-
公开(公告)号：US5491271A
公开(公告)日：1996-02-13
申请号：US296391
申请日：1994-08-26
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2521/16 , C07C2529/05
摘要： Tetrahedrally charged clays have been found to be active, regenerable catalysts in detergent alkylation, both as delaminated and pillared clays. The pillared saponites and beidellites are especially favored in forming detergent range alkylates using olefins as the alkylating agent to afford products with high monoalkylation selectivity and high linearity. Catalysts can be regenerated by a benzene wash or, after severe deactivation, by a carbon burn.
摘要翻译： 已经发现四面带电荷的粘土是洗涤剂烷基化中的活性的可再生催化剂，作为分层和柱状粘土。 在使用烯烃作为烷基化剂形成洗涤剂范围的烷基化物时，柱状皂石和小卫星特别有利，以获得具有高单烷基化选择性和高线性度的产物。 催化剂可以通过苯洗涤或在严重失活后通过碳燃烧再生。
-
2.发明授权Catalyst for minimizing the H.sub.2 S emissions from automotive exhaust and method of its manufacture 失效催化剂用于最大限度地减少汽车排气中的H2S排放及其制造方法
公开(公告)号：US4760044A
公开(公告)日：1988-07-26
申请号：US62024
申请日：1987-06-15
CPC分类号： B01D53/945 , B01J23/63 , B01J37/04 , Y02T10/22
摘要： This invention relates to a catalytic composite comprising a mixture of a primary refractory inorganic oxide having dispersed thereon at least one first active component selected from the group consisting of rare earth oxides and a secondary support consisting of zirconia, titania or cerium oxide having dispersed thereon at least one second active component selected from the group consisting of metals which form a stable sulfide said mixture having at least one main catalytic metal selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium deposited thereon. This invention also relates to a method of manufacturing said catalytic composite. Finally a method to minimize the formation of H.sub.2 S when automotive exhaust is contacted with a catalytic composite is also claimed.
摘要翻译： 本发明涉及一种催化复合材料，其包含主要耐火无机氧化物的混合物，其中分散有至少一种选自稀土氧化物的第一活性组分和由分散在其上的氧化锆，二氧化钛或氧化铈组成的组的第二载体 选自由形成稳定硫化物的金属组成的组中的至少一种活性组分，所述混合物具有选自铂，钯，铑，钌和铱的至少一种主要催化金属。 本发明还涉及制造所述催化剂复合材料的方法。 最后，还要求保护汽车尾气与催化复合材料接触时最小化H2S形成的方法。
-
3.发明授权Arylalkane sulfonate compositions produced using isomerization, dehydrogenation, and alkylation 失效使用异构化，脱氢和烷基化生产的芳基磺酸盐组合物公开(公告)号：US06515169B1
公开(公告)日：2003-02-04
申请号：US10205672
申请日：2002-07-25
IPC分类号： C07C30928
CPC分类号： C07C15/107 , C07C2529/18 , C07C2529/70 , C10M105/06 , C10M2203/06
摘要： The present invention is a process for producing aryl-alkanes by paraffin isomerization followed by paraffin dehydrogenation and then by alkylation of an aryl compound by a lightly branched olefin. The effluent of the alkylation zone comprises paraffins that are recycled to the isomerization step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过石蜡异构化，然后进行链烷烃脱氢，然后通过轻支化烯烃烷基化芳基化合物来制备芳基烷烃的方法。 烷基化区的流出物包括再循环到异构化步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
-
4.发明授权Integrated process for producing diisopropyl ether, an isopropyl tertiary alkyl ether and isopropyl alcohol 失效用于生产二异丙醚，异丙基叔烷基醚和异丙醇的一体化方法
公开(公告)号：US5705712A
公开(公告)日：1998-01-06
申请号：US539394
申请日：1995-10-05
CPC分类号： C07C41/06 , C07C41/09 , Y02P20/125
摘要： A highly integrated process for concurrently producing diisopropyl ether and an isopropyl tertiary alkyl ether has been developed. Optionally, high purity isopropyl alcohol may also be collected as a product. In a first reactor, propylene and water are reacted to form isopropyl alcohol, a portion of which is further reacted to form diisopropyl ether. After removing unreacted propylene, the effluent of the first reactor is separated into an ether rich stream, a water rich stream and an alcohol rich stream. The alcohol rich stream is dried to provide dry isopropyl alcohol. A portion of the dry isopropyl alcohol may be removed and collected as a product. A portion of the dry isopropyl alcohol and isobutylene, isoamylene or a mixture thereof are reacted to form an isopropyl tertiary alkyl ether in a second reactor. Unreacted iso-olefins and inert compounds are then removed from the second reactor effluent. A mixture of the effluent from the second reactor and the ether rich and the water rich streams separated from the first reactor are water washed to produce a mixed ethers product stream and an aqueous isopropyl alcohol recycle stream. The isopropyl tertiary alkyl ether is collected along with the diisopropyl ether in the mixed ethers product stream from the water wash. A modified flowscheme of the process is also discussed.
