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    Sulfonated alkylamines as degreasers and hydrotropes
    1.
    发明授权
    Sulfonated alkylamines as degreasers and hydrotropes 失效
    磺化烷基胺作为脱脂剂和水溶助长剂

    公开(公告)号：US06306816B1

    公开(公告)日：2001-10-23

    申请号：US09757192

    申请日：2001-01-09

    Applicant: Philip W. Pike ,  Bryan A. Grisso ,  Richard W. Jahnke

    Inventor： Philip W. Pike ,  Bryan A. Grisso ,  Richard W. Jahnke

    IPC: C11D1755

    CPC classification number: C07C309/15 ,  C11D1/28 ,  C11D1/83

    Abstract: The reaction product of an alkylenediamine, each amino group thereof being a primary or secondary amino group; with at least two equivalents of an acrylamidoalkanesulfonic acid or a salt thereof, wherein each amine nitrogen atom of said alkylenediamine is reacted with a single molecule of the acrylamidoalkane sulfonic acid or salt thereof provides a useful surfactant or hydrotrope.

    Abstract translation: 亚烷基二胺的反应产物，其各自的氨基为伯或仲氨基; 与至少两当量的丙烯酰氨基烷烃磺酸或其盐，其中所述亚烷基二胺的每个胺氮原子与单分子的丙烯酰氨基烷烃磺酸或其盐反应提供有用的表面活性剂或水溶助长剂。

    Compositions containing derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same
    2.
    发明授权
    Compositions containing derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same 失效
    含有琥珀酰化剂或羟基芳族化合物的衍生物的组合物及其使用方法

    公开(公告)号：US5637557A

    公开(公告)日：1997-06-10

    申请号：US241830

    申请日：1994-05-12

    Applicant: Richard W. Jahnke ,  John W. Forsberg

    Inventor： Richard W. Jahnke ,  John W. Forsberg

    IPC: B01F17/00 ,  C09K8/28 ,  C09K8/36 ,  C09K7/00

    CPC classification number: C09K8/28 ,  B01F17/0021 ,  B01F17/0042 ,  B01F17/005 ,  C09K8/36

    Abstract: This invention relates to a composition comprising: a mixture of a brine and a liquid oil, and (A) an emulsifying amount of (i) at least one reaction product of a hydrocarbyl-substituted succinic acylating agent, and at least one of (a) ammonia, (b) an alcohol, (c) an amine, (d) or mixtures thereof, or at least one salt of the reaction product; or (ii) at least one reaction product of a hydroxyaromatic compound, an aldehyde, and an amine. The compositions of the present invention have beneficial emulsification properties. These compositions are useful in drilling, working over and completing well-bore holes. The well-drilling compositions of the present invention have beneficial viscosity, pumping and suspension properties.

    Abstract translation: 本发明涉及一种组合物，其包含：盐水和液体油的混合物，和（A）乳化量的（i）至少一种烃基取代的琥珀酰化剂的反应产物和（a ）氨，（b）醇，（c）胺，（d）或其混合物，或至少一种反应产物的盐; 或（ii）至少一种羟基芳族化合物，醛和胺的反应产物。 本发明的组合物具有有益的乳化性能。 这些组合物可用于钻孔，加工和完井孔。 本发明的钻井组合物具有有益的粘度，泵送和悬浮性能。

    Compositions containing esters of carboxy-containing interpolymers and methods of using the same
    3.
    发明授权
    Compositions containing esters of carboxy-containing interpolymers and methods of using the same 失效
    含有含羧基的共聚体的酯的组合物及其使用方法

    公开(公告)号：US5283235A

    公开(公告)日：1994-02-01

    申请号：US853064

    申请日：1992-03-17

    Applicant: James H. Bush ,  Richard W. Jahnke ,  Lawrence J. Kocurek

    Inventor： James H. Bush ,  Richard W. Jahnke ,  Lawrence J. Kocurek

    IPC: C09K8/28 ,  C09K8/36 ,  C09K7/02

    CPC classification number: C09K8/36 ,  C09K8/28

    Abstract: This invention relates to a composition comprising a mixture of a brine and a liquid hydrocarbon, and (A) a viscosity increasing amount of at least one ester of a carboxy-containing interpolymer or salt thereof wherein the interpolymer is prepared by polymerizing an olefin selected from the group consisting of alpha-olefins and vinyl aromatic monomers with at least one alpha, beta-unsaturated carboxylic acylating agent, and provided that when the olefin is vinyl toluene, then the alpha, beta-unsaturated carboxylic acylating agent is an alpha, beta-unsaturated dicarboxylic acylating agent. The compositions of the present invention are useful as drilling fluids as well as completion fluids. The esters of the carboxy-containing interpolymer or salts thereof provide beneficial viscosity, formation stabilization, emulsification and rheology properties to the fluids.

