive
    5.
    发明授权
    Liquid detergent with copolymer additive 失效
    液体洗涤剂与共聚添加剂

    公开(公告)号：US5009805A

    公开(公告)日：1991-04-23

    申请号：US424084

    申请日：1989-10-19

    申请人： Johannes Perner ,  Paul Diessel ,  Heinrich Hartmann ,  Walter Denzinger ,  Alfred Oftring ,  Willibald Schoenleben

    发明人： Johannes Perner ,  Paul Diessel ,  Heinrich Hartmann ,  Walter Denzinger ,  Alfred Oftring ,  Willibald Schoenleben

    IPC分类号： C11D3/32 ,  C11D3/37

    CPC分类号： C11D3/3773

    摘要： Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.1,and has a K value of from 8 to 200, or a salt thereof.

    摘要翻译： 液体洗涤剂配方含有表面活性剂和0.1-20重量％的共聚物，其含有（a）50-99摩尔％的单烯属不饱和C3-C8-单羧酸单元，单烯属不饱和C4-C8-二羧酸 酸，单烯键式不饱和C4-C8-二羧酸的半酯，单烯属不饱和C3-C8-一元羧酸的酯，C2-C30-烯烃，苯乙烯，C1-C3-烷基苯乙烯，C1-C28- 烷基乙烯基醚，饱和C1-C8-一元羧酸的乙烯基酯或其混合物，和（b）50-1摩尔％的单烯属不饱和C 3 -C 8 - 羧酸的酰胺单元，其中酰胺基具有 其中R 1为C 8 -C 28 - 烷基或优选R 3和R 4各自为H，CH 3或C 2 H 5，R为C 1 -C 28 - 烷基，n为2至100，R 2为H或R 1，并且 的K值为8〜200，或其盐。

    Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties
    8.
    发明授权
    Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties 失效
    稳定的液体洗涤剂组合物具有增强的粘土污垢去污力和抗再沉积性能

    公开(公告)号：US5049302A

    公开(公告)日：1991-09-17

    申请号：US254467

    申请日：1988-10-06

    申请人： Richard J. Holland ,  Ornie K. Bullard ,  Alicia V. York ,  Dieter Boeckh ,  Wolfgang Trieselt ,  Paul Diessel ,  Hans-Ulrich Jaeger

    发明人： Richard J. Holland ,  Ornie K. Bullard ,  Alicia V. York ,  Dieter Boeckh ,  Wolfgang Trieselt ,  Paul Diessel ,  Hans-Ulrich Jaeger

    IPC分类号： C11D1/83 ,  C11D3/00 ,  C11D3/22 ,  C11D3/37

    CPC分类号： C11D1/83 ,  C11D3/0036 ,  C11D3/225 ,  C11D3/3788

    摘要： A stable liquid detergent composition having improved clay soil detergency, clay soil anti-redeposition, oily soil anti-redeposition and soil release properties is disclosed. The detergent composition is comprised of an anionic surfactant, a nonionic surfactant, a hydrotrope, a graft copolymer of polyalkylene oxide and an ester monomer, and a nonionic cellulosic anti-redeposition agent. The graft copolymer is comprised of (a) a polyalkylene oxide based upon an alkylene oxide having from 2 to 4 carbon atoms having a molecular weight of 300 to 100,000 and, (b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms, and/or methyl or ethyl ester of acrylic or meth-acrylic acid in a weight ratio of (a):(b) of from 1:0.2 to 1:10. The nonionic cellulosic anti-redeposition agent is preferably hydroxypropyl methylcellulose. There is a synergism between the nonionic anti-redeposition agent and the graft polyol which imparts improved clay soil detergency, clay anti-deposition and oily soil anti-redeposition properties to the detergent composition.

    摘要翻译： 公开了一种稳定的液体洗涤剂组合物，其具有改进的粘土污垢去污力，粘土污垢抗再沉积，油性土壤抗再沉积和脱土性质。 洗涤剂组合物由阴离子表面活性剂，非离子表面活性剂，水溶助长剂，聚环氧烷和酯单体的接枝共聚物和非离子纤维素抗再沉积剂组成。 接枝共聚物包含（a）基于分子量为300至100,000的具有2至4个碳原子的烯化氧的聚亚烷基氧化物，和（b）至少一种衍生自饱和一元羧酸的乙烯基酯，其含有1 至（6）个碳原子，和/或丙烯酸或甲基丙烯酸的甲酯或乙酯，重量比（a）：（b）为1:0.2至1:10。 非离子纤维素抗再沉积剂优选为羟丙基甲基纤维素。 非离子抗再沉积剂和接枝多元醇之间存在协同作用，其赋予洗涤剂组合物改进的粘土污垢去污力，粘土抗沉积和油性土壤抗再沉积性能。