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    MACROSCOPIC ORDERED ASSEMBLY OF CARBON NANOTUBES
    1.
    发明申请
    MACROSCOPIC ORDERED ASSEMBLY OF CARBON NANOTUBES 审中-公开
    碳纳米管的大型订购总成

    公开(公告)号：US20080210370A1

    公开(公告)日：2008-09-04

    申请号：US11840033

    申请日：2007-08-16

    申请人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Deron A. Walters ,  Michael J. Casavant ,  Chad B. Huffman ,  Boris I. Yakobson ,  Robert H. Hauge ,  Rajesh Kumar Saini ,  Wan-Ting Chiang ,  Xiao Chuan Qin

    发明人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Deron A. Walters ,  Michael J. Casavant ,  Chad B. Huffman ,  Boris I. Yakobson ,  Robert H. Hauge ,  Rajesh Kumar Saini ,  Wan-Ting Chiang ,  Xiao Chuan Qin

    IPC分类号： C01B31/02 ,  B32B37/00 ,  B05D3/00 ,  B01J19/00 ,  B03C1/32

    CPC分类号： B82Y40/00 ,  B82Y10/00 ,  B82Y30/00 ,  C01B32/168 ,  C01B2202/02 ,  C01B2202/08 ,  H01J2201/30469 ,  Y10S977/75 ,  Y10S977/845 ,  Y10S977/847 ,  Y10T156/10

    摘要： The present invention is directed to the creation of macroscopic materials and objects comprising aligned nanotube segments. The invention entails aligning single-wall carbon nanotube (SWNT) segments that are suspended in a fluid medium and then removing the aligned segments from suspension in a way that macroscopic, ordered assemblies of SWNT are formed. The invention is further directed to controlling the natural proclivity or nanotube segments to self assemble into or ordered structures by modifying the environment of the nanotubes and the history of that environment prior to and during the process. The materials and objects are “macroscopic” in that they are large enough to be seen without the aid of a microscope or of the dimensions of such objects. These macroscopic ordered SWNT materials and objects have the remarkable physical, electrical, and chemical properties that SWNT exhibit on the microscopic scale because they are comprised of nanotubes, each of which is aligned in the same direction and in contact with its nearest neighbors. An ordered assembly of closest SWNT also serves as a template for growth of more and larger ordered assemblies. An ordered assembly further serves as a foundation for post processing treatments that modify the assembly internally to specifically enhance selected material properties such as shear strength, tensile strength, compressive strength, toughness, electrical conductivity, and thermal conductivity.

    摘要翻译： 本发明涉及包括对准的纳米管段的宏观材料和物体的产生。 本发明需要将悬浮在流体介质中的单壁碳纳米管（SWNT）段对准，然后以形成SWNT的宏观有序组件的方式从悬浮液中除去对准的段。 本发明进一步涉及通过在工艺之前和期间修改纳米管的环境和该环境的历史来控制天然倾向或纳米管段自组装成或有序的结构。 材料和物体是“宏观的”，因为它们足够大以便在没有显微镜或这些物体的尺寸的情况下被看到。 这些宏观有序的SWNT材料和物体具有卓越的物理，电学和化学性质，SWNT在微观尺度上显示，因为它们由纳米管组成，其中每个纳米管沿相同方向对齐并与其最近的邻近物接触。 最近的SWNT的有序组件也可以作为增加更多和更大订单组件的模板。 订购的组件还用作后处理处理的基础，其在内部改变组件以特异性地增强选定的材料性能，例如剪切强度，抗拉强度，抗压强度，韧性，导电性和导热性。

    Macroscopic ordered assembly of carbon nanotubes
    2.
    发明授权
    Macroscopic ordered assembly of carbon nanotubes 有权
    宏观有序的碳纳米管组装

    公开(公告)号：US06790425B1

    公开(公告)日：2004-09-14

    申请号：US09890030

    申请日：2001-07-24

    申请人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Deron A. Walters ,  Michael J. Casavant ,  Chad B. Huffman ,  Boris I. Yakobson ,  Robert H. Hague ,  Rajesh Kumar Saini ,  Wan-Ting Chiang

    发明人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Deron A. Walters ,  Michael J. Casavant ,  Chad B. Huffman ,  Boris I. Yakobson ,  Robert H. Hague ,  Rajesh Kumar Saini ,  Wan-Ting Chiang

    IPC分类号： D01F912

    CPC分类号： B82Y40/00 ,  B82Y10/00 ,  B82Y30/00 ,  C01B32/168 ,  C01B2202/02 ,  C01B2202/08 ,  H01J2201/30469 ,  Y10S977/75 ,  Y10S977/845 ,  Y10S977/847 ,  Y10T156/10

    摘要： The present invention is directed to the creation of macroscopic materials and objects comprising aligned nanotube segments. The invention entails aligning single-wall carbon nanotube (SWNT) segments that are suspended in a fluid medium and then removing the aligned segments from suspension in a way that macroscopic, ordered assemblies of SWNT are formed. The invention is further directed to controlling the natural proclivity of nanotube segments to self assemble into ordered structures by modifying the environment of the nanotubes and the history of that environment prior to and during the process. The materials and objects are “macroscopic” in that they are large enough to be seen without the aid of a microscope or of the dimensions of such objects. These macroscopic, ordered SWNT materials and objects have the remarkable physical, electrical, and chemical properties that SWNT exhibit on the microscopic scale because they are comprised nanotubes, each of which is aligned in the same direction and in contact with its nearest neighbors. An ordered assembly of closest SWNT also serves as a template for growth of more and larger ordered assemblies. An ordered assembly further serves as a foundation for post processing treatments that modify the assembly internally to specifically enhance selected material properties such as shear strength, tensile strength, compressive strength, toughness, electrical conductivity, and thermal conductivity.