    Abstract translation: 本发明涉及包含盐水和液体烃的混合物的组合物，和（A）粘度增加量的至少一种含羧基的互聚物或其盐的酯，其中互聚物是通过将选自 由具有至少一种α，β-不饱和羧酸酰化剂的α-烯烃和乙烯基芳族单体组成的组，并且当烯烃为乙烯基甲苯时，α，β-不饱和羧酸酰化剂为α，β-不饱和羧酸酰化剂， 不饱和二羧酸酰化剂。 本发明的组合物可用作钻井液和完井液。 含羧基的互聚物或其盐的酯为流体提供有益的粘度，形成稳定性，乳化和流变性质。

    Corrosion-inhibiting compositions, and oil compositions containing said corrosion-inhibiting compositions
    5.
    发明授权
    Corrosion-inhibiting compositions, and oil compositions containing said corrosion-inhibiting compositions 失效
    腐蚀抑制组合物和含有所述腐蚀抑制组合物的油组合物

    公开(公告)号：US4618539A

    公开(公告)日：1986-10-21

    申请号：US678731

    申请日：1984-12-06

    Applicant: Richard W. Jahnke ,  William C. Woerner

    Inventor： Richard W. Jahnke ,  William C. Woerner

    IPC: C10M159/12 ,  C10M141/12 ,  C10M163/00 ,  C10N10/02 ,  C10N10/04 ,  C10N30/12 ,  C10N40/20 ,  B32B15/04 ,  C04B9/02

    CPC classification number: C10M141/12 ,  C10M163/00 ,  C10M2207/027 ,  C10M2207/028 ,  C10M2219/044 ,  C10M2219/046 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/045 ,  C10M2225/041 ,  C10M2227/061 ,  C10N2230/12 ,  C10N2270/02

    Abstract: Corrosion-inhibiting compositions are described which comprise a mixture of(A) at least one oil-soluble neutral or basic alkali metal or alkaline earth metal salt or complex of at least one organic acid, and(B) a nitrogen- and boron-containing composition which is the reaction product of at least one amino alcohol, at least one of a boric acid or boron trioxide, and at least one organic carboxylic acid. Such compositions exhibit improved corrosion-inhibiting properties, especially when included in preservative oil applications. In a preferred embodiment, the composition of the invention contains, in addition to the nitrogen- and boron-containing compositions, a mixture of calcium and barium salts of one or more organic sulfonic acids.Oil compositions containing the above-described corrosion-inhibiting compositions also are described. The disclosure also describes methods for inhibiting the corrosion of metal surfaces and metal articles which have been coated in accordance with the method of the invention.

    Abstract translation: 描述了包含（A）至少一种油溶性中性或碱性碱金属或碱土金属盐或至少一种有机酸的络合物的混合物的腐蚀抑制组合物，和（B）含氮和硼的 组合物，其为至少一种氨基醇，硼酸或三氧化硼中的至少一种和至少一种有机羧酸的反应产物。 这种组合物表现出改善的腐蚀抑制性能，特别是当包含在防腐油应用中时。 在优选的实施方案中，本发明的组合物除了含氮和硼的组合物外还含有一种或多种有机磺酸的钙和钡盐的混合物。 还描述了含有上述腐蚀抑制组合物的油组合物。 本公开还描述了根据本发明的方法涂覆的金属表面和金属制品的腐蚀抑制方法。

    Method to remediate soil using a surfactant of a salt of an acrylamidoalkanesulfonic acid-amine reaction product
    6.
    发明授权
    Method to remediate soil using a surfactant of a salt of an acrylamidoalkanesulfonic acid-amine reaction product 失效
    使用丙烯酰氨基链烷磺酸 - 胺反应产物的盐的表面活性剂来修复土壤的方法

    公开(公告)号：US06264399B1

    公开(公告)日：2001-07-24

    申请号：US09418346

    申请日：1999-10-14

    Applicant: Bryan A. Grisso ,  Richard W. Jahnke

    Inventor： Bryan A. Grisso ,  Richard W. Jahnke

    IPC: B09C102

    CPC classification number: B09C1/02 ,  Y10S588/901

    Abstract: A method for remediating soil which is contaminated by one or more hydrophobic organic chemicals, comprising: contacting the contaminated soil with an aqueous composition comprising a surfactant prepared by reacting a sulfonate of the formula an amine wherein R1 is hydrogen or methyl, R2 is hydrogen or an alkyl group containing up to 18 carbon atoms, and each of R3, R4 and R5 is individually hydrogen or an alkyl group containing up to 7 carbon atoms and M is an alkali metal, an alkaline earth metal or —NR10R11R12 wherein R10, R11 and R12 are independently hydrogen or hydrocarbyl groups containing from 1 to 22 carbon atoms and removing said aqueous compositions and organic chemicals associated therewith from the soil.