摘要翻译： 已经开发了用于同时生产二异丙醚和异丙基叔烷基醚的高度一体化的方法。 任选地，也可以收集高纯度异丙醇作为产物。 在第一反应器中，使丙烯和水反应形成异丙醇，其中一部分进一步反应形成二异丙醚。 在除去未反应的丙烯之后，将第一反应器的流出物分离成富醚流，富水流和富醇流。 将富醇流干燥以提供干燥的异丙醇。 干燥的异丙醇的一部分可以作为产品被去除和收集。 一部分干异丙醇和异丁烯，异戊烯或其混合物在第二反应器中反应形成异丙基叔烷基醚。 然后从第二反应器流出物中除去未反应的异烯烃和惰性化合物。 将来自第二反应器的流出物和富含醚的混合物和从第一反应器分离的富水物流的混合物进行水洗以产生混合醚产物流和异丙醇水反应物水。 异丙基叔烷基醚与来自水洗的混合醚产物流中的二异丙醚一起收集。 还讨论了该过程的修改流程。
-
公开(公告)号：US20090162264A1
公开(公告)日：2009-06-25
申请号：US12238980
申请日：2008-09-26
IPC分类号： B01J19/00
CPC分类号： C10G45/02 , C10G45/12 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/16 , C10G65/043 , C10G65/12 , C10G2300/1011 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process has been developed for producing aviation fuel from renewable feedstocks such as plant oils and animals fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide n-paraffins having from about 8 to about 24 carbon atoms. At least some of the n-paraffins are isomerized to improve cold flow properties. At least a portion of the paraffins are selectively cracked to provide paraffins meeting specifications for different fuels such as JP-8.
摘要翻译： 已经开发了用于从可再生原料如植物油和动物脂肪和油生产航空燃料的过程。 该方法包括通过氢化和脱氧处理可再生原料以提供具有约8至约24个碳原子的正链烷烃。 至少一些正链烷烃被异构化以改善冷流特性。 选择性裂化至少一部分链烷烃以提供满足不同燃料如JP-8的规格的石蜡。
-
6.发明授权Integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether 失效用于生产二异丙醚和异丙基叔烷基醚的一体化方法
公开(公告)号：US5689014A
公开(公告)日：1997-11-18
申请号：US539577
申请日：1995-10-05
CPC分类号： C07C41/06 , C07C41/09 , Y02P20/125
摘要： A highly integrated process for concurrently producing diisopropyl ether and an isopropyl tertiary alkyl ether has been developed. In a first reactor, propylene and water are reacted to form isopropyl alcohol, a portion of which is further reacted to form diisopropyl ether. After removing unreacted propylene, the effluent of the first reactor is separated into an ether rich stream, a water rich stream and an alcohol rich stream. The alcohol rich stream and isobutylene, isoamylene or a mixture thereof are reacted to form an isopropyl tertiary alkyl ether in a second reactor. The water present in the alcohol rich stream also reacts with the iso-olefin to form tertiary alcohol. The effluent from the second reactor is water washed to produce an oxygenate product stream and an aqueous alcohol recycle stream. Some tertiary alcohol is recycled to the first reactor where it is reacted with propylene to form additional isopropyl tertiary alkyl ether. The isopropyl tertiary alkyl ether and some tertiary alcohol is collected along with the diisopropyl ether in the mixed oxygenate product stream from the water wash.