    摘要翻译： 本发明涉及包括对准的纳米管段的宏观材料和物体的产生。 本发明需要将悬浮在流体介质中的单壁碳纳米管（SWNT）段对准，然后以形成SWNT的宏观有序组件的方式从悬浮液中除去对准的段。 本发明进一步涉及通过在过程之前和过程中修改纳米管的环境和该环境的历史来控制纳米管段的自然倾向自我组装成有序结构。 材料和物体是“宏观的”，因为它们足够大以便在没有显微镜或这些物体的尺寸的情况下被看到。 这些宏观有序的SWNT材料和物体具有显着的物理，电学和化学性质，SWNT在微观尺度上显示，因为它们包含纳米管，每个纳米管沿相同方向排列并与其最近的邻近物接触。 最近的SWNT的有序组件也可以作为增加更多和更大订单组件的模板。 订购的组件还用作后处理处理的基础，其在内部改变组件以特异性地增强选定的材料性能，例如剪切强度，抗拉强度，抗压强度，韧性，导电性和导热性。

    POLYMER-WRAPPED SINGLE-WALL CARBON NANOTUBES
    3.
    发明申请
    POLYMER-WRAPPED SINGLE-WALL CARBON NANOTUBES 审中-公开
    聚合物包裹单壁碳纳米管

    公开(公告)号：US20100143718A1

    公开(公告)日：2010-06-10

    申请号：US11847566

    申请日：2007-08-30

    申请人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Michael O'Connell

    发明人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Michael O'Connell

    IPC分类号： B32B5/02

    CPC分类号： C08K9/08 ,  B82Y10/00 ,  B82Y30/00 ,  D01F11/14 ,  H01C17/0652 ,  H01L51/0048 ,  H01L51/0052 ,  H01Q17/002 ,  H05K1/0373 ,  H05K1/162 ,  Y02E60/364 ,  Y10S977/745 ,  Y10S977/746 ,  Y10S977/748 ,  Y10S977/75 ,  Y10S977/783 ,  Y10T428/2935 ,  Y10T428/2991 ,  Y10T428/2998

    摘要： The present invention relates to new compositions of matter and articles of manufacture comprising SWNTs as nanometer scale conducting rods dispersed in an electrically-insulating matrix. These compositions of matter have novel and useful electrical, mechanical, and chemical properties including applications in antennas, electromagnetic and electro-optic devices, and high-toughness materials. Other compositions of matter and articles of manufacture are disclosed. including polymer-coated and polymer wrapped single-wall nanotubes (SWNTs), small ropes of polymer-coated and polymer-wrapped SWNTs and materials comprising same. This composition provides one embodiment of the SWNT conducting-rod composite mentioned above, and also enables creation of high-concentration suspensions of SWNTs and compatibilization of SWNTs with polymeric matrices in composite materials. This solubilization and compatibilization, in turn, enables chemical manipulation of SWNT and production of composite fibers, films, and solids comprising SWNTs.

    摘要翻译： 本发明涉及包含分散在电绝缘基质中的纳米级导电棒的SWNT的物质和制品的新组合物。 这些物质组合物具有新颖且有用的电学，机械和化学性质，包括在天线，电磁和电光器件以及高韧性材料中的应用。 公开了其他物质组合物和制品。 包括聚合物涂覆的和聚合物包裹的单壁纳米管（SWNT），聚合物涂覆的和聚合物包裹的SWNT的小绳索以及包含它们的材料。 该组合物提供了上述SWNT导电棒复合材料的一个实施方案，并且还能够形成SWNT的高浓度悬浮液，并且使复合材料中的SWNT与聚合物基质相容化。 这种增溶和相容反过来又能使SWNT的化学操作和复合纤维，薄膜和包含SWNT的固体的生产。

    Single-wall carbon nanotubes from high pressure CO
    5.
    发明授权
    Single-wall carbon nanotubes from high pressure CO 有权
    单壁碳纳米管由高压CO

    公开(公告)号：US07204970B2

    公开(公告)日：2007-04-17

    申请号：US10730630

    申请日：2003-12-08

    申请人： Richard E. Smalley ,  Ken A. Smith ,  Daniel T. Colbert ,  Pavel Nikolaev ,  Michael J. Bronikowski ,  Robert K. Bradley ,  Frank Rohmund

    发明人： Richard E. Smalley ,  Ken A. Smith ,  Daniel T. Colbert ,  Pavel Nikolaev ,  Michael J. Bronikowski ,  Robert K. Bradley ,  Frank Rohmund

    IPC分类号： C01B11/02

    CPC分类号： B01J4/002 ,  B01J3/04 ,  B01J3/042 ,  B01J19/121 ,  B01J19/26 ,  B01J2219/0875 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/02 ,  C01B2202/36 ,  D01F9/1278 ,  Y10S977/75 ,  Y10S977/751 ,  Y10S977/843 ,  Y10S977/845 ,  Y10S977/951 ,  Y10T428/30

    摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.