    Abstract translation: 一种用于补救被一种或多种疏水性有机化学物质污染的土壤的方法，包括：使污染的土壤与含有表面活性剂的水性组合物接触，所述水性组合物包含通过使式其中R 1为氢或甲基，R 2为氢或 含有至多18个碳原子的烷基，R 3，R 4和R 5各自独立地为氢或含有至多7个碳原子的烷基，M为碱金属，碱土金属或-NR 10 R 11 R 12，其中R 10，R 11和R 12 独立地是氢或含有1至22个碳原子的烃基，并且从土壤中除去所述含水组合物和与其相关的有机化学物质。

    Salt compositions and explosives using same
    7.
    发明授权
    Salt compositions and explosives using same 失效

    公开(公告)号：US5407500A

    公开(公告)日：1995-04-18

    申请号：US163234

    申请日：1993-12-06

    Applicant: John W. Forsberg ,  Richard W. Jahnke ,  Richard M. Lange ,  Marvin B. DeTar

    Inventor： John W. Forsberg ,  Richard W. Jahnke ,  Richard M. Lange ,  Marvin B. DeTar

    IPC: B01F17/00 ,  B01F17/16 ,  C06B47/14 ,  B01F17/36 ,  C06B45/00 ,  C07C69/40

    CPC classification number: B01F17/0042 ,  C06B47/145 ,  Y10S516/06 ,  Y10S516/07

    Abstract: The present invention provides for a novel salt composition comprising: (A) at least one salt moiety derived from (A)(I) at least one high-molecular weight hydrocarbyl-substituted polycarboxylic acylating agent, said hydrocarbyl-substituent of said acylating agent (A)(I) having a number average molecular weight of at least about 280, and (A)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; (B) at least one salt moiety derived from (B)(I) at least one low-molecular weight polycarboxylic acylating agent, said acylating agent (B)(I) optionally having at least one hydrocarbyl substituent having up to about 18 carbon atoms, and (B)(II) one or more members selected from the group consisting of ammonia, at least one amine, at least one alkali or alkaline earth metal, and at least one alkali or alkaline earth metal compound; said moieties (A) and (B) being coupled together by (C) at least one compound comprising (C)(I) and optionally component (C)(II), component (C)(I) being at least one oxazoline represented by the formula ##STR1## wherein in Formula (I), R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (i) hydrogens, (ii) hydrocarbyl groups, (iii) hydroxy-substituted hydrocarbyl groups, (iv) hydroxy-substituted poly(hydrocarbyloxy) groups, (v) amino-substituted hydrocarbyl groups or (vi) amino-substituted poly(hydrocarbyloxy) groups, with the proviso that at least two of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently (iii), (iv), (v) or (vi); optional component (C)(II) being at least one compound other than component (C)(I) having (i) two or more primary amino groups, (ii) two or more secondary amino groups, (iii) at least one primary amino group and at least one secondary amino group, (iv) at least two hydroxyl groups or (v) at least one primary or secondary amino group and at least one hydroxyl group. The invention also provides for concentrates and explosive emulsions containing the foregoing composition.

    Oil-water emulsions
    8.
    发明授权
    Oil-water emulsions 失效
    油水乳液

    公开(公告)号：US5360458A

    公开(公告)日：1994-11-01

    申请号：US717683

    申请日：1991-06-19

    Applicant: John W. Forsberg ,  Richard W. Jahnke

    Inventor： John W. Forsberg ,  Richard W. Jahnke

    IPC: B01F17/00 ,  C10L1/32 ,  C10L1/22 ,  C10L1/30

    CPC classification number: B01F17/0042 ,  C10L1/328 ,  Y10S516/07 ,  Y10T137/0391

    Abstract: This invention provides for water-oil emulsions comprising water, oil and a minor emulsifying amount of the reaction product of: (A) at least one saturated or unsaturated aliphatic monocarboxylic acid of about 12 to about 24 carbon atoms; (B) at least one acid of the general formula C.sub.19 H.sub.n COOH, wherein n is a number in the range of about 27 to about 31, and having a phenathrene nucleus; and (C) at least one amine. In one hydroxy embodiment, the oil employed in these emulsions can be any oil, the water content of these emulsions being up to about 30% by weight. In a preferred embodiment, the oil employed is crude oil. These emulsions can be facilitatingly pumped through a conduit even when the oil employed is a viscous crude oil. These emulsions are useful as a combustible fuel when the water content is below about 30% by weight.