摘要翻译： 已经开发了用于同时生产二异丙醚和异丙基叔烷基醚的高度一体化的方法。 在第一反应器中，使丙烯和水反应形成异丙醇，其中一部分进一步反应形成二异丙醚。 在除去未反应的丙烯之后，将第一反应器的流出物分离成富醚流，富水流和富醇流。 使富含醇的物流和异丁烯，异戊烯或其混合物在第二反应器中反应形成异丙基叔烷基醚。 存在于富酒精料流中的水也与异烯烃反应形成叔醇。 将来自第二反应器的流出物进行水洗以产生含氧化合物产物流和含水酒精循环流。 一些叔醇被再循环到第一反应器中，在其中与丙烯反应形成另外的异丙基叔烷基醚。 异丙基叔烷基醚和一些叔醇与来自水洗的混合的含氧化合物产物流中的二异丙醚一起收集。
-
7.发明授权公开(公告)号：US07795483B2
公开(公告)日：2010-09-14
申请号：US10658703
申请日：2003-09-09
申请人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
发明人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
CPC分类号： C07C7/13
摘要： The present invention is a process for producing phenyl-alkanes by paraffin adsorptive separation followed by paraffin dehydrogenation and then by alkylation of a phenyl compound by a lightly branched olefin. The adsorptive separation step employs a silicalite adsorbent and, as the desorbent, a C5-C8 linear paraffin, a C5-C8 cycloparaffin, a branched paraffin such as isooctane, or mixtures thereof. The effluent of the alkylation zone comprises paraffins that are recycled to the adsorptive separation step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过链烷烃吸附分离然后进行链烷烃脱氢然后通过轻支化烯烃烷基化苯基化合物来生产苯基烷烃的方法。 吸附分离步骤使用硅沸石吸附剂，并且作为解吸剂，使用C5-C8直链石蜡，C5-C8环烷烃，支链链烷烃如异辛烷，或其混合物。 烷基化区的流出物包括再循环到吸附分离步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
-
8.发明授权公开(公告)号：US06617481B1
公开(公告)日：2003-09-09
申请号：US09650886
申请日：2000-08-29
申请人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
发明人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
IPC分类号： C07C266
CPC分类号： C07C7/13
摘要： The present invention is a process for producing phenyl-alkanes by paraffin adsorptive separation followed by paraffin dehydrogenation and then by alkylation of a phenyl compound by a lightly branched olefin. The adsorptive separation step employs a silicalite adsorbent and, as the desorbent, a C5-C8 linear paraffin, a C5-C8 cycloparaffin, a branched paraffin such as isooctane, or mixtures thereof. The effluent of the alkylation zone comprises paraffins that are recycled to the adsorptive separation step or to the dehydrogenation step. This invention is also a process that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过链烷烃吸附分离然后进行链烷烃脱氢然后通过轻支化烯烃烷基化苯基化合物来生产苯基烷烃的方法。 吸附分离步骤使用硅沸石吸附剂，并且作为解吸剂，使用C5-C8直链石蜡，C5-C8环烷烃，支链链烷烃如异辛烷，或其混合物。 烷基化区的流出物包括再循环到吸附分离步骤或脱氢步骤的链烷烃。 本发明也是一种使具有轻支化脂族烷基的苯基烷烃磺化以生产改性烷基苯磺酸盐的方法。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
-
公开(公告)号：US06521804B1
公开(公告)日：2003-02-18
申请号：US09939059
申请日：2001-08-24
IPC分类号： C07C5107
CPC分类号： C07C2/66 , C07C5/222 , C07C2529/06 , C07C2529/18
摘要： The present invention is a process for producing phenyl-alkanes by alkylation of an aryl compound with an olefinic compound and which uses a mordenite catalyst and a silica-alumina catalyst. This invention is also a process that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过用烯烃化合物烷基化芳基化合物并使用丝光沸石催化剂和二氧化硅 - 氧化铝催化剂来生产苯基烷烃的方法。 本发明也是使具有轻支化脂族烷基的苯基烷烃磺化以产生改性烷基苯磺酸盐的方法。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
-
10.发明授权Process for producing arylalkanes at alkylation conditions using a zeolite having a NES zeolite structure type 有权在烷基化条件下使用具有NES沸石结构类型的沸石制备芳基烷烃的方法
公开(公告)号：US6111158A
公开(公告)日：2000-08-29
申请号：US262249
申请日：1999-03-04
IPC分类号： B01J29/70 , C07C2/66 , C07C2/68 , C07C2/64 , C07C25/107
CPC分类号： C07C2/66 , B01J29/70 , B01J2229/26 , B01J2229/42 , C07C2529/70
摘要： The present invention is a process for producing phenyl-alkanes at alkylation conditions in the presence of a zeolite having an NES zeolite structure type, such as NU-87. This invention produces phenyl-alkanes having lightly branched aliphatic alkyl groups which are used to produce modified alkylbenzene sulfonates that have improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates.
摘要翻译： 本发明是在具有NES沸石结构类型的沸石（如NU-87）的存在下，在烷基化条件下生产苯基烷烃的方法。 本发明产生具有轻支化脂族烷基的苯基烷烃，其用于生产改性烷基苯磺酸盐，其在硬水和/或冷水中具有改善的清洁效果，同时还具有与直链烷基苯磺酸盐相当的生物降解性。
-
-
-
-
-
-
-
-
-
搜索结果
22 条记录 (耗时 0.026 秒)