    摘要翻译： 本发明公开了提供已被预热（例如，约1000℃）的高压（例如30个大气压）的CO和催化剂前体气体（例如Fe（CO）5） >）在CO中，其保持低于催化剂前体分解温度至混合区。 在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长 。 优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。 这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。 在这些条件下，SWNT根据Boudouard反应成核并生长。 如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

    Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure CO
    7.
    发明授权
    Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure CO 有权
    单壁碳纳米管从高压CO气相成核和生长

    公开(公告)号：US06761870B1

    公开(公告)日：2004-07-13

    申请号：US09830642

    申请日：2002-07-01

    申请人： Richard E. Smalley ,  Ken A. Smith ,  Daniel T. Colbert ,  Pavel Nikolaev ,  Michael J. Bronikowski ,  Robert K. Bradley ,  Frank Rohmund

    发明人： Richard E. Smalley ,  Ken A. Smith ,  Daniel T. Colbert ,  Pavel Nikolaev ,  Michael J. Bronikowski ,  Robert K. Bradley ,  Frank Rohmund

    IPC分类号： D01F912

    CPC分类号： B01J4/002 ,  B01J3/04 ,  B01J3/042 ,  B01J19/121 ,  B01J19/26 ,  B01J2219/0875 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/02 ,  C01B2202/36 ,  D01F9/1278 ,  Y10S977/75 ,  Y10S977/751 ,  Y10S977/843 ,  Y10S977/845 ,  Y10S977/951 ,  Y10T428/30

    摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.

    摘要翻译： 本发明公开了在被保留的CO中提供已被预热（例如，约1000℃）的高压（例如，30个大气压）的CO和催化剂前体气体（例如，Fe（CO）5）的过程。 催化剂前体分解温度低于混合区。 在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长 。 优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。 这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。 在这些条件下，SWNT根据Boudouard反应成核并生长。 如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

    Polymer-wrapped single wall carbon nanotubes
    8.
    发明授权
    Polymer-wrapped single wall carbon nanotubes 有权
    聚合物包裹的单壁碳纳米管

    公开(公告)号：US07264876B2

    公开(公告)日：2007-09-04

    申请号：US09935995

    申请日：2001-08-23

    申请人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Michael O'Connell

    发明人： Richard E. Smalley ,  Daniel T. Colbert ,  Ken A. Smith ,  Michael O'Connell

    IPC分类号： B32B5/16

    CPC分类号： C08K9/08 ,  B82Y10/00 ,  B82Y30/00 ,  D01F11/14 ,  H01C17/0652 ,  H01L51/0048 ,  H01L51/0052 ,  H01Q17/002 ,  H05K1/0373 ,  H05K1/162 ,  Y02E60/364 ,  Y10S977/745 ,  Y10S977/746 ,  Y10S977/748 ,  Y10S977/75 ,  Y10S977/783 ,  Y10T428/2935 ,  Y10T428/2991 ,  Y10T428/2998

    摘要： The present invention relates to new compositions of matter and articles of manufacture comprising SWNTs as nanometer scale conducting rods dispersed in an electrically-insulating matrix. These compositions of matter have novel and useful electrical, mechanical, and chemical properties including applications in antennas, electromagnetic and electro-optic devices, and high-toughness materials. Other compositions of matter and articles of manufacture are disclosed. including polymer-coated and polymer wrapped single-wall nanotubes (SWNTs), small ropes of polymer-coated and polymer-wrapped SWNTs and materials comprising same. This composition provides one embodiment of the SWNT conducting-rod composite mentioned above, and also enables creation of high-concentration suspensions of SWNTs and compatibilization of SWNTs with polymeric matrices in composite materials. This solubilization and compatibilization, in turn, enables chemical manipulation of SWNT and production of composite fibers, films, and solids comprising SWNTs.

    摘要翻译： 本发明涉及包含分散在电绝缘基质中的纳米级导电棒的SWNT的物质和制品的新组合物。 这些物质组合物具有新颖且有用的电学，机械和化学性质，包括在天线，电磁和电光器件以及高韧性材料中的应用。 公开了其他物质组合物和制品。 包括聚合物涂覆的和聚合物包裹的单壁纳米管（SWNT），聚合物涂覆的和聚合物包裹的SWNT的小绳索以及包含它们的材料。 该组合物提供了上述SWNT导电棒复合材料的一个实施方案，并且还能够形成SWNT的高浓度悬浮液，并且在复合材料中使SWNT与聚合物基质相容化。 这种增溶和相容反过来又能使SWNT的化学操作和复合纤维，薄膜和包含SWNT的固体的生产。