    Abstract translation: 本发明提供包含水，油和少量乳化量的以下的反应产物的水 - 油乳液：（A）至少一种约12至约24个碳原子的饱和或不饱和脂族单羧酸; （B）至少一种通式C 19 H n COOH的酸，其中n为约27至约31的数，并具有苯并萘核; 和（C）至少一种胺。 在一个羟基实施方案中，这些乳液中使用的油可以是任何油，这些乳液的水含量高达约30重量％。 在优选的实施方案中，所用的油是原油。 即使当所用的油是粘性原油时，这些乳液也可以方便地泵送通过导管。 当水含量低于约30重量％时，这些乳液可用作可燃燃料。

    Compositions containing combinations of surfactants and derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same
    9.
    发明授权
    Compositions containing combinations of surfactants and derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same 失效
    包含表面活性剂和琥珀酰化剂或羟基芳族化合物的衍生物的组合的组合物及其使用方法

    公开(公告)号：US5330662A

    公开(公告)日：1994-07-19

    申请号：US852872

    申请日：1992-03-17

    Applicant: Richard W. Jahnke ,  Lawrence J. Kocurek ,  James H. Bush

    Inventor： Richard W. Jahnke ,  Lawrence J. Kocurek ,  James H. Bush

    IPC: B01F17/00 ,  C09K8/28 ,  C09K8/36 ,  E21B43/00 ,  C09K7/02

    CPC classification number: B01F17/005 ,  B01F17/0085 ,  C09K8/28 ,  C09K8/36 ,  Y10S507/925

    Abstract: This invention relates to a composition comprising a mixture of a brine and a liquid hydrocarbon, and (A) an emulsifying amount of (i) at least one reaction product of a hydrocarbyl-substituted succinic acylating agent, and at least one of (a) ammonia, (b) an alcohol, or (c) an amine, or at least one salt of the reaction product; or (ii) at least one reaction product of a hydroxyaromatic compound, an aldehyde, and an amine, and (B) at least one surfactant selected from the group consisting of a polyoxyalkylene amine, a polyoxyalkylene amide, a polyoxyalkylene alcohol, a polyoxyalkylene phenol, a polyoxyalkylene ester, a fatty acid salt, an amine or an alkaline earth or transition metal sulfonate, or a reaction product of a hydroxyamine or a polyalkylenepolyamine with an acylating agent selected from the group consisting of a fatty monocarboxylic acylating agents, a dicarboxylic acylating agent other than a succinic acylating agent, and a tricarboxylic acylating agent. The compositions of the present invention have beneficial emulsion and viscosity properties. These compositions are useful in drilling, working and completing well bore holes. The compositions of the present invention have beneficial viscosity, pumping and suspension properties. These compositions are stable. The surfactants of the compositions act as wetting agents for barites and organophilic clays. The surfactants may also act as an emulsifier as well as a wetting agent.

    Abstract translation: 本发明涉及包含盐水和液体烃的混合物的组合物，和（A）乳化量的（i）至少一种烃基取代的琥珀酰化剂的反应产物和（a）的至少一种， 氨，（b）醇，或（c）胺，或至少一种反应产物的盐; 或（ii）羟基芳族化合物，醛和胺的至少一种反应产物，和（B）至少一种表面活性剂，其选自聚氧化烯胺，聚氧化烯酰胺，聚氧化烯醇，聚氧化烯苯酚 ，聚氧化烯酯，脂肪酸盐，胺或碱土金属或过渡金属磺酸盐，或羟胺或聚亚烷基多胺与酰化剂的反应产物，所述酰化剂选自脂肪单羧酸酰化剂，二羧酰化剂 琥珀酰化剂以外的其它试剂和三羧酸酰化剂。 本发明的组合物具有有利的乳液和粘度特性。 这些组合物可用于钻孔，加工和完井孔。 本发明的组合物具有有益的粘度，泵送和悬浮性能。 这些组合物是稳定的。 组合物的表面活性剂作为重晶石和亲有机粘土的润湿剂。 表面活性剂也可以用作乳化剂以及润湿剂。

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